Method of joining components made of cross-linked polymers

• US 3,972,548 A
• Filed: 11/20/1974
• Issued: 08/03/1976
• Est. Priority Date: 11/27/1973
• Status: Expired due to Term

• Current Assignee: ABet Atomenergi
• Original Assignee: ABet Atomenergi
• Inventors: Roseen, Rutger Arvid
• Primary Examiner(s): Whitby, Edward G.
• Application Number:
  US05/525,562
• Time in Patent Office: 622 Days
• Field of Search: 156/84-86, 156/83, 156/158, 156/198, 156/272, 156/293, 156/294, 156/296, 156/303.1, 156/304, 285/381, 285/423, 285/156, 285/DIG. 10, 285/382.4, 285/382, 285/423, 138/155, 264/DIG. 71, 264/342 R
• US Class Current: 285/381.4
• CPC Class Codes: B29C 65/4895 Solvent bonding, i.e. the surfaces of the parts to be joined being treated with solvents, swelling or softening agents, without adhesives
• CPC Class Codes: B29C 65/66 by liberation of internal stresses, e.g. shrinking of one of the parts to be joined
• CPC Class Codes: B29C 65/68 using auxiliary shrinkable elements
• CPC Class Codes: B29C 66/03 After-treatments in the joint area B29C66/3262 takes precedence
• CPC Class Codes: B29C 66/112 Single lapped joints
• CPC Class Codes: B29C 66/1122 Single lap to lap joints, i.e. overlap joints B29C66/45, B29C66/472, B29C66/52272 take precedence
• CPC Class Codes: B29C 66/114 Single butt joints
• CPC Class Codes: B29C 66/1142 Single butt to butt joints
• CPC Class Codes: B29C 66/116 Single bevelled joints, i.e. one of the parts to be joined being bevelled in the joint area
• CPC Class Codes: B29C 66/1162 Single bevel to bevel joints, e.g. mitre joints
• CPC Class Codes: B29C 66/131 Single flanged joints, i.e. one of the parts to be joined being rigid and flanged in the joint area
• CPC Class Codes: B29C 66/5221 for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
• CPC Class Codes: B29C 66/5224 for forming fork-shaped connections, e.g. for making Y-shaped pieces
• CPC Class Codes: B29C 66/52241 with two right angles, e.g. for making T-shaped pieces
• CPC Class Codes: B29C 66/5229 involving the use of a socket
• CPC Class Codes: B29C 66/612 Making circumferential joints
• CPC Class Codes: B29C 66/636 using a support which remains in the joined object
• CPC Class Codes: B29C 66/71 characterised by the composition of the plastics material of the parts to be joined welding bar compositions B29C65/125
• CPC Class Codes: B29C 66/72 characterised by the structure of the material of the parts to be joined
• CPC Class Codes: B29C 66/731 characterised by the intensive physical properties of the material of the parts to be joined
• CPC Class Codes: B29C 66/73115 : Melting point
• CPC Class Codes: B29C 66/73117 : Tg, i.e. glass transition temperature
• CPC Class Codes: B29C 66/73715 : heat-shrinkable
• CPC Class Codes: B29C 66/73756 : the to-be-joined areas of both parts to be joined being fully cured
• CPC Class Codes: B29C 66/73774 : the to-be-joined areas of both parts to be joined being semi-crystalline
• CPC Class Codes: B29C 66/73776 : the to-be-joined areas of both parts to be joined being crystalline
• CPC Class Codes: B29C 66/73941 : characterised by the materials of both parts being thermosets
• CPC Class Codes: B29K 2023/00 : Use of polyalkenes or derivatives thereof as moulding material
• CPC Class Codes: B29K 2023/0691 : PEX, i.e. crosslinked polyethylene
• CPC Class Codes: B29K 2023/12 : PP, i.e. polypropylene
• CPC Class Codes: B29K 2023/18 : Polymers of hydrocarbons having four or more carbon atoms, e.g. polymers of butylene, e.g. PB, i.e. polybutylene
• CPC Class Codes: B29K 2077/00 : Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2105/24 : crosslinked or vulcanised
• CPC Class Codes: F16L 41/02 : Branch units, e.g. made in one piece, welded, riveted
• CPC Class Codes: F16L 41/08 : Joining pipes to walls or pipes, the joined pipe axis being perpendicular to the plane of the wall or to the axis of another pipe F16L41/02 takes precedence
• CPC Class Codes: Y10S 264/71 : Processes of shaping by shrinking
• CPC Class Codes: Y10S 285/909 : Fluorocarbons and memory plastics
• CPC Class Codes: Y10T 156/1005 : by inward collapsing of portion of hollow body

Abstract

The invention relates to a method of joining components made of cross-linked polymers, at least one of the components being a tube, which method comprises deforming at least one of the components so as to deviate from the cross-linking shape, inserting an end of the tube into the other component, and heating the joint location to the temperature where the deformed components tend to return to the cross-linking shape, the heating being maintained for a time sufficient to produce fusing together over the joint location.

