Coated architectural glass system and method

• US 3,990,784 A
• Filed: 06/05/1974
• Issued: 11/09/1976
• Est. Priority Date: 06/05/1974
• Status: Expired due to Term

• Current Assignee: Optical Coating Laboratory, Inc. (Lumentum Holdings Inc.)
• Original Assignee: Optical Coating Laboratory, Inc. (Lumentum Holdings Inc.)
• Inventors: Gelber, Robert M.
• Primary Examiner(s): Weiffenbach, Cameron K.
• Assistant Examiner(s): Varndell, Jr., R. Eugene
• Application Number:
  US05/476,684
• Time in Patent Office: 888 Days
• Field of Search: 117/71 R, 117/33.3, 117/211, 117/217, 350/164, 350/166, 427/162, 427/163, 427/164, 427/165, 427/166, 427/167, 427/168, 427/169, 427/404, 427/419, 428/432
• US Class Current: 359/589
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/361 Coatings of the type glass/metal/inorganic compound/metal/inorganic compound/other
• CPC Class Codes: C03C 17/3613 Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 2217/73 Anti-reflective coatings with specific characteristics
• CPC Class Codes: E06B 3/6715 specially adapted for increased thermal insulation or for controlled passage of light E06B3/66323 takes precedence; coating of glass pains C03C17/00; devices or arrangements for controlling the intensity, colour, phase, polarisation or direction of light G02F1/00
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 1/116 including electrically conducting layers

Abstract

Coated architectural glass system having a transparent substrate with a surface and a multi-layer coating disposed on the surface. The multi-layer coating comprises first and second metal layers and a dielectric layer disposed between the first and second metal layers. The first and second metal layers have a thickness ratio so that the transmission of the coating can be changed independent of its reflection properties, by varying the thickness of the metal layers while maintaining the ratio constant. The dielectric has a thickness such that the reflection from the coating is not strongly colored in the region of 400 millimicrons to approximately 700 millimicrons. In the method, the transmission of the coating can be changed merely by varying the thickness of the first and second metal layers in accordance with a thickness ratio.

Claims

1. In a coated article, a substrate having a surface and a multi-layer coating formed on said surface, said multi-layer coating comprising first and second metal layers and a dielectric layer disposed between said first and second metal layers with said first metal layer being thinner than the second metal layer so that the solar transmission of the coating can be changed independent of the reflection properties of the coating by varying the thickness of the first and second metal layers while maintaining the ratio of thickness of the metal first and second layers substantially constant, said dielectric layer having a thickness such that the reflection from the substrate side is not strongly colored in the region of 450 to 650 millimicrons.

2. An article as in claim 1 wherein said reflection from the substrate side is less than 5%.

3. An article as in claim 1 wherein the coating has low reflection when viewed from the substrate side and wherein the dielectric layer disposed between the first and second metal layers has a low to medium index of refraction ranging from 1.38 to 1.90.

4. An article as in claim 1 wherein the coating has low reflection when viewed from the medium side and wherein the dielectric spacer layer between the first and second metal layers has a high index of refraction ranging from 1.90 to 2.35.

5. An article as in claim 4 wherein the coating includes a layer formed of a material having a low index of refraction and being disposed so that it is adjacent the first metal layer counting from the medium and on the side of the first metal layer facing the medium.

6. An article as in claim 3 wherein said material forming the dielectric spacer layer has an index of refraction of 1.45.

7. An article as in claim 4 wherein the dielectric spacer layer has an index of refraction of approximately 2.2.

8. An article as in claim 5 wherein the dielectric spacer layer has an index of refraction of approximately 2.2.

9. An article as in claim 1 together with an additional dielectric layer for changing the color of the reflectance of the article as seen from one side of the article.

10. An article as in claim 9 wherein the material forming said dielectric layer for changing color has a low to medium index of refraction.

11. An article as in claim 9 wherein said dielectric layer has a high index of refraction.

12. An article as in claim 1 together with an additional pane of glass facing the coating on the substrate for protecting said coating.

13. In an architectural glass system for use in a building having an inner enclosed area, a pane of glass having a first surface and a second surface and a multi-layer coating formed on said first surface, said multi-layer coating comprising first and second metal layers and a dielectric spacer layer disposed between the first and second metal layers, said first and second metal layers having a thickness ratio with said first metal layer being thinner than said second metal layer whereby the solar transmission of the coating can be changed by varying the thickness of the first and second metal layers in accordance with the thickness ratio of the first and second metal layers to change the solar transmission without appreciably changing the reflectance properties of the coating.

14. A system as in claim 13 wherein said first surface is adapted to face away from the inner enclosed area and wherein the coating is formed on said first surface with said first metal layer being closer to said first surface than said second metal layer.

15. A system as in claim 13 together with an additional dielectric layer formed on said second metal layer to provide a reflected color as viewed in looking toward the first surface of the pane of glass from the outside of the building.

16. A system as in claim 13 together with an additional pane of glass facing the coating on the pane of glass for protecting said coating.

17. A system as in claim 13 wherein said first surface faces inwardly of the building with the thicker of the metal layers being closer to said first surface and a dielectric layer formed on said thinner metal layer on the side facing away from said first surface, said dielectric layer on said thinner metal layer being formed of a low index material, said dielectric layer between said metal layers being formed of a high index material.

18. A system as in claim 17 together with an additional dielectric layer formed between the thick metal layer and the glass surface to provide a reflector color as viewed in looking toward the second surface of the pane of the glass.

19. A system as in claim 17 together with an additional pane of glass facing the coating on the pane of glass for protecting said coating on said first named pane of glass.

20. In a method for coating a substrate of the type which is substantially transparent and has an index of refraction of 1.50 to 1.52 and having a surface, deposition upon said surface first and second metal layers with a dielectric spacer layer of dielectric material disposed therebetween with the first metal layer being thinner than the second metal layer and varying the thickness of the first and second metal layers while maintaining the ratio of thickness of the first and second metal layers substantially constant to thereby change the solar transmission of the coating independent of the reflection properties of the coating,

21. A method as in claim 20 together with the step of adding an additional dielectric layer to said coating and changing the thickness of the additional dielectric layer to change the color of the coating as seen from one side of the substrate.

22. A method as in claim 21 together with the step of adding an additional dielectric layer adjacent the thinner metal layer to provide an anti-reflection match between the coating and air.

23. A method as in claim 21 wherein said dielectric spacer layer is formed of a low index material having an index of refraction ranging from 1.38 to 1.9.

24. A method as in claim 21 wherein said dielectric spacer layer is formed of material having a high index of refraction ranging from 1.9 to 2.35.