Process for "sulfur reduction of an oxidized hydrocarbon by forming a metal-sulfur-containing compound"

• US 3,945,914 A
• Filed: 08/23/1974
• Issued: 03/23/1976
• Est. Priority Date: 08/23/1974
• Status: Expired due to Term

• Current Assignee: Atlantic Richfield Company Incorporated (BP PLC)
• Original Assignee: Atlantic Richfield Company Incorporated (BP PLC)
• Inventors: Voss, Andrew P., Yoo, Jin Sun
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Crasanakis, G. J.
• Application Number:
  US05/499,885
• Time in Patent Office: 578 Days
• Field of Search: 208/189, 208/190, 208/193, 208/196, 208/201, 208/207, 208/243, 208/244, 208/246, 208/247, 208/208 R, 208/240
• US Class Current: 208/208.00R
• CPC Class Codes: C10G 53/14 including at least one oxidation step

Abstract

A process for reducing the sulfur content of hydrocarbon material by oxidizing the sulfur impurities contained in the hydrocarbon material, contacting the oxidized sulfur-containing hydrocarbon material with at least one of certain metal containing components at conditions to form a metal, sulfur-containing compound and recovering a hydrocarbon material of reduced sulfur content.

Claims

1. A process for producing a hydrocarbon material of reduced sulfur content which comprises:

1. contacting a sulfur-containing hydrocarbon material with an oxidant to preferentially oxidize at least a portion of the sulfur and form an oxidized sulfur-containing hydrocarbon material, a major amount of said sulfur-containing hydrocarbon material boils above about 550°

F.;

2. contacting said oxidized sulfur-containing hydrocarbon material with at least one metal or metal-containing compound at a temperature within the range from about 500°

F. to about 1350°

F., to form a metal-sulfur-containing compound, said metal or metal-containing compound comprising a metal selected from the group consisting of nickel, molybdenum, cobalt, tungsten, zinc, vanadium, copper, manganese, mercury and mixtures thereof; and

3. recovering a hydrocarbon material from step (2) of reduced sulfur content.

2. The method of claim 1 wherein said metal or metal-containing compound is present in an amount to provide at least about 0.1 equivalent of said metal capable of chemically combining with sulfur at the conditions of step (2) per equivalent of sulfur in said oxidized sulfur-containing hydrocarbon material.

3. The process of claim 2 wherein said oxidant is selected from the group consisting of organic peroxides, organic hydroperoxides, organic peracids and mixtures thereof containing from 1 to about 30 carbon atoms per active oxygen atom and is present during said contacting in an amount to provide from about 0.5 to about 10 atoms of active oxygen per atom of sulfur in said sulfur-containing material and said step (1) contacting occurs in the presence of an oxidation catalyst comprising a metal in an amount effective to promote the oxidation of sulfur, said metal being selected from the group consisting of Group IVB metals, Group VB metals, Group VIB metals and mixtures thereof.

4. The method of claim 3 wherein said contacting of step (2) occurs at a temperature within the range from about 650°

F. to about 1000°

F.

5. The process of claim 4 wherein said contacting of step (2) occurs over a period of time from about 5 minutes to about 20 hours.

6. The process of claim 5 wherein said oxidation catalyst comprises a metal selected from the group consisting of titanium, zirconium, vanadium, tantalum, chromium, molybdenum, tungsten and mixtures thereof and is present in an amount of at least about 5 ppm. by weight of said sulfur-containing hydrocarbon material.

7. The process of claim 6 wherein said metal or metal-containing compound comprises a metal selected from the group consisting of molybdenum, cobalt, tungsten, vanadium and mixtures thereof, and is present in an amount from about 0.5 to about 15 equivalent of said metal capable of chemically combining with sulfur at the conditions of step (2) per equivalent of sulfur in said oxidized sulfur-containing hydrocarbon material.

8. The process of claim 7 wherein said oxidation catalyst comprises molybdenum.

9. The process of claim 7 wherein said metal or metal-containing compound comprises molybdenum.

10. The process of claim 8 wherein said oxidation catalyst is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at least one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.

11. The process of claim 10 wherein said metal or metal-containing compound is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at leaast one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.

12. The process of claim 9 wherein said oxidation catalyst is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at least one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.

13. The process of claim 12 wherein said metal or metal-containing compound is prepared by a method which comprises interacting molybdenum metal with a compound selected from the group consisting of organic hydroperoxide, organic peroxide, hydrogen peroxide and mixtures thereof in the presence of at least one saturated alcohol having from one to four carbon atoms per molecule at conditions such that at least a portion of said molybdenum is solubilized.

14. The process of claim 13 wherein said contacting of step (2) occurs at a temperature within the range from about 700°

F. to about 850°

F. and for a period of time from about 30 minutes to about 2 hours.