ELECTRODE SHEET, BATTERY INCORPORATING THE ELECTRODE SHEET, METHOD FOR MANUFACTURING THE ELECTRODE SHEET, METHOD FOR MANUFACTURING THE BATTERY INCORPORATING THE ELECTRODE SHEET, AND DIE HEAD

• US 20200136133A1
• Filed: 08/28/2019
• Published: 04/30/2020
• Est. Priority Date: 10/31/2018
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: UMEHARA, Masakazu
• Granted Patent: US 11,695,120 B2
• Time in Patent Office: Days
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/058 Construction or manufacture
• CPC Class Codes: H01M 10/0587 of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 2004/021 Physical characteristics, e.g. porosity, surface area
• CPC Class Codes: H01M 2004/028 Positive electrodes
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0409 by a doctor blade method, slip-casting or roller coating
• CPC Class Codes: H01M 4/043 involving compressing or compaction
• CPC Class Codes: H01M 4/0471 involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/139 Processes of manufacture
• CPC Class Codes: H01M 4/1391 of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/628 Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A strip-shaped electrode sheet includes an electrode foil including a strip-shaped foil exposed portion in which the electrode foil is exposed, a strip-shaped active material layer extending in a longitudinal direction, and a strip-shaped insulator layer containing insulating resin and formed on an insulator-layer support portion along a one-side layer edge portion of the active material layer and between the foil exposed portion of the electrode foil and an active-material-layer support portion. The insulator layer is located lower than a top face of the active material layer toward the electrode foil and includes a slant coating portion covering at least a lower portion of a one-side slant portion of the active material layer and a foil coating portion extending from the slant coating portion in a width-direction one side and covering the insulator-layer support portion of the electrode foil.

Claims

1. A strip-shaped electrode sheet comprising:

a strip-shaped electrode foil extending in a longitudinal direction, the electrode foil including a one-side foil edge on one side in a width direction of the electrode foil and a strip-shaped foil exposed portion extending along the one-side foil edge in the longitudinal direction, in which the electrode foil is exposed;

a strip-shaped active material layer extending in the longitudinal direction, the active material layer being formed on an active-material-layer support portion of the electrode foil on an other side in the width direction relative to the foil exposed portion; and

a strip-shaped insulator layer extending in the longitudinal direction and containing insulating resin, the insulator layer being formed along a one-side layer edge portion of the active material layer located on the one side in the width direction and on an insulator-layer support portion of the electrode foil located between the foil exposed portion and the active-material-layer support portion,

wherein the one-side layer edge portion of the active material layer includes a one-side slant portion in which the active material layer has a thinner thickness as closer to the one side in the width direction,

the insulator layer is located lower than a top face of the active material layer toward the electrode foil, and

the insulator layer includes;

a slant coating portion that covers at least a lower portion of the one-side slant portion of the active material layer; and

a foil coating portion that extends from the slant coating portion toward the one side in the width direction to cover the insulator-layer support portion of the electrode foil.

2. The strip-shaped electrode sheet according to claim 1, wherein the slant coating portion of the insulator layer has a thickness that is thicker than a thickness of the foil coating portion.

3. The strip-shaped electrode sheet according to claim 1, wherein the insulator layer contains inorganic insulation powder.

4. The strip-shaped electrode sheet according to claim 1, wherein the active material layer contains positive active material particles made of metal oxide.

5. A rectangular electrode sheet made of the strip-shaped electrode sheet according to claim 1, the strip-shaped electrode sheet being cut at a predetermined length in the longitudinal direction.

