Fuel for generation of nontoxic propellant gases

• US 3,947,300 A
• Filed: 07/09/1973
• Issued: 03/30/1976
• Est. Priority Date: 07/24/1972
• Status: Expired due to Term

• Current Assignee: Bayern-Chemie
• Original Assignee: Bayern-Chemie
• Inventors: Hubel, Roland, Passauer, Hermann
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US05/377,325
• Time in Patent Office: 995 Days
• Field of Search: 149/35, 149/61, 149/77
• US Class Current: 149/35
• CPC Class Codes: B01J 7/00 Apparatus for generating gases production of inert gas mixtures B01J19/14; for generating specific gases, see the relevant subclasses, e.g. C01B, C10J ; in "air bags" on vehicles B60R21/26; for starter gas F02C7/26; blasting cartridges for producing gas under pressure F42B3/04
• CPC Class Codes: C06B 23/001 Fillers, gelling and thickening agents (e.g. fibres) , absorbents for nitroglycerine binders, plasticisers for propellants C06B45/10; crosslinking or curing agents C06B45/10
• CPC Class Codes: C06B 35/00 Compositions containing a metal azide
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A propellant composition for the generation of nontoxic propellant gases suitable for the inflation of air cushion protective devices for passengers in motor vehicles comprises mixtures of (a) at least one stable metal azide, (b) at least one oxidant metal compound, and (c) silicon dioxide.

Claims

1. A propellant composition for the generation of non-toxic propellant gases suitable for the inflation of air cushion protective devices for passengers in motor vehicles comprising mixtures of (a) at least one stable metal azide selected from the group consisting of alkali metal azides and alkaline earth metal azides, (b) at least one oxidant metal compound capable of absorbing electrons during reaction with said at least one metal azide, and (c) silicon dioxide, the total metal ion ratio relative to the metal oxides developed during the combustion assuring the formation of glasslike silicates having as low as possible a melting point or softening point, the ratio of a:

b;

c being from 5;

1;

2 to 10;

1;

5.

2. The composition of claim 1, in which the mol ratio of said azide of (a) to said oxidant of (b) to said silicon dioxide of (c) is essentially stoichiometric.

3. The composition of claim 1, in which the metal of said oxidant compound is selected from the group consisting of alkali metals and alkaline earth metals.

4. The composition of claim 1, which further comprises glass flux promoting metal oxides.

5. The composition of claim 1, in which the silicon dioxide of (c) is at least partially replaced by at least one other acid reacting metal oxide compound which forms glasslike melts selected from the group consisting of boric oxide and alkali metal metaphosphates.

6. The composition of claim 1 wherein the oxidant is selected from the group consisting of chlorates, nitrates, chromates and peroxides.