Absorption of sulfur oxides from flue gas
First Claim
1. A closed-cycle process capable of removing in a single spray-drying step at least 90% of a sulfur oxide impurity from a hot waste gas comprising the steps of:
- contacting the hot sulfur oxide-containing waste gas at a temperature of at least 90°
C in a single spray-drying step with an aqueous scrubbing medium containing between 2 and 40 wt.% of an absorbent selected from the group consisting of alkali metal carbonate, alkali metal bicarbonate, and mixtures of alkali metal carbonate and bicarbonate to form alkali metal sufate and sulfite,recovering the resultant reaction product as a flowable, dry powder mixture not requiring further drying, said mixture containing from 20 to 85 wt.% alkali metal sulfite and sulfate and from 15 to 80 wt.% alkali metal carbonate and bicarbonate,reacting said mixture in the molten state with a carbonaceous reducing agent under reducing conditions to convert sulfite and sulfate to sulfide while supplying a controlled amount of a source of gaseous oxygen to the reaction to provide internal heat generation to melt the mixture and maintain it in the molten state.recovering a molten reaction product of alkali metal sulfide and carbonate,dissolving this reaction product in water to form an aqueous solution, andreacting said aqueous solution with a carbon dioxide-yielding material to form hydrogen sulfide gas as a recoverable product and regenerate alkali metal bicarbonate and carbonate for recirculation in the process.
2 Assignments
0 Petitions
Accused Products
Abstract
A method is shown for removing sulfur dioxide from a hot flue gas by absorption of the sulfur dioxide in an aqueous solution or slurry containing no more than 40 wt.% of an alkali metal carbonate or bicarbonate, preferably sodium carbonate and/or sodium bicarbonate using a spray-dryer scrubber to produce a dry mixture of sodium sulfite, sodium sulfate, and sodium carbonate and/or bicarbonate. Such a mixture is directly suitable as a feed to a regeneration stage.
It is particularly preferred to regenerate the absorbent and recover commercial sulfur values in a closed-cycle process by next treating the solid absorption product in a molten salt reduction step with a reducing agent, preferably a carbonaceous material, to reduce the sodium sulfite and sulfate to sodium sulfide. Concurrently, a source of oxygen is fed to the reducer to generate sufficient heat therein for the reduction step by a combustion reaction. In the subsequent aqueous reformation step, the resulting sodium sulfide-carbonate melt from the reduction step is dissolved in water and reacted with carbon dioxide or a carbon dioxide-yielding material to form hydrogen sulfide as a recoverable product for further processing and regenerate the sodium carbonate-bicarbonate absorbent.
-
Citations
7 Claims
-
1. A closed-cycle process capable of removing in a single spray-drying step at least 90% of a sulfur oxide impurity from a hot waste gas comprising the steps of:
-
contacting the hot sulfur oxide-containing waste gas at a temperature of at least 90°
C in a single spray-drying step with an aqueous scrubbing medium containing between 2 and 40 wt.% of an absorbent selected from the group consisting of alkali metal carbonate, alkali metal bicarbonate, and mixtures of alkali metal carbonate and bicarbonate to form alkali metal sufate and sulfite,recovering the resultant reaction product as a flowable, dry powder mixture not requiring further drying, said mixture containing from 20 to 85 wt.% alkali metal sulfite and sulfate and from 15 to 80 wt.% alkali metal carbonate and bicarbonate, reacting said mixture in the molten state with a carbonaceous reducing agent under reducing conditions to convert sulfite and sulfate to sulfide while supplying a controlled amount of a source of gaseous oxygen to the reaction to provide internal heat generation to melt the mixture and maintain it in the molten state. recovering a molten reaction product of alkali metal sulfide and carbonate, dissolving this reaction product in water to form an aqueous solution, and reacting said aqueous solution with a carbon dioxide-yielding material to form hydrogen sulfide gas as a recoverable product and regenerate alkali metal bicarbonate and carbonate for recirculation in the process. - View Dependent Claims (2, 3, 4, 5, 6, 7)
-
Specification