Method for rapidly melting and refining glass

• US 3,951,635 A
• Filed: 11/29/1974
• Issued: 04/20/1976
• Est. Priority Date: 11/29/1974
• Status: Expired due to Term

• Current Assignee: Owens-Illinois Glass Container, Inc. (O-I Glass, Inc.)
• Original Assignee: Owens-Illinois Incorporated (O-I Glass, Inc.)
• Inventors: Rough, Robert R. Sr.
• Primary Examiner(s): Bashore, S. Leon
• Assistant Examiner(s): Miga, Frank W.
• Application Number:
  US05/528,031
• Time in Patent Office: 508 Days
• Field of Search: 65/134, 65/180, 65/179, 65/135, 65/136, 65/178, 65/347
• US Class Current: 65/134.9
• CPC Class Codes: C03B 3/005 using screw feeders
• CPC Class Codes: C03B 5/00 Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
• CPC Class Codes: C03B 5/027 by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
• CPC Class Codes: C03B 5/1875 of the screw or pump-action type
• CPC Class Codes: C03B 5/225 Refining C03B5/18 takes precedence ; Refining agents C03C1/004
• CPC Class Codes: C03B 5/2255 by centrifuging

Abstract

In accordance with the method and apparatus of this invention, glass-forming materials are subjected to heat and agitation sufficient to form a molten glass having mostly dissolved glass-forming materials, mostly completed chemical reactions between the glass-forming materials and containing a high number of gaseous inclusions, and containing up to 50 volume percent entrapped gases. This glass appears foamy. The molten glass is transferred to a second chamber to complete melting of any unmelted sand grains remaining from the glass-forming materials, and completes the chemical reactions that remain incompleted, and to remove any remaining cords, and to reduce the foamy character of the melt to a dense molten glass which contains only small-sized gaseous inclusions. This molten glass is then subjected to centrifugal forces sufficient to remove the small-sized gaseous inclusions and thereby produce a refined molten glass having a desired quality of homogeneity and both a reduced number and a different size distribution of gaseous inclusions.

Claims

1. A method of making glass which comprises applying heat to glass-forming materials to produce a mass of molten glass;

a. adding glass-forming materials to said mass of molten glass;

b. agitating the mixture of glass-forming materials and molten glass while applying heat to said mixture;

c. continuing the adding, mixing, agitation and application of heat for a time such as to disperse the materials rapidly and uniformly in the mass of molten glass, thus facilitating transfer of heat to the materials and promote rapid chemical reactions until a molten glass is produced which has some small amount of undissolved glass-forming materials, cords, and incompleted chemical reactions between the glassforming materials and contains gaseous inclusions, said molten glass mixture having a foamy appearance due to the gaseous inclusions therein;

d. transferring said foamy glass mixture to a chamber containing a pool of molten glass at an elevated temperature;

e. dispersing said foamy glass over the surface of said molten pool of glass;

f. subjecting said foamy glass to heat both from the pool of glass and from above, whereby said foamy glass gives up the gaseous inclusions and becomes part of the pool of glass, and thereafter rotating the homogenized molten glass containing gaseous inclusions in a centrifugal refining apparatus, and continuing the rotation for a time and at a speed such as to produce pressure gradients within the glass to cause gaseous inclusions to migrate out of the glass, thereby producing a refined molten glass having a controlled number of gaseous inclusions.