Claims

1. A method of joining at least two components made of cross-linked polymers that possess a memory effect and are heat expandable or heat shrinkable, the first of said components being a tube and the second having an opening into which an end of the tube can be inserted, the original size of said opening being no greater than the original external size of said tube end, comprising the steps of

a. adjusting at least one of said original sizes so as to enable insertion of the tube end into said opening, whereby at least one of said components is imparted with the memory effect;

b. inserting said tube end into said opening to form a joint location;

c. heating said joint location to a temperature, which as a result of the memory effect causes said components to return to their original sizes and to form a joint and to fuse together over said joint.

2. The method of claim 1 wherein said second component is a tube having an open end into which an end of the first tube can be inserted.

3. The method of claim 2 for producing a joint of the fixed sleeve type wherein said adjustment in step (a) comprises enlarging the size of the open end of the second component so that the end of the first component can be inserted therein.

4. The method of claim 2 for producing a joint of the fixed sleeve type, wherein said adjustment in step (a) comprises reducing the size of the end of the first tube so that said end can be inserted in said open end of the second tube.

5. The method of claim 2 for producing a joint of the fixed sleeve type, wherein said adjusting in step (a) comprises enlarging the size of said open end of the second tube and reducing the size of the end of the first tube so that said end can be inserted in said open end.

6. The method of claim 2 for producing a joint of the loose sleeve type comprising using a third tube having both ends open, the original internal size of which is no greater than the original external sizes of the two other tubes, and enlarging, in step (a), the internal size of said third tube so that one of each of the two other tubes can be inserted in one of each of said open ends to form said joint location wherein the ends of said two other tubes inside of said third tube butt up against one another.

7. The method of claim 2, for producing a joint of the loose sleeve type, comprising using a third tube, the original external size of which is equal or greater than the internal sizes of the two other tubes, and, in step (a), reducing the external size of said third tube so that the two other tubes can each be slipped over the respective ends of said third tube to form said joint location of step (b) wherein the ends of said two other tubes butt up against one another.

8. The method of claim 1 wherein said second component is a tube having an opening which is not at either end of the tube into which an end of the first tube can be inserted to form a joint of the tee-piece type.

9. The method of claim 8 comprising enlarging, in step (a), the size of said opening so that the end of the first tube can be inserted therein.

10. The method of claim 8 comprising reducing, in step (a), the size of the end of the first tube so that said end can be inserted in said opening.

11. The method of claim 8 wherein adjustment step (a) comprises enlarging the size of the opening and reducing the size of the end of the first tube so that the end of the first tube can be inserted in the opening.

12. The method of claim 1 wherein said second component is a junction box having an opening into which an end of the tube can be inserted.

13. The method of claim 12 wherein, in step (a), the size of said junction box opening is enlarged so that the end of the tube can be inserted therein.

14. The method of claim 12 wherein, in step (a), the size of the end of the tube is reduced so that said end can be inserted in said junction box opening.

15. The method of claim 12 wherein, in step (a), the size of said junction box opening is enlarged and the size of the end of the tube is reduced so that the end of said tube can be inserted in said junction box opening.

16. The method of claim 1 wherein adjustment step (a) is carried out with a mandrel.

17. The method of claim 1 comprising using components made wholly or partially of crystalline polymers and wherein adjustment step (a) is carried out at a temperature below the crystalline melting point of the polymer and said heating in step (c) is carried out at a temperature equal to or greater than the crystalline melting point.

18. The method of claim 17 wherein the polymer is cross-linked polyethylene.

19. The method of claim 1 wherein adjustment step (a) is carried out in the cold state.

20. The method of claim 1 wherein the resultant joint is bombarded with high-energy radiation.

21. The method of claim 1 wherein prior to the heating in step (c), at least one of the components is coated with a cross-linking agent, which produces free radicals at a temperature in excess of the softening point of the polymer.

22. The method of claim 21 wherein the cross-linking agent is a peroxide.

23. The method of claim 1 wherein a ring is coaxially disposed in the end of the tube, which ring has an external diameter which is greater than the size of the opening of said second component.

24. The method of claim 23 wherein the ring is metal.

25. The method of claim 8 wherein said opening has been given a stepped form and wherein the tube end to be inserted therein has been stepped in a corresponding way.

26. The method of claim 1 for joining a first tube to a second tube, the external size of the first tube being smaller than the internal size of the second tube, comprising using a third tube section, the internal size of which is no greater than the external size of said first tube and the external size of which is at least as great as the internal size of said second tube, and adjusting the size of at least one of said three tubes so that said first tube can be inserted into one end of the third tube and the second tube can be slipped over the other end of the third tube.

27. A joint prepared by a method as claimed in claim 1.