Gasification process and apparatus

• US 3,985,520 A
• Filed: 06/26/1975
• Issued: 10/12/1976
• Est. Priority Date: 05/30/1973
• Status: Expired due to Term

• Current Assignee: Louis Gold
• Original Assignee: Louis Gold
• Inventors: Gold, Louis
• Primary Examiner(s): Serwin, R.E.
• Application Number:
  US05/590,743
• Time in Patent Office: 474 Days
• Field of Search: 48/210, 48/209, 48/197, 48/101, 48/202, 75/41, 75/42
• US Class Current: 48/202
• CPC Class Codes: C01B 3/061 by reaction of metal oxides with water
• CPC Class Codes: C01B 3/10 by reaction of water vapour with metals
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0943 Coke
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/0976 as steam
• CPC Class Codes: C10J 2300/0996 Calcium-containing inorganic materials, e.g. lime
• CPC Class Codes: C10J 2300/1671 with the production of electricity
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 2300/1892 with one stream being water/steam
• CPC Class Codes: C10J 3/08 with ash-removal in liquid state
• CPC Class Codes: C10J 3/57 Gasification using molten salts or metals C10J3/02, C10J3/46 take precedence
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

In addition to introducing steam and/or oxygen in the heated airblast through the tuyeres of a conventional blast furnace to provide a blast furnace gas enriched with carbon monoxide and hydrogen, air and/or steam can be forced through the molten pig iron which has been withdrawn from the blast furnace into a separate reactor having a modified construction similar to the basic oxygen furnace for the purpose of producing large volumes of hydrogen. The blast furnace gasses can be combined with the gasses from the reactor to provide a clean burning fuel for use in power plants and the like or the hydrogen from the reactor can be utilized directly in fuel-cell technology. The resulting iron oxides (magnetite, etc.) which result from the pig iron-steam reaction can then be recycled through the blast furnace.

Claims

1. A process for the production of hydrogen comprising producing a quantity of molten pig iron in a blast furnace, charging said molten pig iron into a separate reaction vessel, passing steam through the molten pig iron in said reactor to produce iron oxides and hydrogen, collecting said hydrogen and recycling said iron oxides through said blast furnace.

2. A process as set forth in claim 1 wherein the reaction of said steam and molten pig iron takes place in a closed environment.

3. A process as set forth in claim 1 further comprising passing steam through the charge in said blast furnace to provide a hydrogen enriched blast furnace gas.

4. A process as set forth in claim 1 further comprising passing oxygen through the charge in said blast furnace to provide a carbon monoxide enriched blast furnace gas.

5. A process as set forth in claim 3 wherein the hydrogen produced in said reactor is added to said blast furnace gas to enrich the same.

6. A process as set forth in claim 4 wherein the hydrogen produced in said reactor is added to said blast furnace gas to enrich the same.

7. A reactor for the production of gasses from molten pig iron comprising a vessel having an open top adapted to receive a charge of molten pig iron, means for pivoting said vessel from a tilted position for assisting in charging and discharging the molten material to a substantially vertical position, blast means for introducing a gaseous blast through the molten pig iron and conduit means having movable sealing means at one end adapted to be moved into tight sealing engagement with the top of said vessel to provide for the collection of all gasses emanating therefrom.

8. A reactor as set forth in claim 7 wherein said blast means are provided for in said conduit means.

9. A reactor as set forth in claim 7 wherein said blast means is comprised of a lance adapted to be extended into and withdrawn from the vessel through the top thereof.

10. A reactor as set forth in claim 7 wherein said blast means is comprised of a plurality of apertures in the bottom of said vessel and additional conduit means adapted to supply a gaseous blast through said apertures.