Method for the treatment of red mud

• US 3,989,513 A
• Filed: 03/11/1975
• Issued: 11/02/1976
• Est. Priority Date: 06/06/1972
• Status: Expired due to Term

• Current Assignee: Magyar Aluminiumipari Troszt
• Original Assignee: Magyar Aluminiumipari Troszt
• Inventors: Horvath, Gyula, Solymar, Karoly, Osvald, Zoltan, Kaptay, Gyorgy, Felfoldi, Zoltan, Dobos, Gyorgy
• Primary Examiner(s): Andrews, M. J.
• Application Number:
  US05/557,341
• Time in Patent Office: 602 Days
• Field of Search: 75/21, 75/24, 75/28, 75/29, 75/30, 75/33, 75/38, 75/101 R, 75/40, 423/119, 423/111, 423/131, 423/137
• US Class Current: 75/10.67
• CPC Class Codes: C01F 7/066 Treatment of the separated residue
• CPC Class Codes: C01F 7/38 Preparation of aluminium oxide by thermal reduction of aluminous minerals
• CPC Class Codes: C21B 11/00 Making pig-iron other than in blast furnaces
• CPC Class Codes: C21B 3/02 by applying additives, e.g. fluxing agents
• CPC Class Codes: C22B 7/04 Working-up slag
• CPC Class Codes: Y02P 10/20 Recycling
• CPC Class Codes: Y10S 75/958 with concurrent production of iron and other desired nonmetallic product, e.g. energy, fertilizer

Abstract

Disclosed is a method for the treatment of the red mud byproduct of the Bayer aluminum process, wherein limestone, hydrated lime or other CaO-containing material is added to the red mud in certain molar proportions to the ingredients of the red mud, then the mixture is further mixed with a reducing agent, and the entire mixture is subjected to a reducing heat treatment during the course of which the mix becomes softened or molten. The iron and the slag are separated from each other while the mix is still molten, or after it has been cooled, and then the Na and Al-content of the slag is extracted with a sodium carbonate solution containing a caustic, or with a sodium carbonate solution and a solution of a caustic in two steps.

Claims

1. In a method for the treatment of the red mud byproduct of aluminum manufacture said red mud containing Fe₂ O₃, Al₂ O₃, Na₂ O, SiO₂ and TiO₂, wherein the red mud is subjected to a reducing heat treatment with an added reducing agent during the course of which said red mud is molten, the iron and slag that are formed are separated from each other, and subsequently leaching out the Na and Al contents of the solidified slag, the improvement in combination therewith comprising adding to the red mud which contains more than 5% Na₂ O a CaO-containing ingredient in the following molar ratios and based on the weight of dry red mud ##EQU2## carrying out the reducing heat treatment and then leaching the Na and Al-contents of the solidified slag with a caustic solution and sodium carbonate, the entire process requiring only a single reducing heat treatment.

2. The process of claim 1, further comprising the adding of a reducing agent to the red mud before said heat treatment.

3. The process of claim 1, wherein said reducing heat treatment is carried out rapidly, within 20 minutes.

4. The process of claim 1, wherein after solidification iron is separated from the slag by magnetic separation.

5. The process of claim 1, wherein the iron and slag are separated from each other while molten.

6. The process of claim 1, wherein the Na and Al contents of the slag are leached in a single step with a sodium carbonate with caustic solution.

7. The process of claim 1, wherein the Na and Al contents of the slag are leached in a plurality of steps, with a caustic solution and then with a sodium carbonate solution.