Blends of biodegradable thermoplastic oxyalkanoyl polymer, a naturally occurring biodegradable product, filler and plastic additive

• US 3,931,068 A
• Filed: 07/15/1974
• Issued: 01/06/1976
• Est. Priority Date: 07/28/1972
• Status: Expired due to Term

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Clendinning, Robert A., Potts, James E., Niegisch, Walter D.
• Primary Examiner(s): Rzucidlo, Eugene C.
• Application Number:
  US05/488,492
• Time in Patent Office: 540 Days
• Field of Search: 260/DIG. 43, 260/40 R, 260/862, 260/78.3 R, 260/7.5, 260/9, 220/1 R, 220/DIG. 30
• US Class Current: 524/14
• CPC Class Codes: A01G 13/0275 Films
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 67/04 Polyesters derived from hydroxycarboxylic acids, e.g. lactones C08L67/06 takes precedence
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: C09K 17/52 Mulches
• CPC Class Codes: Y02A 40/28 specially adapted for farming
• CPC Class Codes: Y10S 220/03 Breaker strips and sealing strips

Abstract

Blends comprising biodegradable thermoplastic oxyalkanoyl polymer, e.g., epsilon-caprolactone polymer, and naturally occurring biodegradable product, e.g., tree bark. These novel blends are useful in the production of shaped articles such as mulch film, transplanter containers, package containers, and the like.

Claims

1. A blend comprising (i) from about 3 to about 97 weight percent of biodegradable thermoplastic oxyalkanoyl polymer, said polymer having a reduced viscosity value of at least about 0.1 and upwards to about 12 and being further characterized in that at least about 10 weight percent of said thermoplastic oxyalkanoyl polymer is attributable to recurring oxyalkanoyl units of the formula ##EQU15## wherein x is an integer having a value of 2 to 7, with the proviso that x does not equal 3;

(ii) from less than 97 to about 3 weight percent of naturally occurring biodegradable product; and

(iii) more than 0 to about 75 weight percent of ingredients of the group consisting of plastic additives, fillers, and mixtures thereof, based on the total weight of said blend.

2. The blend of claim 1 wherein said recurring oxyalkanoyl units have the formula ##EQU16##

3. The blend of claim 2 wherein said biodegradable thermoplastic oxyalkanoyl polymer has a reduced viscosity value of at least about 0.2 to about 8 and is further characterized in that at least about 20 weight percent of said polymer is attributable to the recurring oxyalkanoyl unit shown therein.

4. The blend of claim 3 wherein at least about 50 weight percent of said polymer is attributable to recurring oxycaproyl units.

5. The blend of claim 4 wherein at least about 80 to about 100 weight percent of said polymer is attributable to recurring oxycaproyl units.

6. The blend of claim 4 wherein said polymer has a reduced viscosity value of at least about 0.25 to about 3.

7. The blend of claim 4 comprising (i) from about 10 to about 90 weight percent of biodegradable thermoplastic oxycaproyl polymer, and (ii) from about 10 to about 90 weight percent of naturally occurring biodegradable product, based on the total weight of said blend.

8. The blend of claim 7 comprising (i) from about 20 to about 80 weight percent of biodegradable thermoplastic oxycaproyl polymer, (ii) from about 20 to about 80 weight percent of naturally occurring biodegradable product, and (iii) from greater than 0 to about 60 weight percent of ingredients of the group consisting of plastic additives, fillers, and mixtures thereof, based on the total weight of said blend.

9. The blend of claim 8 wherein said naturally occurring biodegradable product is tree bark.

10. The blend of claim 9 wherein said naturally occurring biodegradable product is shredded wood.

11. The blend of claim 9 wherein said tree bark is Douglas Fir bark.

12. Articles of manufacture from the blend claimed in claim 1.

13. Articles of manufacture from the blend claimed in claim 2.

14. Articles of manufacture from the blend claimed in claim 3.

15. Articles of manufacture from the blend claimed in claim 4.

16. Articles of manufacture from the blend claimed in claim 5.

17. The articles of manufacture of claim 16 in the form of a container.

18. The articles of manufacture of claim 16 in the form of a film.

19. The articles of manufacture of claim 16 in the form of packaging material.

20. A blend comprising (i) from about 3 to about 97 weight percent of biodegradable thermoplastic oxyalkanoyl polymer, said polymer having a reduced viscosity value of at least about 0.1 and upwards to about 12 and being further characterized in that at least about 10 weight percent of said thermoplastic oxyalkanoyl polymer is attributable to recurring oxyalkanoyl units of the formula ##EQU17## wherein x is an integer having a value of 2 to 7, with the proviso that x does not equal 3;

(ii) from less than 97 to about 3 weight percent of soybean meal; and

, (iii) more than 0 to about 75 weight percent of ingredients of the group consisting of plastic additives, fillers, and mixtures thereof, based on the total weight of said blend.

21. The blend of claim 20 wherein said recurring oxyalkanoyl units have the formula ##EQU18##

22. The blend of claim 21 wherein said biodegradable thermoplastic oxyalkanoyl polymer has a reduced viscosity value of at least about 0.2 to about 8 and is further characterized in that at least about 20 weight percent of said polymer is attributable to the recurring oxyalkanoyl unit shown therein.

23. The blend of claim 22 wherein at least about 50 weight percent of said polymer is attributable to recurring oxycaproyl units.

24. The blend of claim 23 wherein at least about 80 to about 100 weight percent of said polymer is attributable to recurring oxycaproyl units.

25. The blend of claim 23 wherein said polymer has a reduced viscosity value of at least about 0.25 to about 3.

26. The blend of claim 23 comprising (i) from about 10 to about 90 weight percent of biodegradable thermoplastic oxycaproyl polymer, and (ii) from about 10 to about 90 weight percent of soybean meal, based on the total weight of said blend.

27. Articles of manufacture from the blend claimed in claim 26.

28. The articles of manufacture of claim 27 in the form of a container.