Encapsulation particles

• US 3,983,254 A
• Filed: 04/14/1975
• Issued: 09/28/1976
• Est. Priority Date: 12/07/1973
• Status: Expired due to Term

• Current Assignee: Lever Brothers Company (Unilever PLC)
• Original Assignee: Lever Brothers Company (Unilever PLC)
• Inventors: Chun, Kil Whan, Alterman, David S.
• Primary Examiner(s): Kendell, Lorraine T.
• Application Number:
  US05/567,677
• Time in Patent Office: 533 Days
• Field of Search: 428/403, 428/411, 428/420, 252/95, 252/96, 252/103, 252/187 C
• US Class Current: 428/403
• CPC Class Codes: B01J 2/006 Coating of the granules without description of the process or the device by which the granules are obtained to prevent the granules sticking together B01J2/30
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 3/3955 Organic bleaching agents C11D3/3951 takes precedence
• CPC Class Codes: Y10T 428/2991 Coated

Abstract

Particles of a fluidizable substance are coated with a complete and continuous coating by a process wherein a non-aqueous solution of a coating substance is sprayed from a nozzle downwardly on a fluidized bed of the particles to be coated, the nozzle height being adjusted so that the liquid droplets of coating material would just cover the cross-sectional area of the upper surface of the bed, if sprayed on the unexpanded bed. When the aforementioned coating is a fatty acid having 12-20 carbon atoms applied to particles of a chlorine-releasing agent, and when a second coating is applied by treatment with a solution of a fixed alkali hydroxide, i.e., sodium, potassium, or calcium hydroxide, an effective, completely encapsulated, non-pinholing bleach product is obtained.

Claims

1. Encapsulated potassium dichloroisocyanurate in particulate form, said particles having thereon an inner and an outer coating, said inner coating comprising a saturated fatty acid from 12 to 20 carbon atoms, or mixtures thereof, and said outer coating comprising a sodium salt of said acid, or mixtures thereof, said particles of potassium dichloroisocyanurate having said inner coating being completely encapsulated by said sodium salt.

2. Encapsulated particles suitable for bleaching fabrics in an aqueous medium, comprising:

i. a core of potassium dichloroisocyanurate,

ii. a primary coating of a fatty acid comprising about 55% palmitic acid and about 45% stearic acid, and

iii. an outer coating of the sodium salt of said fatty acid,

said primary coating and said outer coating being substantially continuous.

3. Encapsulated particles of an oxidizing material having at least one reactive chlorine atom in its molecular structure and being selected from the group consisting of potassium dichloroisocyanurate, sodium dichloroisocyanurate, [(mono-trichloro)-tetra-(mono-potassium dichloro)] pentaisocyanurate and trichlorocyanuric acid, said particles having thereon a complete and continuous inner and outer coating, the inner coating comprising a saturated fatty acid having from 12 to 20 carbon atoms or mixtures thereof, and the outer coating comprising a sodium salt of said acid or mixtures thereof;

said inner coating being completely encapsulated by said sodium salt.