Liquid hydroxy-terminated polyesters
First Claim
1. Substantially primarily hydroxyl terminated linear and branched polyester polyols which remain liquid at ambient temperature prepared by the process which comprises simultaneously and substantially completely reacting:
- i. e-caprolactone, 6-hydroxycaproic acid, a lower oligomer of 6-hydroxycaproic acid or mixture of the foregoing in an amount sufficient to provide from about 25 to 70 percent by weight of the oxycaproyl unit ##EQU4## ii. at least one dicarboxylic acid or dicarboxylic acid anhydride selected from the group consisting of adipic acid, succinic acid, glutaric acid, sebacic acid, pimelic acid and azelaic acid, their anhydrides and mixtures thereof; and
iii. at least two different glycols selected from the group consisting of ethylene glycol, 1,3-propanediol, 1,4-butanediol and 1,5-pentanediol, the molar ratio of the glycols being in the range of from about 1/3 to about 3.
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Accused Products
Abstract
Solid and microcellular polyurethane elastomers prepared by reacting (a) liquid polyesters containing from about 25 percent by weight to about 70 percent by weight of the epsilon-oxycaproyl unit, the balance of the polyester being derived from the reaction of at least one dicarboxylic acid with at least two glycols selected from the group consisting of ethylene glycol 1,3-propanediol, 1,4-butanediol and 1,5-pentanediol, (b) an organic polyisocyanate, and optionally (c) a chain-extender comprising water, glycols, amino alcohols, or diamines. If the liquid polyester (a) is branched, for example, by addition of small quantities of a triol, the reaction with the organic polyisocyanate may be conducted in the absence of a chain-extender. Processes for producing these elastomers are also disclosed.
Novel liquid, substantially primary hydroxyl-terminated, linear and branched polyesters containing from about 25 percent by weight to as much as about 70 percent by weight of the epsilonoxycaproyl unit ##EQU1## the balance of the polyester being derived from the reaction of at least one dicarboxylic acid with at least two straight chain glycols selected from the group consisting of ethylene glycol, 1,3-propanediol, 1,4-butanediol and 1,5-pentanediol. These polyesters have a true melting point no higher than about 30°C. Also provided are processes for producing these polyesters.
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Citations
5 Claims
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1. Substantially primarily hydroxyl terminated linear and branched polyester polyols which remain liquid at ambient temperature prepared by the process which comprises simultaneously and substantially completely reacting:
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i. e-caprolactone, 6-hydroxycaproic acid, a lower oligomer of 6-hydroxycaproic acid or mixture of the foregoing in an amount sufficient to provide from about 25 to 70 percent by weight of the oxycaproyl unit ##EQU4## ii. at least one dicarboxylic acid or dicarboxylic acid anhydride selected from the group consisting of adipic acid, succinic acid, glutaric acid, sebacic acid, pimelic acid and azelaic acid, their anhydrides and mixtures thereof; and iii. at least two different glycols selected from the group consisting of ethylene glycol, 1,3-propanediol, 1,4-butanediol and 1,5-pentanediol, the molar ratio of the glycols being in the range of from about 1/3 to about 3. - View Dependent Claims (2, 3, 4, 5)
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Specification