Fuel cell cooling system using a non-dielectric coolant

• US 3,969,145 A
• Filed: 07/21/1975
• Issued: 07/13/1976
• Est. Priority Date: 07/21/1975
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Gelting, Raymond L., Grevstad, Paul E.
• Primary Examiner(s): Mack, John H.
• Assistant Examiner(s): Feeley, H. A.
• Application Number:
  US05/597,613
• Time in Patent Office: 358 Days
• Field of Search: 136/86 R, 136/86 B, 136/86 C, 136/86 E
• US Class Current: 429/437
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/04074 Heat exchange unit structures specially adapted for fuel cell
• CPC Class Codes: H01M 8/08 Fuel cells with aqueous electrolytes
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A cooler for removing waste heat from a stack of fuel cells uses a non-dielectric coolant which is carried in a plurality of tubes passing through one or more separator plates in the stack. Preferably the coolant is water so that heat removal is by evaporation of the water within the tubes by boiling. The tubes are electrically insulated from the cells by a coating of dielectric material such as polytetrafluoroethylene. In one embodiment of the present invention the cooler tubes are connected to the stack coolant supply conduits by dielectric hoses having a high length to diameter ratio to provide a several hundred thousand ohm impedance path in case of a flaw in the protective dielectric coating, in order that a short circuit of the stack does not occur.

Claims

1. In a fuel cell cooling system including a stack comprising a plurality of cells connected electrically in series said stack connected electrically to ground and electrically conductive separator plate means disposed between each pair of adjacent cells, an improvement to said stack comprising:

at least one of said separator plate means including passageways formed therein parallel to the plane of said plate means;

cooler means for carrying an electrically conductive coolant between said cells and including a plurality of cooler tubes disposed in said passageways and passing through said plate means, said tubes comprising electrically conductive wall means;

a dielectric material disposed between said electrically conductive plate means and said electrically conductive wall means adapted to provide an electrical barrier between said plate means and said wall means and Coolant circulation means in fluid Communication with said cooler means.

2. The improvement to said system according to claim 1 wherein said dielectric material is a continuous coating on said wall means.

3. The improvement to said system according to claim 2 wherein said cooler means includes resistance means external of said separator plate means adapted to create a high electrical resistance path through the coolant.

4. The improvement to said system according to claim 3 wherein said cooler means includes sacrificial electrode material disposed at the higher potential end of said resistance path.

5. The improvement to said system according to claim 2 wherein said circulation means is electrically conductive and connected electrically to ground and wherein said cooler means comprises conduit means external of said plate means connecting said circulation means to said cooler tubes, said conduit means comprising a wall of dielectric material having a length to diameter ratio adapted to create a high electrical resistance path through the coolant.

6. The improvement to said system according to claim 5 wherein said cooler means includes sacrificial electrode material adjacent the higher potential end of said resistance path.

7. The improvement to said system according to claim 6 wherein said cooler tubes include an inlet end and an outlet end and said sacrificial material is additional material disposed at least at one of said ends of said cooler tubes.

8. The improvement to said system according to claim 7 wherein each of said ends includes said additional material, and said wall of dielectric material is connected to said ends.

9. The improvement to said system according to claim 8 wherein said additional material comprises an insert disposed in each of said ends comprising a material which corrodes at a lower potential than said cooler tube material.

10. The improvement to said system according to claim 2 wherein said cells include phosphoric acid electrolyte, said dielectric material is a fluorocarbon polymer, and said separator plate means comprises graphite and is porous.

11. In a fuel cell cooling system including a stack comprising a plurality of cells connected electrically in series said stack connected electrically to ground and electrically conductive separator plate means disposed between each pair of adjacent cells, an improvement to said system comprising:

at least one of said separator plate means including passageways formed therein parallel to the plane of said plate means;

cooler means for carrying an electrically conductive coolant between said cells and including a plurality of cooler tubes disposed in said passageways and passing through said plate means, said tubes comprising electrically conductive wall means;

a continuous coating of dielectric material disposed on said electrically conductive wall means and having a thickness sufficient to prevent electric current from passing into the coolant to be carried by said tubes; and

a coolant circulation means in fluid communication with said cooler.

12. The improvement to said system according to claim 11 wherein said cooler means includes resistance means external of said separator plate means adapted to create a high electrical resistance path through the coolant.

13. The improvement to said system according to claim 12 wherein said cooler means includes sacrificial electrode material disposed at the higher potential end of said resistance path.

14. The improvement to said system according to claim 11 wherein said dielectric material is between said wall means and said plate means.

15. The improvement to said system according to claim 14 wherein said dielectric material is a fluorocarbon polymer.

16. The improvement to said system according to claim 14 wherein said coolant circulation means is electrically conductive and connected electrically to ground and wherein said cooler means includes conduit means in fluid communication with said circulation means, said conduit means including a dielectric wall portion for creating a high electrical resistance path through the coolant.

17. A fuel cell power plant cooling system comprising:

a non-dielectric coolant;

a load;

electrical connection means;

a plurality of fuel cell stacks connected electrically in series to each other via said electrically connection means and connected electrically in series with said load, said series of stacks being connected electrically to ground, each stack comprising a plurality of cells connected electrically in series and electrically conductive separator plate means disposed between each pair of adjacent cells in each stack, at least one of said separator plate means in each stack including passageways formed therein parallel to the plane of said plate means, each of said stacks including a cooler, said coolant flowing through said cooler, said cooler including cooler tubes disposed within said passageways and passing through said plate means, said tubes comprising electrically conductive wall means, said stack including a dielectric material disposed between said coolant and said plate means;

coolant circulation means connected electrically to ground and in fluid communication with each of said coolers; and

dielectric conduit means interconnecting said circulation means and said coolers, said conduit means adapted to create a high electrical resistance path through said coolant, said cooler including sacrifical electrode material in contact with said coolant at the higher potential end of said resistance path.

18. The fuel cell power plant cooling system according to claim 17 wherein said coolant is water.

19. The fuel cell power plant cooling system according to claim 18 wherein said dielectric material is a continuous coating on said wall means.

20. The fuel cell power plant cooling system according to claim 19 wherein said coating is disposed between said wall means and said plate means.

21. The fuel cell power plant cooling system according to claim 20 wherein said coolant circulation means includes pump means to circulate said coolant through said system and coolant separator means, said separator means adapted to receive coolant from said cooler means and to separate coolant in vapor form from coolant in liquid form, and conduit means connecting said separator means to said pump means for recirculating at least a portion of the separated liquid coolant through said coolers.