Method of simultaneous concentration and dilution of isotopes

• US 3,953,568 A
• Filed: 07/17/1972
• Issued: 04/27/1976
• Est. Priority Date: 07/22/1971
• Status: Expired due to Term

• Current Assignee: Hidetake Kakihana, Maomi Seko
• Original Assignee: Hidetake Kakihana, Maomi Seko
• Inventors: Seko, Maomi, Kakihana, Hidetake
• Primary Examiner(s): Padgett, Benjamin R.
• Assistant Examiner(s): Miller, E. A.
• Application Number:
  US05/272,250
• Time in Patent Office: 1,380 Days
• Field of Search: 423/2, 423/6, 423/7, 423/139, 423/181, 423/298, 423/351, 423/414, 423/276, 423/157, 252/301.1 R, 210/31 C
• US Class Current: 423/7
• CPC Class Codes: B01D 59/30 by ion exchange
• CPC Class Codes: C22B 60/0265 extraction by solid resins
• CPC Class Codes: Y10S 423/07 Isotope separation
• CPC Class Codes: Y10S 423/14 Ion exchange; chelation or liquid/liquid ion extraction

Abstract

A method of simultaneously obtaining separate enriched fractions of heavier and lighter isotopes from mixtures thereof with the use of an ion exchange resin column by passing a ligand body containing this isotope mixture through the column. The isotopes, as they are passed through the column, are present in the forms of ligand-containing coordination compounds having different valence states and are followed by an eluant and form a band which travels through the column, the front and rear portions of which are respectively enriched in one of the isotopes and depleted in the other.

Claims

1. Method of simultaneously obtaining separate enriched fractions of heavier and lighter isotopes from isotopic mixtures thereof, which comprises establishing a liquid body containing a mixture in which the isotopes are in the form of coordination complexes of a metal with a ligand, said complexes being present in a plurality of different valent states, alternately passing through a highly cross-linked porous ion exchange resin said body and then an eluant but not a regenerant, thereby forming a plurality of spaced apart isotope-containing bands each about 2 to 1000 cm in width, and as each isotope-containing band leaves the resin collecting it in at least three fractions, the intermediate fraction having approximately the isotope composition of the starting liquid body, and one of the first and last fractions being selectively enriched in the heavier isotope and the other being selectively enriched in the lighter isotope.

2. Method according to claim 1, in which said isotope is selected from the group consisting of metals which after forming said coordination complexes have a rare gas structure and a valence of at least 2, and transition metals having electron vacancies in the d-sub shell or outer shell.

3. Method according to claim 1, wherein said metal of said coordination complex is present in only one valence state, the ligand providing for the plurality of different valent states of said complexes.

4. Method according to claim 1, in which said isotopes constitute a part of said ligand which is in a coordination complex with said metal.

5. Method according to claim 1, in which said coordination complex is formed in situ with ligands obtained from at least one of said eluant and adsorbate on said ion exchange resin.

6. Method according to claim 5, in which said ion exchange resin is equilibrated with the ligand solution and in which said eluant is an electrolyte solution formed from an electrolyte different from said ligand complex.

7. Method according to claim 4, in which said eluant is passed through said column at a substantially higher flow velocity than the flow velocity of the bands of said isotope-containing coordination complex.

8. Method according to claim 1, in which said ion exchange resin is equilibrated with the ligand solution and in which said eluant is an electrolyte solution containing not more than a minor molar percentage of said ligand.

9. Method according to claim 1, in which said eluant comprises an electrolyte solution of a compound of said ligand.

10. Method according to claim 1, in which said ion exchange resin is an anion exchange resin and in which said eluant is water.

11. Method according to claim 1, in which said ligand comprises a sulfuric acid group and in which said ion exchange resin is a cation exchange resin.

12. Method according to claim 1, in which said ion exchange resin has a member selected from the group consisting of sulfonic acid and carboxylic acid ion exchange groups.

13. Method according to claim 1, in which said isotope is selected from the group consisting of lithium, boron, carbon, nitrogen, nickel, oxygen, sulfur and phosphorus.

14. Method according to claim 1, in which the eluaant comprises a solution of a mineral acid, an organic acid, a salt or an electrolyte.

15. Method according to claim 1, in which a plurality of successive ion exchange columns are provided, a middle fraction of the effluent also being collected, at least one of the enriched or depleted fractions being advanced to a subsequent ion exchange column and the middle fraction being recycled as feed to an ion exchange column whose feed has substantially the same isotope ratio.

16. Method according to claim 1, in which said ion exchange resin is enclosed by a high polymer film having the same charge as the ion exchange group of the resin.

17. Method according to claim 1, in which the ion exchange groups of the resin are no more than about 0.15 mm from the surface of the resin, the groups being present to the extent of about 1 to 10 milliequivalents per gram of dry resin in the portion carrying such groups.

18. Method according to claim 17, in which the resin comprises a copolymer of a monoolefin and a diolefin, the diolefin constituting about 5 to 50 percent of the copolymer, said copolymer having been aftertreated to provide ion exchange groups thereon.