Method for the electrolytic production of alkali

• US 3,963,592 A
• Filed: 09/30/1974
• Issued: 06/15/1976
• Est. Priority Date: 09/29/1972
• Status: Expired due to Term

• Current Assignee: Occidental Chemical Corporation (Occidental Petroleum Corporation)
• Original Assignee: Hooker Chemicals & Plastics Corp.
• Inventors: Lindstrom, Olle
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US05/510,210
• Time in Patent Office: 624 Days
• Field of Search: 204/103, 204/98, 204/128, 204/129, 204/292, 136/86 F
• US Class Current: 205/512
• CPC Class Codes: C25B 1/16 Hydroxides by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 11/04 characterised by the material
• CPC Class Codes: C25B 9/70 Assemblies comprising two or more cells

Abstract

A method whereby an alkali, such as an alkali metal hydroxide, is produced at the cathode by the electrolysis of aqueous alkali metal halide solutions and the process is operated to produce either chlorine or HCl at the anode.

Claims

1. In the process for electrolyzing an aqueous solution of an alkali metal chloride to form an alkali metal hydroxide at the cathode and chlorine at the anode by the oxidation of chloride ions in the anolyte, the improvement which comprises introducing hydrogen gas at the anode, preferentially anodically oxidizing said hydrogen gas in the presence of a catalyst to hydrogen ions by passing said hydrogen gas through a porous anode containing the catalyst into the anolyte and reacting the thus-formed hydrogen ions with the chloride ions in the anolyte, the porous anode through which the hydrogen gas is passed being formed in two layers, said first layer being a porous sintered coarse layer of platinized titanium and said second layer being a porous sintered finer layer of titanium, the hydrogen gas being passed initially through said first layer and then through said second layer into the anolyte.

2. The process as claimed in claim 1 wherein the hydrogen gas introduced at the anode is at least partially supplied by hydrogen gas formed at the cathode.