Process for preparing a hollow, rib-reinforced laminated structure

• US 3,935,358 A
• Filed: 02/15/1974
• Issued: 01/27/1976
• Est. Priority Date: 03/29/1973
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Wyeth, Nathaniel Convers, Arnoth, Frank William
• Primary Examiner(s): Silbaugh, Jan H.
• Application Number:
  US05/443,199
• Time in Patent Office: 711 Days
• Field of Search: 264/89, 264/90, 264/92, 264/93, 264/94, 264/96, 264/98, 264/99, 264/294, 264/296, 264/248, 156/145, 156/221, 156/156, 156/285, 156/292, 156/245, 29/157.3 V, 29/421 R, 72/60-62, 425/387, 425/388, 425/387 B, 425/503, 425/504, 161/122, 161/123, 428/166, 428/167
• US Class Current: 428/166
• CPC Class Codes: B29C 2791/006 Using vacuum
• CPC Class Codes: B29C 49/0691 using sheet like material, e.g. sheet blow-moulding from joined sheets
• CPC Class Codes: B32B 2315/16 Clay
• CPC Class Codes: B32B 2323/04 Polyethylene
• CPC Class Codes: B32B 2323/10 Polypropylene
• CPC Class Codes: B32B 27/00 Layered products comprising a layer of synthetic resin fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 3/30 characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs apertured layer B32B3/266; layer with cavities or internal voids B32B3/26
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: Y10T 428/24562 Interlaminar spaces
• CPC Class Codes: Y10T 428/2457 Parallel ribs and/or grooves

Abstract

The invention provides a process for preparing a hollow, rib-reinforced, laminated article by:

A. placing two sheets between opposing mold platens, the sheets being aligned such that the sheet surfaces oppose each other, at least one of the sheets being a thermoplastic material heated to its thermoforming temperature and at least one of the sheets being provided with grooves or integral projections which form fluid passageways, and at least one of the mold platens being provided with a mold caivty to form a shaped article having ribs;

B. closing the mold platens to contact the sheets; and

C. introducing a fluid into the fluid passageways to distend the thermoplastic sheet into its mold cavity forming a shaped article having ribs, while the sheets maintain contact in the nondistended areas.

Claims

1. A process for preparing a hollow, ribreinforced, laminated article consisting essentially of:

a. placing two sheets between opposing mold platens, the sheets being aligned such that the sheet surfaces are in interfacial contact, at least one of the sheets being a thermoplastic material heated to its thermoforming temperature and at least one of the sheets being provided with grooves or integral projections, on the surface which contacts the other sheet, which form fluid passageways, and at least one of the mold platens being provided with a mold cavity to form a shaped article having ribs;

b. closing the mold platens to contact the sheets and position the mold cavity contiguous to the thermoplastic sheet which is at its thermoforming temperature;

c. introducing a fluid into the fluid passageways to distend the thermoplastic sheet into its mold cavity forming a shaped article having ribs, while the closed mold platens maintain contact between the sheets in the nondistended areas; and

(d) adhering the sheets in the nondistended areas to form a laminate.

2. The process of claim 1 wherein both sheets are a thermoplastic material.

3. The process of claim 2 wherein the thermoplastic material is polyethylene or polypropylene.

4. The process of claim 2 wherein both sheets are distended in step (c).

5. The process of claim 2 wherein fluid is introduced into the fluid passageways under pressure.

6. The process of claim 5 wherein the fluid is heated air.

7. The process of claim 6 wherein a vacuum is drawn in the mold.

8. The process of claim 2 wherein the projections of the sheet are ridges having a width less than the thickness of the sheet.

9. The process of claim 1 wherein, in step (d), the mold platens are further closed to seal nondistended portions of the sheets.

10. The process of claim 9 wherein both sheets are a thermoplastic material.

11. The process of claim 10 wherein a composite preform of two thermoplastic sheets is placed between the mold platens in step (a).

12. The process of claim 11 wherein one of the thermoplastic sheets has projections and the other thermoplastic sheet is smooth.

13. The process of claim 11 wherein both thermoplastic sheets have projections.

14. The process of claim 11 wherein both sheets are distended in step (c).

15. The process of claim 11 wherein fluid is introduced into the fluid passageways under positive pressure.

16. The process of claim 15 wherein the fluid is heated air.

17. The process of claim 11 wherein the preform is heated by placing the preform between two opposing hot platens.

18. The process of claim 11 wherein the preform is heated by subjecting the preform to radiant heat.

19. The process of claim 11 including the step of heating the mold platens.

20. The process of claim 11 wherein fluid is introduced into the preform passageways through at least one marginal edge.

21. The process of claim 11 wherein the fluid is introduced into the preform passageways by drawing a vacuum in the mold to draw the fluid into the passageways through at least one marginal edge.

22. The process of claim 21 wherein the fluid is introduced under pressure.

23. The process of claim 22 wherein the fluid is heated air.

24. The process of claim 11 wherein the opposing mold platens are closed on the preform with the mold platens spaced apart a distance equivalent to about the thickness of the preform and said mold platens remain in this position until the thermoplastic article has been formed by introducing a fluid into the fluid passages of the preform whereupon the opposing mold platens are closed an incremental amount sufficient to pressure seal the nondistended areas of the preform.

25. The process of claim 11 wherein the thermoplastic material is polyethylene.

26. The process of claim 11 wherein the thermoplastic material is polypropylene.

27. The process of claim 11 wherein the thermoplastic contains an inert filler material in the amount of about 1 to 70 weight percent based on the total weight of the polymer and filler present.

28. The process of claim 11 wherein the thermoplastic contains a filler material of clay in the amount of about 30 to 60 weight percent based on the weight of the polymer present.

29. The process of claim 11 wherein the fluid passages on an interfacial surface of the preform is made up of a pattern which in cross section consists of trapezoidal-shaped protuberances extending in a continuous parallel pattern across the width of the sheet with trapezoidal valleys between the protuberances.

30. The process of claim 11 wherein the fluid passages in the preform are interconnected.

31. The process of claim 11 wherein the thermoplastic sheets of the preform are adhesively bonded together.

32. The process of claim 11 wherein the projections of the sheet are ridges having a width less than the thickness of the sheet.

33. The process of claim 11 wherein the mole is vertically aligned.

34. A hollow, rib-reinforced, laminated article made by the process of claim 1.