Pressure-sensitive adhesive tape or drape

• US 3,983,297 A
• Filed: 10/24/1974
• Issued: 09/28/1976
• Est. Priority Date: 06/14/1972
• Status: Expired due to Term

• Current Assignee: Teijin Limited
• Original Assignee: Teijin Limited
• Inventors: Ono, Tomoyoshi, Matsuguma, Yoshihiko
• Primary Examiner(s): Cannon, J.C.
• Application Number:
  US05/517,644
• Time in Patent Office: 705 Days
• Field of Search: 260/80.8, 260/78.5 UA, 428/355, 428/521, 428/522
• US Class Current: 428/355.0AC
• CPC Class Codes: C08F 220/1808 C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
• CPC Class Codes: C09J 133/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: C09J 7/385 Acrylic polymers
• CPC Class Codes: Y10T 428/2891 including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

An adhesive tape or drape comprising a base sheet and formed thereon a layer of a pressure-sensitive adhesive comprising as a main constituent a copolymer prepared by copolymerizing an alkyl acrylate with 2 to 6 mol% of acrylic acid or methacrylic acid and 0.002 to 0.05 mol% of a polyfunctional compound having at least 2 non-conjugated carbon-to-carbon double bonds per molecule.

Claims

1. An adhesive tape or drape comprising a base sheet and formed thereon, a layer of a pressure-sensitive adhesive comprising as a main constituent a copolymer comprising

3. The adhesive tape or drape of claim 1 wherein said alkyl acrylate monomer is selected from the group consisting of butyl acrylate, amyl acrylate, hexyl acrylate, heptyl acrylate, octyl acrylate, nonyl acrylate, decyl acrylate, and 2-ethylhexyl acrylate.

4. The adhesive tape or drape of claim 1 wherein said polyfunctional compound is selected from the group consisting of diallyl phthalate, ethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, trimethylol ethane trimethacrylate, and pentaerthritol tetramethacrylate.

5. The adhesive tape or drape of claim 3 wherein said polyfunctional compound is polyethylene glycol dimethacrylate.

6. The adhesive tape or drape of claim 3 wherein said polyfunctional compound is ethylene glycol dimethacrylate.

7. The adhesive tape or drape of claim 3 wherein said polyfunctional compound is trimethylol ethane trimethacrylate.

8. The adhesive tape or drape of claim 3 wherein said polyfunctional compound is pentaerythritol tetramethacrylate.

9. The adhesive tape or drape of claim 3 wherein said polyfunctional compound is diallylphthalate.

10. The adhesive tape or drape of claim 1 wherein said monomer component (1) comprises 94 to 98 mol% of at least one alkyl acrylate monomer with the alkyl group containing 1 to 14 carbon atoms, the average number of the carbon atoms being 4 to 12, and another monomer selected from the group consisting of methyl methacrylate, vinyl acetate and mixtures thereof in a mol ratio of at least 5 to 1.

11. The adhesive tape or drape of claim 9 wherein said other monomer is methyl methacrylate.

12. The adhesive tape or drape of claim 9 wherein said other monomer is vinyl acetate.

2. 94 to 98 mol% based on the total of components (1) and (2) of at least one alkyl acrylate monomer with the alkyl group containing 1 to 14 carbon atoms, the average number of the carbon atoms being 4 to 12, or a mixture of said alkyl acrylate with another monomer selected from the group consisting of methyl methacrylate, vinyl acetate and mixtures thereof in a mol ratio of said alkyl acrylate to said other monomer of at least 5 to 1,2 to 6 mol% based on the total of components (1) and (2) of a monomer selected from the group consisting of acrylic acid, methacrylic acid, and mixtures thereof, and0.002 to 0.05 mol% based on the total of components (1) and (2) of a polyfunctional compound copolymerizable with the monomers (1) and (2) and having at least two non-conjugated carbon-to-carbon double bonds per molecule with the proviso that the amounts of component (1) and component (2) totals 100 mol%;

said copolymer prepared by copolymerizing components (1), (2), and (3) by solution polymerization or emulsion polymerization.