Process for making a polyurethane foam sheet and composites including the sheet

• US 3,989,869 A
• Filed: 08/22/1974
• Issued: 11/02/1976
• Est. Priority Date: 08/28/1973
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Reiff, Helmut, Noll, Klaus, Neumaier, Hermann
• Primary Examiner(s): Van Balen, William J.
• Application Number:
  US05/499,754
• Time in Patent Office: 803 Days
• Field of Search: 161/159, 161/160, 161/190, 156/78, 156/77, 260/29.2 TN, 427/244, 427/407, 428/310, 428/315, 428/424, 428/425, 428/246, 428/254, 428/261, 428/262, 428/286, 428/290
• US Class Current: 442/226
• CPC Class Codes: B32B 2250/24 All layers being polymeric
• CPC Class Codes: B32B 2262/0238 Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 2266/0278 Polyurethane
• CPC Class Codes: B32B 2305/022 Foam
• CPC Class Codes: B32B 2305/18 Fabrics, textiles
• CPC Class Codes: B32B 2305/186 Knitted fabrics
• CPC Class Codes: B32B 2305/188 Woven fabrics
• CPC Class Codes: B32B 2305/20 in the form of a non-woven mat
• CPC Class Codes: B32B 2327/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B32B 2375/00 Polyureas; Polyurethanes
• CPC Class Codes: B32B 27/00 Layered products comprising a layer of synthetic resin fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18
• CPC Class Codes: B32B 27/065 of foam
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/40 comprising polyurethanes
• CPC Class Codes: B32B 43/006 Delaminating
• CPC Class Codes: B32B 5/022 Non-woven fabric
• CPC Class Codes: B32B 5/024 Woven fabric
• CPC Class Codes: B32B 5/026 Knitted fabric
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: B32B 5/245 another layer next to it being a foam layer
• CPC Class Codes: B32B 7/06 : permitting easy separation
• CPC Class Codes: B32B 7/12 : using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: D06N 3/0045 : obtained by applying a ready-made foam layer; obtained by compressing, crinkling or crushing a foam layer, e.g. Kaschierverfahren für Schaumschicht
• CPC Class Codes: D06N 3/14 : with polyurethanes
• CPC Class Codes: Y10T 428/249978 : Voids specified as micro
• CPC Class Codes: Y10T 428/249992 : Linear or thermoplastic
• CPC Class Codes: Y10T 428/31554 : Next to second layer of polyamidoester
• CPC Class Codes: Y10T 428/3158 : Halide monomer type [polyvinyl chloride, etc.]
• CPC Class Codes: Y10T 442/3366 : Woven fabric is coated, impregnated, or autogenously bonded
• CPC Class Codes: Y10T 442/652 : Nonwoven fabric is coated, impregnated, or autogenously bonded

Abstract

A process is provided for making a polyurethane mechanical foam adapted to be used as an interlayer between a plastic surface layer and a textile, the process involving frothing a non-ionic aqueous dispersion free from emulsifying agents of a polyurethane having a particle size of less than 1 micron, said dispersion containing more than 45% by weight polyurethane and a thickening agent whereby its viscosity of the dispersion is from about 10 to about 70 seconds with a Ford Cup having a 4 mm orifice to form a foamable mixture, spreading the frothed dispersion into a foamed film, and drying the resulting product.

Claims

1. A composite material comprising the following adjacent layers:

a. a plastics sheet, and

b. a sheet of mechanical foam having a density of about 0.04 to about 0.40 g/cm³ obtained by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0μ

.

2. A composite according to claim 1, characterized in that about 0.1 to about 10% by weight of thickener, based on the polyurethane solids, are added to the nonionic polyurethane dispersion.

12. A process for producing a composite material

which comprises applying a layer of adhesive to a composite material according to claim 1, embedding a textile layer in the layer of adhesive by light pressure and drying.

18. The process of claim 12 wherein the textile is a woven or knitted textile or a non-woven web.

22. The composite material of claim 1 wherein the plastics sheet is a substantially non-porous polyurethane sheet.

23. The composite material of claim 1 wherein the plastics sheet is microporous polyurethane sheet.

24. The composite material of claim 1 wherein the plastics sheet is a polyvinyl chloride sheet.

3. A composite material comprising the following adjacent layers;

a. a woven or knitted textile layer or nonwoven web of a fibrous material,

b. a foam layer having a density of about 0.04 to about 0.40 g/cm³ obtained by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0μ

, and

c. a plastics sheet.

