Extraction of fat from starch-containing vegetable matter

• US 3,939,281 A
• Filed: 11/09/1973
• Issued: 02/17/1976
• Est. Priority Date: 11/14/1972
• Status: Expired due to Term

• Current Assignee: Studiengesellschaft Kohle MBH
• Original Assignee: Pfeifer & Langen
• Inventors: Schwengers, Dieter
• Primary Examiner(s): Naff, David M.
• Application Number:
  US05/414,495
• Time in Patent Office: 830 Days
• Field of Search: 426/429, 426/430, 426/425, 426/436, 426/16, 426/11, 426/417, 195/31 R
• US Class Current: 426/11
• CPC Class Codes: B01D 11/0203 with a supercritical fluid
• CPC Class Codes: C11B 1/104 using super critical gases or vapours
• CPC Class Codes: Y02P 20/54 using solvents, e.g. supercritical solvents or ionic liquids

Abstract

Fat is removed from starch-containing vegetable material such as cereal grains, potatoes or tapioca by a process involving crushing the vegetable material, contacting the crushed material with a normally gaseous inert solvent under supercritical condition at a temperature of about 20° to 100°C and a pressure of about 30 to 1000 atmospheres to dissolve fat from the vegetable material into the solvent, separating the fat-containing solvent from the resultant substantially fat-free vegetable residue, and separating the dissolved fat from the solvent by raising the temperature and/or lowering the pressure to separate vaporized solvent from the fat. The vaporized solvent may be liquefied and recycled. The fat-free residue may be treated to dissolve away gluten, to form glucose by enzymatic hydrolysis and/or subjected to alcoholic fermentation.

Claims

1. The process for degreasing vegetable matter containing starch and fats which comprises crushing said vegetable matter, extracting the crushed matter with a normally gaseous inert solvent in liquid state at a temperature of about 20°

to 100°

C and below the critical temperature and a pressure of about 30 to 1000 atmospheres and above the critical pressure of the inert solvent which solvent has a critical temperature below about 200°

C, separating the fat-containing solvent from the substantially fatfree vegetable residue, separating the dissolved fat from the solvent by raising the temperature to vaporize the solvent, and reducing the pressure of the fat-free vegetable residue.

2. The process of claim 1, wherein the pressure during extraction is about 40 to 150 atmospheres.

3. The process of claim 1, wherein the vegetable matter comprises freshly harvested cereal.

4. The process of claim 1, wherein the solvent comprises at least one member selected from the group consisting of alkenes, dialkyl ethers, halogenated alkanes, argon, NH₃, N₂, SO₂ and CO₂.

5. The process of claim 4, where the solvent comprises at least two of said members of which one is SO₂ or CO₂.

6. The process of claim 1, including the further steps of grinding the fat-free vegetable residue, mixing the ground residue with at least about twice its weight of water, and separating an aqueous suspension of starch from unsuspended residue.

7. The process of claim 1, including the further steps of soaking the fat-free vegetable residue with about 1.5 to 3 times its weight of water having about 0.1 to 0.2% by weight of SO₂ dissolved therein to dissolve away gluten from the residue, and separating husks and fiber from said residue to leave the raw starch.

8. The process of claim 1, including the further steps of suspending the fat-free vegetable residue in at least about twice its weight of water, adding starch-decomposing enzymes to said suspension thereby to decompose the starch to glucose, and removing the aqueous solution of glucose.

9. The process of claim 1, including the further step of subjecting the fat-free vegetable residue to an alcoholic fermentation.