Method and apparatus for continuously determining the internal resistance of an electrolysis cell

• US 3,969,669 A
• Filed: 05/07/1975
• Issued: 07/13/1976
• Est. Priority Date: 06/05/1974
• Status: Expired due to Term

• Current Assignee: Aluminium Pechiney (Rio Tinto Limited)
• Original Assignee: Aluminium Pechiney (Rio Tinto Limited)
• Inventors: Lacroix, Jean-Claude, Brault, Thierry
• Primary Examiner(s): Krawczewicz, Stanley T.
• Application Number:
  US05/575,479
• Time in Patent Office: 433 Days
• Field of Search: 324/65 R, 324/30 A, 324/30 B, 324/30 R
• US Class Current: 324/442
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26
• CPC Class Codes: G01R 27/08 Measuring resistance by measuring both voltage and current

Abstract

The invention relates to a method of continuously determining the internal resistance of an electrolysis cell and to an apparatus for carrying out this method. In the method according to the invention a weak alternating current (if) of frequency (f) is superimposed upon the electrolysis current, the active part (rf) of the impedance which the cell offers to this alternating current is measured, followed by extrapolation to the zero frequency of the function giving the active part (rf) of the impedance as a function of the frequency (f), (rf) thus inclining towards the internal resistance of the cell. The invention is applicable to any electrolysis cell and more particularly to cells for the igneous electrolysis of alumina.

Claims

1. A method for continuously determining the internal resistance (R) of an electrolysis cell from the voltage (U) at the terminals of the cell and from the current (I) flowing through the cell, a weak alternating current (if) of frequency (f) being superimposed upon the direct current (I) used for electrolysis, wherein the active part (rf) of the impedance which the cell offers to this alternating current is determined, followed by extrapolation to zero frequency of the function giving the active part (rf) of the impedance as a function of the frequency (f), this active value (rf) thus inclining towards the internal resistance (R) of the cell.

2. A method as claimed in claim 1 using synchronous detection, wherein the alternating current (if) is taken by induction from a bar feeding the cell, the signal obtained is brought back into phase with the alternating current (if), after which it is measured by synchronous detection from a reference formed by a voltage of frequency (f), a voltage (V) is tapped at the terminals, the a.c. component (uf) is separated from that voltage and measured by synchronous detection from the same reference voltage of frequency (f), and finally the modulus (uo) of (uf) is divided by the modulus (io) of (if) to obtain the active component (rf) of the impedance of the cell, followed by extrapolation by making the frequency (f) tend towards zero so as to make the active component (rf) tend towards the internal resistance (R) of the cell.

3. A method as claimed in claim 1, wherein the phase of the reference signal of frequency (f) of the synchronous detections is synchronized with that of the a.c. component (if) of the current flowing through the cell.

4. A method as claimed in claim 1, wherein extrapolation to the zero frequency is carried out by tracing the curve representing the active component (rf) of the impedance of the cell as a function of the frequency (f), this curve is extrapolated to the zero frequency so as to obtain:

r = rf(f=0), after which a frequency (f) is selected and the ratio (K) of the internal resistance (R) of the cell to the active component (rf) of its impedance at the frequency (f) selected is assumed to be constant, which enables the internal resistance (R) to be obtained by multiplying the active value (rf) of the impedance of the cell measured at the frequency (f) by the coefficient K (assumed to be constant).

5. An apparatus using the method claimed in claim 1 comprising synchronous detectors and a generator (9) of frequency (f) with a sinusoidal output and an inphase square signal output, wherein the sinusoidal output of the generator (9) is connected to a current converter (8) connected between two points (50) and (51) on the feed bars (3) of the cell (1-2) on either side thereof, and superimposing a sinusoidal current (if) upon the direct current (1) flowing through the cell, the square signal output of the generator (9) is connected to the input of a galvanically insulated reference amplifier (10), said apparatus further comprising an inductive probe (4) for measuring the current (if) placed between the points (50) and (51) of the feed bars and attacking a first synchronous detector (11) whose reference input is connected to the output (176) of the galvanically insulated reference amplifier (10), an amplifier/a.c.-d.c. separator (7) whose inputs are connected to the poles (1) and (2) of the cell and whose output (97) giving the a.c. component (uf) of the voltage (U) at the poles of the cell is connected to the input of a second synchronous detector (11) whose reference input is also connected to the output (176) of the galvanically insulated reference amplifier (10), and a dividing operator (12) whose inputs are respectively connected to the outputs (Uof) and (iof) of the synchronous detectors (11) associated with (uf) and (if).

