Pressure exponent suppressants

• US 3,953,259 A
• Filed: 09/01/1970
• Issued: 04/27/1976
• Est. Priority Date: 09/01/1970
• Status: Expired due to Term

• Current Assignee: United States Of America As Represented By The Secretary Of The Army (Government of the United States of America)
• Original Assignee: The United States Of America As Represented By The Secretary Of The Army
• Inventors: Sayles, David C.
• Primary Examiner(s): Sebastian, Leland A.
• Assistant Examiner(s): Walsh, Donald P.
• Application Number:
  US05/078,332
• Time in Patent Office: 2,065 Days
• Field of Search: 149/92, 149/105, 149/19, 149/20, 149/19.5, 149/19.6, 149/108.2, 149/76
• US Class Current: 149/19.5
• CPC Class Codes: C06B 25/04 the nitrated compound being an aromatic
• CPC Class Codes: C06B 45/10 the organic component containing a resin

Abstract

The use of certain chemical constituents, such as hexanitrostilbene, triaotrinitrobenzene, picric acid and the ammonium salt of picric acid, which can be incorporated into propellant compositions which have high pressure exponents to reduce them to acceptable values. The propellant compositions generally include a binder, a curing agent, oxidizer ingredients, and other additives which depend upon the specific structure of a particular propellant formulation.

Claims

1. A propellant composition comprising;

a binder present in an amount of about 4 to about 20 weight percent, an oxidizer present in an amount of about 50 to about 80 weight percent, a pressure exponent suppressant selected from the group consisting of hexanitrostilbene, triaminotrinitrobenzene, picric acid and the ammonium salt of picric acid and a curing agent, said pressure exponent suppressant being present in an amount of about 1 to about 20 weight percent of the propellant composition.

2. The propellant composition of claim 1, wherein said oxidizer includes an inorganic oxidizer.

3. The propellant composition of claim 1, wherein said composition additionally contains a plasticizer present in an amount of about 20 to about 35 weight percent.

4. The propellant composition of claim 3, wherein said binder is an acrylate-acrylic acid copolymer, said oxidizer includes the oxidizing ingredient cyclotetramethylenetetranitroamine, and said pressure exponent suppressant is hexanitrostilbene.

5. The propellant composition of claim 4 wherein said composition additionally contains the oxidizer-ammonium perchlorate.

6. The propellant composition of claim 4, wherein said composition further contains the additive-carbon black.

7. The propellant composition of claim 4, wherein said cyclotetramethylenetetranitroamine is present in an amount of about 50 weight percent of said composition;

said binder is present in an amount of about 5 weight percent of said composition;

said plasticizer is present in an amount of about 25 weight percent of said composition; and

said pressure exponent suppressant is present in an amount of about 20 weight percent of said propellant composition.

8. The propellant composition of claim 7, wherein said composition contains the additional ingredients carbon black, and said carbon black and curing agent are present in said composition as additives to all the other composition ingredients, said carbon black being present in an amount of about 0.5 weight percent and said curing agent being present in an amount of about 1.0 weight percent.

9. The propellant composition of claim 8, wherein said curing agent is 4,5-epoxycyclohexylmethyl 4'"'"',5'"'"'-epoxycyclohexylcarboxylate.

10. The propellant composition of claim 1, wherein said pressure exponent suppressant is incorporated in said composition in an amount of about 1 to 5 weight percent.