Process for obtaining cellulose from ligno-cellulosic raw materials

• US 3,932,207 A
• Filed: 03/05/1973
• Issued: 01/13/1976
• Est. Priority Date: 03/06/1972
• Status: Expired due to Term

• Current Assignee: Societe de Promotion et D'Exploitation Industrielles de Procedes de Brevets SA
• Original Assignee: Societe de Promotion et D'Exploitation Industrielles de Procedes de Brevets SA
• Inventors: Fogarassy, Andre
• Primary Examiner(s): Lindsay, Jr., Robert L.
• Assistant Examiner(s): Corbin, Arthur L.
• Application Number:
  US05/337,858
• Time in Patent Office: 1,044 Days
• Field of Search: 162/70, 162/77, 162/76, 162/75, 162/72, 162/81, 162/83, 162/90, 162/86, 162/19, 162/84
• US Class Current: 162/19
• CPC Class Codes: D21C 3/20 with organic solvents or in solvent environment

Abstract

Prior to cooking, fragments of raw ligno-cellulosic material are impregnated with a solution of a lignin-solubilizing reactant in an organic solvent which has a boiling point higher than the cooking temperature in order for the material to absorb an amount of solution containing at least the amount of reactant required for solubilizing the lignin, then the impregnated material is immersed in a liquid which is substantially non-miscible with the solvent of said solution, said liquid having a boiling point higher than the cooking temperature, and said liquid is maintained at the cooking temperature until the lignin has been substantially converted to a derivative which is soluble in water or a water-miscible organic solvent.

Claims

1. In a process for obtaining cellulose from ligno-cellulosic raw materials comprising the steps of cooking the raw material in contact with a solution of a reactant for converting lignin present in said raw material into a derivative which is soluble in water or in a water-miscible organic solvent, extracting the thus formed derivative in an aqueous medium, and separating cellulose from the aqueous medium, the improvement which comprises impregnating the raw material, before the cooking step, in the form of fragments, with a solution of said reactant in a solvent which has a boiling point higher than the cooking temperature and which is selected from the group consisting of ethyleneglycol, dipropylengeglycol, glycerol, aniline, diethanolamine and triethanolamine and mixtures of at least one of these substances with water, said reactant being employed in an amount sufficient to solubilize the lignin, whereby the raw material absorbs a portion of the solution, after which the impregnated material is immersed in a liquid which is substantially non-miscible with the solvent of said solution, said liquid having a boiling point higher than the cooking temperature, and which is selected from the group consisting of paraffinic mineral oils, siloxanes, n-butyl acetylricinoleate, n-butyl benzoate, diethyleneglycol monolaurate, propiophenone, dibutylether and mixtures thereof and then maintaining said liquid having the impregnated material immersed therein at the cooking temperature until the lignin has been substantially converted to said derivative.

2. A process according to claim 1, wherein said solution is a solution of sodium hydroxide in a mixture of aniline and water, and said liquid is a paraffinic mineral oil.

3. A process according to claim 1, wherein said solution is a solution of sodium hydroxide in a mixture of ethyleneglycol, aniline and water, and said liquid is a paraffinic mineral oil.

4. A process according to claim 1, wherein said solution is a solution of sodium anilide in a mixture of ethyleneglycol and water, and said liquid is n-butyl acetylricinoleate.

5. A process according to claim 1, wherein said solution is a solution of the acetone-sodium bisulfite compound in a mixture of aniline, diethanolamine and water, and said liquid is n-butyl benzoate.

6. A process according to claim 1, wherein said solution is a solution of sodium phenate and sodium benzoate in a mixture of glycerol, diethanolamine and water, and said liquid is diethyleneglycol monolaurate.

7. A process according to claim 1, wherein said solution is a solution of sodium hydroxide and sodium stearate in a mixture of glycerol, aniline, and water, and said liquid is propiophenone.

8. A process according to claim 1, wherein said solution is a solution of the acetone-sodium bisulfite compound in a mixture of aniline, triethanolamine and water, and said liquid is dibutylether.

9. A process according to claim 1, wherein said solution is a solution of ammonium thiosulfate in a mixture of dipropyleneglycol, triethanolamine and water, and said liquid is a paraffinic mineral oil.

10. A process according to claim 1, wherein said solution is a solution of ammonium thiosulfate in a mixture of ethyleneglycol, aniline and water, and said liquid is a siloxane.

11. A process according to claim 1, wherein said solution is a solution of sodium benzoate in a mixture of triethanolamine, aniline and water, and said liquid is a siloxane.

12. A process according to claim 1, wherein, said aqueous medium is an azeotropic mixture having a low boiling point.