Composition and method for inflation of passive restraint systems

• US 3,936,330 A
• Filed: 08/08/1973
• Issued: 02/03/1976
• Est. Priority Date: 08/08/1973
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Lane, George A., Dergazarian, Thomas E.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US05/386,815
• Time in Patent Office: 909 Days
• Field of Search: 149/35, 149/42, 149/75, 149/77, 149/82, 280/150 AB
• US Class Current: 149/35
• CPC Class Codes: C06B 43/00 Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Disclosed is a pyrotechnic composition and a method for the inflation of passive restraint systems, i.e., crash bags. The method utilizes gases produced by the ignition and burning of a pyrotechnic composition containing an alkali metal azide, a metal halide and an inorganic perchlorate.

Claims

1. A composition which burns to produce gases which are rich in nitrogen and substantially free of elemental alkali metals, oxides of nitrogen and alkali metal oxides, which comprises:

an intimate mixture of an alkali metal azide of the formula MN₃, a metal halide of the formula RX_n and an inorganic oxidizer corresponding to the formula A(ClO₄)_m wherein M is an alkali metal;

R is tin, zinc, cobalt, nickel, calcium or magnesium;

X is chlorine, bromine or iodine, n is an integer representing the valence state of R;

A is potassium, sodium, or magnesium and m is equal to the valence of A, said constituents provided in amounts so that upon burning of the composition, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.

2. The composition of claim 1 including in addition up to about 5 percent by weight of a particulate metal fuel.

3. The composition of claim 1 including in addition up to about 2 percent by weight of particulate graphite.

4. The composition of claim 1 wherein said constituents are provided in the following amounts as percent by weight;

MN₃, about 48 to about 53 percent;

RX_n, about 32 to about 40 percent and A(ClO₄)_m, about 10 to about 15 percent.

5. The composition of claim 4 including in addition up to about 5 percent by weight of a particulate metal selected from the group consisting of magnesium, aluminum, titanium, silicon or zinc.

6. The composition of claim 5 including in addition up to about 2 percent by weight of graphite.

7. The composition of claim 4 including up to about 2 percent by weight of graphite.

8. The composition of claim 4 wherein M is sodium or potassium.

9. The composition of claim 4 including in addition up to about 5 percent by weight of a particulate metal selected from the group consisting of magnesium, aluminum, titanium, silicon or zinc;

up to about 2 percent by weight of graphite wherein all the constituents are provided in particulate form having a particle size of about 250 microns or less.

10. A pyrotechnic grain comprising:

an intimate mixture of particles wherein said particles comprise, as percent by weight of the grain, sodium azide, about 50.7 percent;

potassium perchlorate, about 12.2 percent; and

magnesium chloride, about 37.1 percent, said grain being further characterized in that upon burning of the grain, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.

11. A pyrotechnic grain comprising, as percent by weight:

about 49.7 percent NaN₃, about 11.9 percent KClO₄, about 36.4 percent MgCl₂, about 1 percent magnesium and about 1 percent graphite, said grain being further characterized in that upon burning of the grain, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.

12. The composition of claim 11 wherein the individual constituents are in particulate form ranging in size from about 250 microns or less.

13. A method of rapidly generating gases which are rich in nitrogen and substantially free of elemental alkali metals, alkali metal oxides and oxides of nitrogen which comprises:

igniting an intimate mixture of an alkali metal azide of the formula MN₃, a metal halide of the formula RX_n and an inorganic oxidizer corresponding to the formula A(ClO₄)_m wherein M is an alkali metal;

R is tin, zinc, cobalt, nickel, calcium or magnesium;

X is chlorine, bromine or iodine, n is an integer representing the valence state of R;

A is potassium, sodium, or magnesium, and m is equal to the valence of A, said constituents provided in amounts so that upon burning of the composition, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.

14. The method of claim 13 wherein the mixture of metal azide and metal halide is ignited while in fluid communication with an inflatable flexible container, thereby filling and inflating the container with combustion gases upon ignition of the mixture.

15. The method of claim 14 wherein said container is located in an automobile.

16. The method of claim 15 wherein the mixture comprises, as percent by weight, about 50.7 percent sodium azide, about 12.2 percent potassium perchlorate and about 37.1 percent magnesium chloride.

17. The method of claim 14 wherein said mixture comprises, as percent by weight, about 49.7 percent NaN₃, about 11.9 percent KClO₄, about 36.4 percent MgCl₂, about 1 percent magnesium, and about 1 percent graphite.