6. A battery incorporating either the strip-shaped electrode sheet according to claim 1.

7. A method for manufacturing a strip-shaped electrode sheet, the strip-shaped electrode sheet comprising:

a strip-shaped electrode foil extending in a longitudinal direction, the electrode foil including a one-side foil edge on one side in a width direction of the electrode foil and a strip-shaped foil exposed portion extending along the one-side foil edge in the longitudinal direction, in which the electrode foil is exposed;

a strip-shaped active material layer extending in the longitudinal direction, the active material layer being formed on an active-material-layer support portion of the electrode foil on an other side in the width direction relative to the foil exposed portion; and

a strip-shaped insulator layer extending in the longitudinal direction and containing insulating resin, the insulator layer being formed along a one-side layer edge portion of the active material layer located on the one side in the width direction and on an insulator-layer support portion of the electrode foil located between the foil exposed portion and the active-material-layer support portion,

wherein the one-side layer edge portion of the active material layer includes a one-side slant portion in which the active material layer has a thinner thickness as closer to the one side in the width direction,

the insulator layer is located lower than a top face of the active material layer toward the electrode foil, and

the insulator layer includes;

a slant coating portion that covers at least a lower portion of the one-side slant portion of the active material layer; and

a foil coating portion that extends from the slant coating portion toward the one side in the width direction to cover the insulator-layer support portion of the electrode foil,

wherein the method comprises;

a coating step of applying active material paste and insulator paste each discharged from a die head respectively to the active-material-layer support portion and the insulator-layer support portion of the electrode foil that is being fed in the longitudinal direction to form an undried active material layer and an undried insulator layer; and

a drying step of drying the undried active material layer and the undried insulator layer to form the strip-shaped electrode sheet including the active material layer and the insulator layer,

wherein the die head includes;

a first slot extending straight in the width direction and configured to discharge the active material paste; and

a second slot located on the one side in the width direction relative to the first slot and arranged in line with the first slot at a predetermined distance, the second slot being narrower in the width direction than the first slot and configured to discharge the insulator paste,

the coating step includes causing the undried active material layer made of the active material paste discharged from the first slot and applied to the electrode foil to spread on the electrode foil toward the one side in the width direction and contact with the undried insulator layer made of the insulator paste discharged from the second slot and applied to the electrode foil with a clearance from the undried active material layer from the other side in the width direction on the electrode foil, so that a portion of the undried insulator layer located on the other side in the width direction overrides an undried one-side slant portion of the undried active material layer, in which the undried active material layer is thinner in thickness as closer to the one side in the width direction.

8. The method for manufacturing a strip-shaped electrode sheet according to claim 7, wherein the die head is configured to discharge the insulator paste from the second slot toward the electrode foil opposed to the second slot and toward the other side in the width direction.

9. The strip-shaped electrode sheet manufacturing method according to claim 7, wherein the second slot of the die head has a size in a feeding direction set different from a size of the first slot in the feeding direction.

10. The method for manufacturing a strip-shaped electrode sheet according to claim 9, wherein the insulator paste is lower in viscosity than the active material paste, and

the die head is configured such that the size of the second slot in the feeding direction is smaller than the size of the first slot in the feeding direction.

11. The method for manufacturing a strip-shaped electrode sheet according to claim 10, wherein the die head is configured such that a position of the second slot is biased to a downstream side in the feeding direction relative to a position of the first slot.

12. A method for manufacturing a rectangular electrode sheet comprising a longitudinal-direction cutting step of cutting the strip-shaped electrode sheet manufactured by the strip-shaped electrode sheet manufacturing method according to claim 7 at a predetermined length in a longitudinal direction.

13. A method for manufacturing a battery, comprising an electrode-body forming step of forming an electrode body from either the strip-shaped electrode sheet manufactured by the strip-shaped electrode sheet manufacturing method according to claim 7.

14. A die head comprising:

a first slot extending straight in a width direction and configured to discharge first paste; and

a second slot located on one side in the width direction relative to the first slot at a predetermined distance, the second slot being narrower in the width direction than the first slot and configured to discharge second paste,

wherein the die head further includes a passage configured to direct the second paste to the second slot, and

the second passage has a shape allowing the second paste to move toward the second slot and move toward an other side in the width direction.

15. The die head according to claim 14, wherein the second slot has a size in a feeding direction set different from a size of the first slot in the feeding direction.

16. The die head according to claim 15, wherein the size of the second slot in the feeding direction is smaller than the size of the first slot in the feeding direction.

17. The die head according to claim 16, wherein a position of the second slot is biased to a downstream side in the feeding direction relative to a position of the first slot.