Si-h to c=c or c=c addition in the presence of a nitrile-platinum (ii) halide complex

• US 3,410,886 A
• Filed: 10/23/1965
• Issued: 11/12/1968
• Est. Priority Date: 10/23/1965
• Status: Expired due to Term

• Current Assignee: John R. Joy
• Original Assignee: John R. Joy
• Inventors: Joy, John R.
• Application Number:
  US04/504,051
• Time in Patent Office: 1,116 Days
• US Class Current: 556/479
• CPC Class Codes: C07F 7/0801 General processes

Claims

1. A PROCESS FOR THE PRODUCTION OF ORGANOSILICON COMPOUNDS CONTAINING SILICON-CARBON BONDS WHICH COMPRISES CONTACTING A SILICON COMPOUND CONTAINING AT LEAST ONE HYDROGEN ATOM ATTACHED TO A SILICON ATOM PER MOLECULE, BUT NO MORE THAN TWO HYDROGEN ATOMS BEING ATTACHED TO ANY SILICON ATOM IN THE MOLECULE, WITH AN ALIPHATIC ORGANIC COMPOUND HAVING CARBON-TO-CARBON UNSATURATION BUT FREE FROM OTHER FUNCTIONAL GROUPS REACTIVE TOWARD $SIH, IN THE PRESENCE OF CATALYTIC AMOUNTS OF A PLATINUM (II) COMPLEX WHICH IS A MEMBER OF THE GROUP CONSISTING OF AN ARYL NITRILE-PLATINUM (II) HALIDE COMPLEX, AN ALKYL NITRILE-PLATINUM (II) HALIDE COMPLEX, AN ALKARYL NITRILEPLATINUM (II) HALIDE COMPLEX, AN ARALKYL NITRILE-PLATINUM (II) HALIDE COMPLEX, AND A HALOARYL NITRILE-PLATINUM (II) HALIDE COMPLEX, FOR A TIME PERIOD SUFFICIENT TO FORM A SILICON-CARBON BOND.