Method for processing bauxites
First Claim
1. A method for processing goethite-containing bauxite to aluminum hydrate according to the Bayer technology, in which bauxite is digested in sodium hydroxide and the resulting material clarified to remove red mud, with an increased yield of aluminum hydrate and with decreased losses of sodium hydroxide, comprising conducting said digestion at 200°
- to 250°
C. in an aluminate liquor containing Na2 Ocaustic in a concentration of 80 to 300 g./l., and a calcium compound selected from the group consisting of calcium carbonate, calcium oxide, calcium hydroxide and calcium sulfate in an amount corresponding to 2 to 6% by weight of CaO calculated on the dry weight of the bauxite and a sulfate salt selected from the group consisting of sodium sulfate and calcium sulfate in an amount corresponding to 1.0 to 7.0 g./l. of sulfate ion concentration, whereby the goethite content of the bauxite is converted into hematite.
0 Assignments
0 Petitions
Accused Products
Abstract
A method for processing bauxites according to the Bayer technology, with an increased yield in Al2 O3 and with decreased caustic soda losses, starting particularly from goethite bauxites of boehmite and/or diaspore type and carrying out the digestion at 180°C to 300°C using an aluminate liquor containing Na2 Ocaustic in a concentration of 80 to 300 g./l. The digestion is carried out in the presence of a calcium compound in an amount corresponding to 2 to 6 % of CaO calculated for the dry weight of bauxite and of a sulfate salt in an amount corresponding to 1.0 to 7.0 g./l. of sulfate ion concentration, whereby the goethite content of the bauxite is converted into hematite. The process provides advantageous conditions for the complete dissolution of the boehmite and diaspore content of bauxite in the vicinity of the equilibrium molar ratio, and enables to recover efficiently the caustic soda losses in the Bayer process itself, requiring no supplementary operation.
24 Citations
7 Claims
-
1. A method for processing goethite-containing bauxite to aluminum hydrate according to the Bayer technology, in which bauxite is digested in sodium hydroxide and the resulting material clarified to remove red mud, with an increased yield of aluminum hydrate and with decreased losses of sodium hydroxide, comprising conducting said digestion at 200°
- to 250°
C. in an aluminate liquor containing Na2 Ocaustic in a concentration of 80 to 300 g./l., and a calcium compound selected from the group consisting of calcium carbonate, calcium oxide, calcium hydroxide and calcium sulfate in an amount corresponding to 2 to 6% by weight of CaO calculated on the dry weight of the bauxite and a sulfate salt selected from the group consisting of sodium sulfate and calcium sulfate in an amount corresponding to 1.0 to 7.0 g./l. of sulfate ion concentration, whereby the goethite content of the bauxite is converted into hematite. - View Dependent Claims (2, 3)
- to 250°
-
4. A method for processing goethite-containing bauxite to aluminum hydrate according to the Bayer technology, in which bauxite is digested in sodium hydroxide and the resulting material clarified to remove red mud, with an increased yield of aluminum hydrate and with decreased losses of sodium hydroxide, comprising conducting said digestion at 200°
- to 250°
C. in an aluminate liquor containing Na2 Ocaustic in a concentration of 80 to 300 g./l., and calcined lime in an amount corresponding to 2 to 6% by weight of CaO calculated on the dry weight of the bauxite and sodium sulfate in an amount corresponding to 1.0 7.0 g./l. of sulfate ion concentration, whereby the goethite content of the bauxite is converted into hematite. - View Dependent Claims (5, 6, 7)
- to 250°
Specification