25. The composite material of claim 3 wherein the plastics sheet is a homogeneous polyurethane sheet.

26. The composite material of claim 3 wherein the plastics sheet is a microporous polyurethane sheet.

27. The composite material of claim 3 wherein the plastics sheet is a polyvinyl chloride plastic sheet.

4. A composite material comprising the following adjacent layers:

a. a foam layer having a density of about 0.04 to about 0.40 g/cm³ obtained by mechanically frothing a nonionic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0μ

, and

b. a fibrous textile layer.

5. A self-supporting polyurethane foam sheet having a density of about 0.04 to about 0.40 g/cm³ which has been produced by mechanically frothing a nonionic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0 μ

.

6. In a process for producing a composite material from

a. a homogeneous or microporous plastics sheet and

b. a polyurethane foam,

the improvement which comprises applying a homogeneous or microporous plastic sheet to a release support, spread-coating on the sheet a polyurethane foam having a density of about 0.04 to about 0.40 g/cm³, which has been produced by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0 μ

,

and drying the coating and thereafter removing the release support.

10. The process for producing composite material according to claim 6, wherein the plastics sheet is a microporous or homogeneous polyurethane sheet.

11. The process for producing composite materials according to claim 6, wherein the plastics sheet is a polyvinyl chloride sheet.

15. The process of claim 6 wherein the plastic sheet is applied to the release support by coating the release support with a liquid plastic coating and drying the coating.

16. The process of claim 6 wherein the plastic sheet is preformed and then applied to the release support.

7. A process for producing a composite material from

a. a homogeneous or microporous plastics sheet and

b. a polyurethane foam, which comprises spread coating on a release support a polyurethane foam having a density of about 0.04 to about 0.40 g/cm³ which has been produced by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0 μ

,

applying and lightly pressing a solid, self-supporting homogeneous or microporous plastics sheet to the still liquid foam, drying and removing the release support.

8. A process for producing a composite material from

a. a homogeneous or microporous plastics sheet and

b. a polyurethane foam,

which comprises spread coating on a release support a polyurethane foam having a density of about 0.04 to about 0.40 g/cm³, which has been produced by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0 μ

,

drying the coating, applying a liquid plastics coating compound on the coating, solidifying the liquid plastics coating compound on the layer of foam to produce a homogeneous or microporous plastics sheet and removing the release support.

9. A process for producing a composite material from

a. a plastics sheet,

b. a polyurethane foam and

c. a textile material

which comprises applying a homogeneous or microporous plastics sheet to a release support, spread coating on the sheet a polyurethane foam having a density of from about 0.04 to about 0.40 g/cm³, which has been produced by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0 μ

,

applying a textile material to the foam while the foam is still liquid, drying and removing the release support.

17. The process of claim 9 wherein the textile is a woven or knitted textile or a non-woven web.

13. A process for producing a composite material consisting of a polyurethane foam and a woven or knitted textile material or consisting of a polyurethane foam and a non-woven web, which comprises spreadcoating a polyurethane foam having a density of from about 0.04 to about 0.40 g/cm³ which has been produced by mechanically frothing a nonionogenic aqueous polyurethane dispersion having

i. a solids content of more than about 45% by weight of polyurethane,

ii. a viscosity of about 10 to about 70 seconds outflow time from a Ford cup with 4 mm nozzle and

iii. a particle diameter of less than 1.0 μ

,

on a release support and then laminating the coating to the textile material or to the non-woven web, drying the laminate and removing the release support.

14. A process for producing a self-supporting polyurethane foam sheet which comprises preparing a spread-coatable polyurethane foam from a nonionic aqueous polyurethane dispersion having

a. a solids content of more than 45% by weight of polyurethane,

b. a viscosity of 10-70 seconds outflow time from a Ford cup with 4 mm nozzle,

c. a particle diameter of less than 1.0μ

, and

d. 0.1-10% by weight of thickener, based on the polyurethane solids content by the churning process, applying the foam to a release support, drying, and removing the release support.

19. A process for making a polyurethane foam sheet adapted to be laminated with a textile which comprises mechanically frothing a nonionic aqueous dispersion free from emulsifying agents of a polyurethane having a particle size of less than 1 micron, said dispersion containing more than 45 % by weight polyurethane and a thickening agent whereby the viscosity of the dispersion is from about 10 to about 70 seconds with a Ford cup having a 4 mm orifice to form a foamable mixture stirring air into said mixture, spreading the frothed dispersion into a film and drying the resulting product.

20. The process of claim 19 wherein the thickening agent is polyvinyl pyrrolidone.

21. The process of claim 19 wherein the said film is spread over a release support.