Regeneration apparatus

• US 3,953,175 A
• Filed: 12/28/1973
• Issued: 04/27/1976
• Est. Priority Date: 12/28/1973
• Status: Expired due to Term

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: Universal Oil Products Company (Honeywell International Inc.)
• Inventors: Pulak, Richard P.
• Primary Examiner(s): Scovronek, Joseph
• Application Number:
  US05/429,422
• Time in Patent Office: 851 Days
• Field of Search: 23/288 B, 23/288 S, 23/288 E, 252/417, 208/164
• US Class Current: 422/144
• CPC Class Codes: B01J 8/26 with two or more fluidised beds, e.g. reactor and regeneration installations
• CPC Class Codes: C10G 11/182 Regeneration
• CPC Class Codes: Y02P 30/40 Ethylene production

Abstract

The apparatus comprises in combination and particular arrangement a spent-catalyst receiving chamber for containing a dense-bed of fluidized catalyst in which chamber spent catalyst is oxidized to produce regenerated catalyst and partially spent regeneration gas; a transfer conduit through which said gas and said catalyst pass and in which carbon monoxide is essentially completely converted to carbon dioxide to produce spent regeneration gas and regenerated catalyst at an increased temperature; a regenerated-catalyst receiving chamber for containing a dense-bed of regenerated catalyst and in which spent regeneration gas and regenerated catalyst are separated; and, a regenerated-catalyst recycle means by which hot regenerated catalyst can be recycled within the apparatus from the regenerated-catalyst receiving chamber to the spent-catalyst receiving chamber in amounts to control the temperature and hence the rate of coke oxidation in the spent-catalyst receiving chamber. Residual coke on regenerated catalyst can therefore be significantly reduced or controlled to low levels as desired. The CO burning rate in the transfer conduit is also increased because of the higher inlet temperature and the CO concentration in the spent regeneration gas leaving the apparatus is therefore reduced.

A particularly novel feature of my invention is the arrangement of its components which permits most existing single-vessel regeneration apparatus, in which coke is generally not oxidized at a controllable temperature and in which CO is not essentially completely converted to CO₂, to be incorporated into my regeneration apparatus.

Claims

1. An apparatus for oxidizing coke on spent catalyst which comprises in combination:

a. a spent-catalyst receiving chamber for containing a dense-phase fluidized bed of catalyst having a spent catalyst inlet means and a fresh-regeneration gas inlet means connected thereto to allow passage of spent catalyst and fresh regeneration gas respectively into said chamber and having a regenerated-catalyst/regeneration-gas outlet means connected thereto to allow passage of regenerated catalyst and regeneration gas from said chamber;

b. a transfer conduit positioned above said spent-catalyst receiving chamber and having a substantially vertical portion and a substantially horizontal portion in interconnection with said vertical portion, said vertical portion extending above said horizontal portion and having an inlet connected to the regenerated-catalyst/regeneration-gas outlet means and said horizontal portion extending into the side of a hereinafter described regenerated-catalyst receiving chamber and being provided with an outlet means into said chamber whereby regenerated catalyst and regeneration gas are carried from said spent-catalyst receiving chamber in admixture to said regenerated-catalyst receiving chamber, said portions of said transfer conduit being of sufficient internal volume to permit substantially complete CO oxidation and transfer of the heat of combustion to said catalyst therein, said transfer conduit having a combustible fluid inlet means to allow passage of combustible fluid into said conduit and having connected thereto a fresh regeneration gas inlet means to allow passage of fresh regeneration gas into said conduit;

c. a regenerated-catalyst receiving chamber for containing a dense-phase bed of regenerated catalyst, said chamber having a regenerated-catalyst outlet means and a spent-regeneration-gas outlet means connected thereto to allow passage of regenerated catalyst and spent regeneration gas from said chamber and said chamber being positioned adjacent to and at an elevation above said spent-catalyst receiving chamber sufficient to maintain at least a portion of said dense-phase bed of regenerated catalyst above said dense-phase fluidized bed of catalyst in said spent-catalyst receiving chamber; and

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d. a regenerated-catalyst recycle means to allow passage of regenerated catalyst directly from the regenerated-catalyst receiving chamber to the spent-catalyst receiving chamber.

2. The apparatus of claim 1 further characterized in that said outlet of said transfer conduit is in communication with a disengaging space provided to separate catalyst and regeneration gas passing through said conduit.

3. The apparatus of claim 1 further characterized in that said regenerated-catalyst receiving chamber has a regenerated-catalyst stripper located in the bottom portion thereof to strip regenerated catalyst.

4. The apparatus of claim 3 further characterized in that said stripper is concentric with said regenerated-catalyst receiving chamber.

5. The apparatus of claim 1 further characterized in that said regenerated-catalyst recycle means is an external regenerated-catalyst recycle means.

6. The apparatus of claim 5 further characterized in that said external regenerated-catalyst recycle means comprises at least one conduit having a flow regulating means located thereon.

7. An apparatus for oxidizing coke on spent catalyst which comprises in combination:

a. a spent-catalyst receiving chamber for containing a dense-phase fluidized bed of catalyst, said chamber having upper and lower sections, a fresh-regeneration-gas inlet means connected to said chamber at said lower section to allow passage of fresh regeneration gas into said chamber through said lower section, a spent-catalyst inlet means connected to said chamber to allow passage of spent catalyst into said chamber, and a regenerated-catalyst/regeneration-gas outlet means at the upper section of said chamber to allow passage of regenerated catalyst and regeneration gas in admixture from said chamber;

b. a transfer conduit positioned above said spent catalyst receiving chamber and having a substantially vertical portion and a substantially horizontal portion in interconnection with said vertical portion, said vertical portion extending above said horizontal portion and having an inlet for regenerated catalyst and regeneration gas connected to the regenerated-catalyst regeneration-gas outlet means, said horizontal portion extending into the side of a hereinafter described regenerated-catalyst receiving chamber and having an outlet means within said chamber in communication with a disengaging space whereby regenerated catalyst and regeneration-gas are carried in admixture from said spent-catalyst receiving chamber to said disengaging space, said portions of said transfer conduit being of sufficient internal volume to permit substantially complete CO oxidation and transfer of the heat of combustion to said catalyst therein, said transfer conduit having a combustible fluid inlet means to allow passage of combustible fluid into said conduit and having connected thereto a fresh regeneration gas inlet means to allow passage of fresh regeneration gas into said conduit;

c. a regeneration-catalyst receiving chamber for containing a dense-phase bed of regenerated catalyst, said chamber being positioned adjacent to and at an elevation above said spent-catalyst receiving chamber to thereby maintain at least a portion of said bed of regenerated catalyst above said dense-bed fluidized bed of catalyst in the spent-catalyst receiving chamber, said regenerated-catalyst receiving chamber having upper and lower sections, a spent-regeneration-gas outlet means connected to said chamber at its upper section to allow passage of spent regeneration gas from said chamber, and a regenerated catalyst stripper within said chamber at its lower section to strip regenerated catalyst, said stripper having connected to its outlet a regenerated-catalyst outlet means to allow passage of regenerated catalyst from the stripper; and

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d. an external regenerated-catalyst recycle means comprising at least one conduit having a flow regulating means located thereon to allow passage of regenerated catalyst from the dense bed of regenerated catalyst in the regenerated-catalyst receiving chamber to the dense-phase fluidized bed of catalyst in the spent-catalyst receiving chamber.

8. The apparatus of claim 7 further characterized in that said regenerated catalyst stripper is concentric with said regenerated-catalyst receiving chamber.