Exhaust gas analyzer having pressure and temperature compensation

• US 3,958,122 A
• Filed: 12/19/1974
• Issued: 05/18/1976
• Est. Priority Date: 12/19/1974
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Cross, Thomas A., Jowett, Terence W., Knights, Anthony D. M.
• Primary Examiner(s): Borchelt, Archie R.
• Assistant Examiner(s): Anderson, B. C.
• Application Number:
  US05/534,493
• Time in Patent Office: 516 Days
• Field of Search: 250/343, 250/344, 250/345, 250/346
• US Class Current: 250/346
• CPC Class Codes: G01M 15/108 using optical methods
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis

Abstract

The contaminants in the exhaust gas emissions from a motor vehicle such as carbon monoxide (CO) and hydrocarbons (HC) are analyzed and the concentration of the contaminants together with other pertinent data is displayed in a digital manner. The exhaust gas emissions are fed into a sample cell contained within a nondispersive infrared analyzer and the absorption of an infrared radiation beam at selected wavelengths by the gas within the cell is measured. A reference cell containing a reference gas is also positioned in the infrared radiation beam path. By means of a rotating chopper disk positioned in the light path, the infrared radiation beam passes alternately through the reference cell and the sample cell and is focused at a plurality of detectors which are each sensitized to a narrow wave band by a filter and which receive the alternate sample cell and reference cell radiation pulses. Synchronization of the system is provided by a notch in the chopper disk which passes alternately between three light sources and associated photoresponsive devices. Automatic span correction is obtained by an automatic gain control circuit which maintains the reference cell output at a predetermined amplitude. The sample cell is initially filled with ambient air by a gas transport system. By measuring the sample cell and reference cell outputs with ambient air in the sample cell, and then measuring the sample cell and reference cell outputs with exhaust gas in the sample cell, a ratio can be computed which is proportional to the amount of the contaminant. Computation of the ratio in this manner results in automatic zeroing and spanning of the system. The computed ratio is then calibrated for nonlinearities in the system, and linear corrections are made for variations in ambient pressure and for variations in the temperature of the gas passing through the sample tube. Provision is also made for assuring that the vehicle being tested has achieved a predetermined engine speed and that no blockage has occurred in the gas transport system when the measurements are made. After the exhaust gas has been analyzed it is replaced in the sample cell with ambient air to prevent contamination of the system optics from the exhaust gas. A sapphire window is positioned in front of the infrared source to reduce changes in source temperature by air currents produced by the rotating chopper disk.

Claims

1. A gas analysis system for measuring the amount of a selected contaminant in a sample gas comprising

means for generating a beam of infrared radiation,

a sample cell adapted to contain a gas,

means for passing a sample gas through said sample cell,

a reference cell containing a reference gas,

means for passing said beam alternately through said sample cell and said reference cell,

detector means responsive to said beam and producing respectively first and second electrical signals respectively indicative of the absorption of said beam by the selected contaminant within said cells,

means responsive to said first and second signals for computing an output signal indicative of the amount of said selected gas contaminant in said sample gas,

means for measuring the temperature of said sample gas and producing a gas temperature signal indicative thereof,

means for producing a pressure signal indicative of the ambient pressure,

and compensation means responsive to said gas temperature signal and said pressure signal for correcting said output signal.

2. A gas analysis system as in claim 1 in which said sample cell has an inlet port and an outlet port,

said means for measuring the temperature of said sample gas including a thermistor located in the output port of said sample cell.

3. A gas analysis system as in claim 1 in which said means for producing a pressure signal comprises a pressure sensor responsive to ambient pressure.

4. A gas analysis system as in claim 1 in which said selected contaminant is carbon monoxide, and said compensation means includes means for multiplying said output signal by the relationship [K₁ + K₂ T_G - K₃ P_A ] where T_G is said gas temperature signal and is indicative of the temperature of said gas in degree centigrade, P_A is said pressure signal and is indicative of ambient pressure in millimeters of mercury, and K₁, K₂ and K₃ are constants.

5. A gas analysis system as in claim 1 in which said selected contaminant is a hydrocarbon, and said compensation means includes means for multiplying said output signal by the relationship [K₁ + K₂ T_G - K₃ P_A ] where T_G is said gas temperature signal and is indicative of the temperature of said gas in degrees centigrade, P_A is said pressure signal and is indicative of ambient pressure in millimeters of mercury, and K₁, K₂ and K₃ are constants.

6. A gas analysis system as in claim 1 and including means for sampling the exhaust gas from a motor vehicle to produce said sample gas.

7. A gas analysis system as in claim 1 in which said compensation means includes a digital computer.

8. A gas analysis system as in claim 1 in which said compensation means includes scaling amplifier means responsive to said gas temperature and pressure signals.

9. A method for measuring the amount of a selected contaminant in a gas sample comprising

filling a sample cell with a sample gas,

generating a rotating beam of infrared radiation,

passing said beam of radiation alternately through said sample cell and a reference cell which contains a reference gas,

measuring the absorption of said infrared beam by a selected contaminant in the gases contained within said sample and reference cells and producing electrical signals indicative thereof,

computing from said electrical signals an output signal indicative of the amount of said contaminant in the sample gas,

and compensating said output signal as a function of the temperature of said sample gas and as a function of ambient pressure.

10. A method as in claim 9 in which said selected contaminant is carbon monoxide, and in which the step of compensating said output signal includes the steps of

measuring the temperature of said sample gas and producing a gas temperature signal T_G indicative thereof,

measuring the ambient pressure and producing a pressure signal T_A indicative thereof,

12. A method as in claim 9 in which said selected contaminant is a hydrocarbon, and in which the step of compensating said output signal includes the steps of

measuring the temperature of said sample gas and producing a gas temperature signal T_G indicative thereof,

measuring the ambient pressure and producing a pressure signal T_A indicative thereof,

computing a correction signal according to the relationship [K₁ + K₂ T_G - K₃ P_A ] where K₁, K₂ and K₃ are constants,

and multiplying said output signal by said correction signal.

11. computing a correction signal according to the relationship [K₁ + K₂ T_G - K₃ P_A ] where K₁, K₂ and K₃ are constants,

and multiplying said output signal by said correction signal.