Process for the preparation of a bisphenol bischlorocarbonic acid ester

• US 3,959,335 A
• Filed: 03/04/1975
• Issued: 05/25/1976
• Est. Priority Date: 03/06/1974
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Hucks, Uwe, Vernaleken, Hugo, Lenz, Gunther, Weirauch, Kurt
• Primary Examiner(s): Brust, Joseph Paul
• Application Number:
  US05/555,149
• Time in Patent Office: 448 Days
• Field of Search: 260/463
• US Class Current: 558/281
• CPC Class Codes: C07C 317/00 Sulfones; Sulfoxides
• CPC Class Codes: C07C 323/00 Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
• CPC Class Codes: C07C 68/02 from phosgene or haloformates
• CPC Class Codes: C07C 69/96 Esters of carbonic or haloformic acids
• CPC Class Codes: C08G 64/04 Aromatic polycarbonates
• CPC Class Codes: C08G 64/24 and phenols

Abstract

A continuous process for the production of a bisphenol bischlorocarbonic acid ester wherein an aqueous solution of a dialkali metal salt of a hydroquinone or a bisphenol is reacted in a pump circulating system with 2.5 to 5.0 mol, per mol of dihydroxy compound of phosgene dissolved in a suitable solvent for the bischlorocarbonic acid ester formed in the reaction under the addition of an alkali metal hydroxide solution to keep the pH-value between 9.0 and 12.0, the organic phase obtained is separated wherefrom the bisphenol bischlorocarbonic acid ester is isolated by distillation and/or crystallisation.

Claims

1. A process for the continuous production of bisphenol bischlorocarbonic acid esters which comprises feeding a reaction mixture containing an aqueous dialkali metal salt solution of a hydroquinone or of an aromatic dihydroxy compound of the formula ##SPC3##

wherein X is alkylene or alkylidene having 1 to 6 carbon atoms, cycloalkylene or cycloalkylidene having 5 to 15 carbon atoms, O, S, SO₂ or ##SPC4##

and R¹ and R², which may be the same or different, are alkyl having 1 to 4 carbon atoms, chlorine or bromine and containing 2.5-5.0 mol per mol of dihydroxy compound of phosgene dissolved in a water immiscible solvent for the bischlorocarbonic ester product into a pump circulation reactor including a delivery pump on the upstream side of the delivery pump, delaying an interval of at least 1 second after commencing said feeding and then introducing into said reaction mixture, as the sole acid neutralizing agent for acid byproduct, an alkali metal hydroxide solution at a rate to maintain the pH value of the reaction mixture between 9.0 and 12.0, maintaining the reaction mixture in said pump circulation reactor for a dwell time of up to 12 minutes and at a Reynolds number greater than 2,000, separating the organic phase from the resulting reaction mixture and recovering bisphenol bischlorocarbonic acid ester therefrom by distillation, crystallization or a combination thereof.

2. A process according to claim 1, wherein the dialkali metal salt solution used is the disodium or dipotassium salt solution of bisphenol A, tetrachlorobisphenol A, tetrabromobisphenol A and tetramethyl bisphenol A.

3. A process according to claim 1, wherein a 5-30 % by weight dialkali metal salt solution is used.

4. A process according to claim 1, wherein the phosgene is dissolved in an aromatic hydrocarbon or in a halogenated hydrocarbon.

5. A process according to claim 4, wherein the phosgene solvent used is methylene chloride, chloroform, 1,2-dichloroethane or chlorobenzene.

6. A process according to claim 1, wherein the reaction is carried out at 0°

to 50°

C.