Process for the production of high impact compositions of polyethylene and polypropylene block copolymers

• US 3,937,758 A
• Filed: 07/01/1975
• Issued: 02/10/1976
• Est. Priority Date: 03/26/1973
• Status: Expired due to Term

• Current Assignee: Rexene Corp. (Huntsman Corporation)
• Original Assignee: Dart Industries Incorporated (Tupperware Brands Corporation)
• Inventors: Castagna, Eugene G.
• Primary Examiner(s): Turer, Richard B.
• Application Number:
  US05/592,145
• Time in Patent Office: 224 Days
• Field of Search: 260/876 B, 260/878 B
• US Class Current: 525/88
• CPC Class Codes: C08F 297/08 polymerising mono-olefins
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Abstract

Novel polypropylene compositions comprising blends of 85-97wt percent block copolymers of propylene and ethylene with 3-15wt percent linear polyethylene and a process therefor. The compositions exhibit improved impact and low temperature brittleness properties.

Claims

1. A process for the preparation of a binary polypropylene composition having synergistic impact properties which comprises:

1. polymerizing propylene in a slurry in the presence of a catalytic amount of a catalyst formed by admixing a subhalide of a metal selected from the metals of Groups IVa, Va and VIa of the Periodic Table according to Mendeleef and an aluminum compound containing at least one carbon to metal bond to a solids content of 10 to 60 percent by weight to form a polypropylene preblock;

2. removing any volatiles present with said preblock to a level of no more than 5 percent by weight;

3. transferring said preblock while it still contains active catalyst to a continuously agitated reaction zone;

4. introducing ethylene and another α

-olefin having from 3 to 8 carbon atoms to said reaction zone;

5. block copolymerizing said ethylene and other α

-olefin onto said preblock in the vapor phase to form a random copolymer post block having from about 25 to about 75 mole percent ethylene derived units and constituting from about 5 to about 40 percent by weight of the total block copolymer;

6. deashing the block copolymer thus produced;

7. transferring the deashed copolymer to at least one agitated drying zone;

8. introducing a linear polyethylene having a melt index between about 0.5 and about 0.9 and a density of at least 0.93 to the drying zone in an amount corresponding to between about 3 and about 15 percent by weight of the total of the linear polyethylene component and the block copolymer component, and

9. recovering the polypropylene composition from said drying zone.

2. A process according to claim 1, wherein another α

-olefin having from 2 to 8 carbon atoms is copolymerized with the propylene to form a preblock containing no more than 5 mole percent units derived from the other α

-olefin.

3. A process according to claim 1, wherein propylene is the other α

-olefin of steps (4) and (5) and the random copolymer postblock contains from about 30 to about 70 mole percent of ethylene derived units.

4. A process according to claim 1 wherein the linear polyethylene is a polyethylene homopolymer.

5. A process according to claim 1, wherein the drying is carried out in two agitated dryers and the linear polyethylene is added to the second dryer.