Pressurized fuel cell power plant with single reactant gas stream

• US 3,976,507 A
• Filed: 02/12/1975
• Issued: 08/24/1976
• Est. Priority Date: 02/12/1975
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Bloomfield, David P.
• Primary Examiner(s): Mack, John H.
• Assistant Examiner(s): Feeley, H. A.
• Application Number:
  US05/549,602
• Time in Patent Office: 559 Days
• Field of Search: 136/86 R, 136/86 A, 136/86 B, 136/86 C
• US Class Current: 429/415
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell power plant for producing electricity uses pressurized air and fuel in the cells. The power plant includes an autothermal reactor for processing the fuel and a compressor driven by a turbine for compressing the air used by the fuel cells. Pressurized effluent gases from the cathode side of the cell and pressurized fuel is delivered into the autothermal reactor and from the reactor passes into the anode side of the cells. Effluent gases from the anode side of the cells is delivered into the turbine thereby driving the compressor. A burner is used to increase the temperature of the gases entering the turbine. The burner is run on air and unburned fuel in the effluent gases from the anode side of the cells.

Claims

1. A power plant for generating electricity comprising:

a fuel cell stack including a plurality of fuel cells connected electrically in series through a load, each cell comprising a cathode electrode, an anode electrode, an electrolyte disposed therebetween, a cathode gas space on the nonelectrolyte side of said cathode electrode and an anode gas space on the nonelectrolyte side of said anode electrode;

compressor means including a compressor operably connected to turbine means;

means for delivering air at a pressure of at least two atmospheres from said compressor into said cathode gas space;

fuel conditioning apparatus including an autothermal reactor;

means for delivering effluent gases from said cathode gas space and pressurized hydrogen containing fuel into said autothermal reactor;

means for delivering pressurized hydrogen from said fuel conditioning apparatus into said anode gas space;

means for delivering anode gas space effluent gases into said turbine means for powering said turbine means and driving said compressor; and

means disposed downstream of said anode gas space for increasing the temperature of the anode gas space effluent gases before they are delivered into said turbine means, including a burner and means for delivering anode gas space effluent gases into said burner to provide fuel therefor.

2. The power plant according to claim 1 wherein said hydrogen containing fuel is gaseous and said means for delivering pressurized hydrogen containing fuel into said autothermal reactor includes means for first delivering said hydrogen containing fuel into said compressor for compressing said fuel to a pressure of at least two atmospheres.

3. The power plant according to claim 2 wherein said means for delivering pressurized fuel into said autothermal reactor includes means for delivering said pressurized fuel from said compressor into said cathode gas space along with said compressed air.

4. The power plant according to claim 1 including heat exchanger means in heat exchange relationship with the gases entering and leaving said autothermal reactor for transferring heat from said autothermal reactor effluent gases to the gases entering said autothermal reactor.

5. The power plant according to claim 1 wherein said electrolyte is phosphoric acid.

6. The power plant according to claim 1 wherein said burner is disposed upstream of said turbine means, and said means for delivering anode gas space effluent gases into said turbine means comprises means for delivering the effluent gases from said burner into said turbine means.

7. The power plant according to claim 6 including means for delivering compressed air from said compressor into said burner.

8. The power plant according to claim 1 wherein said burner is disposed downstream of said turbine means, and said means for delivering anode gas space effluent gases into said burner includes means for delivering effluent gases from said turbine means into said burner, said burner being in heat transfer relationship with said anode gas space effluent gases upstream of said turbine means.

9. In the process of generating electricity in a power plant comprising a compressor operably connected to turbine means, autothermal reactor means, and a fuel cell stack including a plurality of full cells connected electrically in series through a load, each cell comprising a cathode electrode, an anode electrode, an electrolyte disposed therebetween, a cathode gas space on the nonelectrolyte side of said cathode electrode and an anode gas space on the nonelectrolyte side of said anode electrode, the steps of:

compressing air to greater than two atomspheres pressure in said compressor;

delivering said compressed air at greater than two atmospheres pressure from said compressor into said cathode gas space;

delivering cathode gas space effluent into said autothermal reactor;

delivering pressurized hydrogen containing fuel into said autothermal reactor;

delivering the effluent gases from said autothermal reactor into said gas space;

delivering the effluent gases from said anode gas space into said turbine means for powering said turbine means and driving said compressor;

increasing the temperature of said anode gas space effluent gases prior to delivering them into said turbine means comprising burning the anode effluent gases in a burner.

10. The process according to claim 9 wherein said fuel is gaseous and said step of delivering pressurized fuel into said autothermal reactor includes the step of first delivering said fuel into said compressor for pressurizing said fuel.

11. The process according to claim 10 wherein the step of delivering pressurized fuel into said autothermal reactor includes the step of delivering said pressurized fuel from said compressor into said cathode gas space along with said compressed air and from said cathode gas space into said autothermal reactor.

12. The process according to claim 9 wherein the step of burning anode effluent gases in a burner includes burning said anode effluent gases with air before delivering said anode effluent gases into said turbine means.

13. The process according to claim 12 wherein said step of burning said anode gas space effluent gases with air includes the step of burning said gases with air delivered from said compressor.

14. The process according to claim 9 wherein the step of burning anode effluent gases in a burner is done after said anode effluent gases have been exhausted from said turbine means, including transferring the heat resulting from said step of burning to the anode effluent gases before said anode effluent gases are delivered into said turbine means.