Coolant additives for nitrogen generating solid propellants

• US 3,977,924 A
• Filed: 04/01/1974
• Issued: 08/31/1976
• Est. Priority Date: 04/01/1974
• Status: Expired due to Term

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: McCulloch, Charles R., MacKenzie, Gerald L.
• Primary Examiner(s): Engle, Samuel W.
• Assistant Examiner(s): Walsh, Donald P.
• Application Number:
  US05/456,703
• Time in Patent Office: 883 Days
• Field of Search: 149/19.3, 149/35, 149/77, 149/82, 149/83, 149/70, 149/71, 149/37, 149/42, 280/150 AB
• US Class Current: 149/19.3
• CPC Class Codes: C06B 35/00 Compositions containing a metal azide
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Cooled gas generating solid propellant, includes sodium azide or lithium de as a nitrogen gas source, a fluorocarbon binder material, a combustion catalyst, and alkaline metal acid salt coolant.

Claims

1. A gas generating solid propellant comprising sodium azide, a fluorocarbon binder material, a combustion catalyst selected from the group consisting of a finely divided colloidal silicon dioxide, a finely divided carbon black, and mixtures thereof, an alkaline metal acid salt coolant, a halogen substituted organic acid salt and an oxidizer.

2. The propellant of claim 1 wherein the coolant is selected from the group consisting of alkaline metal salts of formic acid, carbonic acid, oxalic acid, tartaric acid, nitric acid and mesoxalic acid or mixtures thereof.

3. The propellant of claim 2 wherein the coolant is selected from the group consisting of sodium oxalate and sodium bicarbonate or mixtures thereof, the halogen substituted organic acid salt is sodium trichloroacetate and the oxidizer is sodium perchlorate.

4. The propellant of claim 2 wherein the halogen substituted organic acid salt is present in an amount equal to the amount of the coolant and the oxidizer is present in an amount equal to about one half of the amount of the coolant.

5. The gas generating solid propellant of claim 1 wherein said finely divided colloidal silicon dioxide is further characterized by having a minimum surface area of about 175 square meters per gram.

6. The gas generating solid propellant of claim 1 wherein said fluorocarbon binder material is a polymeric fully fluorinated fluorocarbon.

7. The gas generating solid propellant of claim 6 wherein said polymeric fully fluorinated fluorocarbon is polytetrafluoroethylene.

8. The gas generating solid propellant of claim 1 wherein said fluorocarbon binder material is a polymeric partially fluorinated fluorocarbon.

9. The gas generating solid propellant of claim 8 wherein said polymeric partially fluorinated fluorocarbon is selected from the group consisting of a copolymer of vinylidene fluoride and hexafluoropropylene, a hydroxy-terminated fluorocarbon, a homopolymer of chlorotrifluoroethylene and a copolymer of vinylidene fluoride and chlorotrifluoroethylene;

and the coolant is at least one salt selected from the group consisting of an alkaline salt of carbonic acid, oxalic acid, formic acid, tartaric acid, nitric acid, and mesoxalic acid.

10. The gas generating solid propellant of claim 9 wherein said polymeric partially fluorinated fluorocarbon is a copolymer of vinylidene fluoride and hexafluoropropylene.

11. The gas generating solid propellant of claim 9 wherein said polymeric partially fluorinated fluorocarbon is a hydroxy terminated fluorocarbon, and the coolant is selected from the group consisting of sodium bicarbonate and sodium oxalate.

12. The gas generating solid propellant of claim 2 wherein said sodium azide and said fluorocarbon binder material are present in about stoichiometric quantities.

13. The gas generating solid propellant of claim 2 which further includes a metal selected from the group consisting of magnesium and aluminum.