6. An apparatus as claimed in claim 5 of which the generator (9) of frequency (7) has only one sinusoidal output, wherein the input of the galvanically insulated reference amplifier (10) is connected to that sinusoidal output, its output being connected to the reference input of the synchronous detectors (11) through a device transforming the sinusoidal signal into a square signal.

7. An apparatus as claimed in claim 5 comprising a low-frequency generator (9) of frequency (f) with, on the one hand, a sinusoidal output connected to a current converter (8) connected between two points (50) and (51) on the feed bars (3) of the cell (1-2) on either side thereof, and on the other hand a square signal output connected to the input of a galvanically insulated reference amplifier (10), an inductive probe (4) placed between the points (50) and (51) of the feed bars and attacking, through an impedance adapter/integrator (5), a first synchronous detector (201), a separator amplifier (7) whose inputs are connected to the poles of the cell and whose output (97) giving the a.c. component of the voltage at the poles of the cell attacks a second synchronous detector (203), the outputs of the first and second synchronous detector (201) and (203) being respectively connected to the inputs (101) and (193) of a dividing operator (204) giving, at its output, the active component (rf) of the impedance of the cell at the frequency (f), wherein the output of the galvanically insulated amplifier (10) is connected to the input of a slave phase shifter (198) comprising a O-phase output connected to the reference inputs of the first and second synchronous detectors (201) and (203) and a 90°

output connected to the reference input of an auxiliary synchronous detector (200) attacked by the output of the impedance adapter/integrator (5) and of which the output is connected to the control input of the slave phase shifter (198) so that the reference signal of the first and second synchronous detectors (201) and (203) is synchronized with the a.c. component (if) of the current flowing through the cell.

8. An apparatus as claimed in claim 7, comprising a processor (205) processing a factor K whose output is connected to a multiplication input of the dividing operator (204) so that the product K.rf = R is obtained at the output of this operator.

9. An apparatus as claimed in claim 7 comprising a shunt (207) for measuring the intensity of the direct current (1) flowing through the cell connected in series in the feed bar (3) of the cell outside the points (50)-(51), of which the terminals are respectively connected to the inputs of a galvanically insulated measuring amplifier (208) with differential inputs, wherein the output (R) of the dividing operator (204) is connected to an input of a multiplying operator (209) whose other input is connected to the output of the galvanically insulated amplifier (208) and whose output (223) is connected to the input of a subtracting operator (210) whose second input is connected to the output (110) of the separator amplifier (7) giving the d.c. voltage (1) of the cell and whose output gives the counterelectromotive force of electrolysis E = U - RI.

10. An apparatus as claimed in claim 9 in which the intensity of the direct current 1 flowing through the cell is measured by an inductive probe, wherein the second input of the multiplying operator (209) is directly connected to this inductive probe.

11. An apparatus as claimed in claim 7 wherein the current converter (8) comprises at least one power transistor (115) in series with a shunt (122) connected in parallel with the points (50) and (51) on the feed bars (3) of the cell on either side thereof, the bases (123) of these transistors being connected to the output of an amplifier (121 - 125 - 128) with two differential inputs, of which one (120) is connected to the shunt (122), while the other is connected to the sinusoidal output of the generator (9) through an amplifier (131 - 132).

12. An apparatus as claimed in claim 5 wherein it is used in cells for the production of aluminum by the igneous electrolysis of alumina.