Method for dispersing gas into a molten metal

• US 3,972,709 A
• Filed: 04/23/1975
• Issued: 08/03/1976
• Est. Priority Date: 06/04/1973
• Status: Expired due to Term

• Current Assignee: Southwire Company
• Original Assignee: Southwire Company
• Inventors: Chia, Enrique C., Forberg, Helge Ole
• Primary Examiner(s): Andrews, M. J.
• Application Number:
  US05/570,673
• Time in Patent Office: 468 Days
• Field of Search: 75/93 R, 75/68 R, 75/61, 75/93 AC, 261/87, 266/34 A, 266/34 T
• US Class Current: 75/680
• CPC Class Codes: C22B 9/05 Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ

Abstract

A method of and apparatus for uniformly dispersing a gas into a molten metal bath by supplying gas to a rotatably mounted distributor located at a submerged zone beneath the bath surface while preventing physical contact between the gas and the molten metal; emitting the gas from the distributor in the form of a plurality of bubble jets into contact with the molten metal at said zone, said bubble jets exerting a reaction force on the distributor; and agitating the molten metal to effect uniform dispersion of the gas emitted therein by whirling the bubble jets in the molten metal, said whirling being accomplished by rotating the distributor in response to said reaction forces. The apparatus comprises a supply conduit connected at one end to a source of pressurized gas and connected at the other end to a rotatable hollow sleeve immersed in the molten metal. An array of apertures extend through the sleeve for discharging the gas into the molten metal in the form of numerous gas bubble jets and the apertures are arranged to discharge the gas bubble jets in mutually cooperative jetting directions to rotationally propel the sleeve about the supply conduit. The rotary movement of the sleeve causes the gas bubble jets to whirl about in the molten metal thereby agitating the molten metal to effect uniform dispersion of the gas within the molten metal.

Claims

1. A method of fluxing molten metal to remove dissolved gases and non-metallic impurities therefrom comprising the steps of:

a. providing a fluxing gas which at least partially includes a component that is non-reactive with the molten metal;

b. supplying the gas to a rotatably mounted distributor located at a submerged zone beneath the surface of the molten metal at a positive pressure sufficient to prevent physical contact between the gas and the molten metal upstream of the distributor;

c. emitting the gas from the distributor into the molten metal in a plurality of very small bubble jets extending in a direction oblique to radial lines extending perpendicular to the axis of rotation of the distributor, said jets having a tangential component which exerts a reaction force on the distributor; and

d. rotating the distributor solely in response to said reaction force in a direction opposite to the direction of said bubble jets emitted therefrom, thereby substantially preventing bubble coalescence in the region of the distributor and thus effecting uniform and complete dispersion of the bubbles through the molten metal.

2. A method according to claim 1 wherein the step of supplying gas to the distributor includes continuously passing the gas downwardly to said submerged zone from above the surface of the molten metal through a conduit extending into the metal and maintaining the conduit fixed with respect to the molten metal while rotating the distributor to effect whirling of the bubble jets, thereby preventing turbulence at the surface of the metal and thus inhibiting the inclusion of ambient gas therein.

3. The method of claim 1 wherein the non-reactive component is selected from the group consisting of helium, neon, argon, krypton, xenon, nitrogen, carbon dioxide and mixtures thereof.

4. The method of claim 1, said gas further including a reactive component, and wherein the ratio of non-reactive components to reactive component is from about 9:

1 to about 1;

9.

5. The method of claim 1 wherein the gas has a reactive component.

6. The method of claim 5 wherein the reactive component of the gas is selected from the group consisting of a chlorine-containing gas, aluminum chloride, fluorine, aluminum fluoride, hydrofluoric acid, nitrogen, monatomic nitrogen, carbon monoxide, dichlorodifluoromethane, halogenated hydrocarbons and mixtures thereof.

7. The method of claim 5 wherein the reactive component of the gas is selected from the group consisting of lithium nitride, aluminum nitride, alkali metal chlorides, alkali metal fluorides, alkaline earth metal chlorides, alkaline earth metal fluorides and mixtures thereof.