System for pollution suppression

• US 3,998,714 A
• Filed: 12/09/1974
• Issued: 12/21/1976
• Est. Priority Date: 04/23/1964
• Status: Expired due to Term

• Current Assignee: Edward T. Armstrong
• Original Assignee: TII Corporation
• Inventors: Armstrong, Edward T.
• Primary Examiner(s): Hart, Charles N.
• Assistant Examiner(s): Spitzer, Robert H.
• Application Number:
  US05/531,095
• Time in Patent Office: 743 Days
• Field of Search: 210/50, 210/49, 210/62-64, 210/53
• US Class Current: 210/752
• CPC Class Codes: A61L 2/16 using chemical substances
• CPC Class Codes: A61L 2/20 Gaseous substances, e.g. vapours
• CPC Class Codes: B01D 21/00 Separation of suspended solid particles from liquids by sedimentation separation of ores or the like by sedimentation B03B5/48 - B03B5/60 ; differential sedimentation B03D3/00; purification of water, waste water, sewage or sludge C02F, e.g. devices for separating or removing fatty or oily substances or similar floating material from water, waste water or sewage C02F1/40
• CPC Class Codes: B01D 21/01 using flocculating agents for purifying water C02F1/52; for liquid radioactive waste G21F9/10
• CPC Class Codes: B01D 21/14 with rotating scrapers
• CPC Class Codes: B01D 21/24 Feed or discharge mechanisms for settling tanks
• CPC Class Codes: B01D 21/30 Control equipment
• CPC Class Codes: C01B 13/10 Preparation of ozone
• CPC Class Codes: C01B 13/11 by electric discharge
• CPC Class Codes: C01B 2201/66 Pretreatment of the feed
• CPC Class Codes: C02F 1/24 by flotation C02F1/465 takes precedence
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 1/76 with halogens or compounds of halogens C02F1/4674 takes precedence
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 3/006 Regulation methods for biological treatment
• CPC Class Codes: C02F 3/02 Aerobic processes
• CPC Class Codes: C02F 3/04 using trickle filters
• CPC Class Codes: C02F 3/043 Devices for distributing water over trickle filters
• CPC Class Codes: C02F 3/121 Multistep treatment
• CPC Class Codes: C02F 3/302 Nitrification and denitrification treatment C02F3/308 takes precedence
• CPC Class Codes: C02F 3/34 : characterised by the microorganisms used
• CPC Class Codes: C02F 9/00 : Multistage treatment of water, waste water or sewage
• CPC Class Codes: F16L 55/02 : Energy absorbers; Noise absorbers in valves F16K47/00
• CPC Class Codes: F16L 55/045 : specially adapted to prevent or minimise the effects of water hammer
• CPC Class Codes: Y02W 10/10 : Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 423/09 : Reaction techniques
• CPC Class Codes: Y10S 423/17 : Microbiological reactions

Abstract

The present invention relates to a two stage oxidative system for the disinfection of material which may contain nitrogen commonly in the form of ammonia or ammonium as in the treatment of waste or sewage plant effluent by adding a primary oxidizing agent to the effluent to disinfect as well as to lower the pH of the effluent and by adding a secondary oxidizing agent to produce a synergistic disinfection system in which the distribution of ammonium and ammonia is shifted to nearly all ammonium. A desirable pH level is 7 or less with desirable primary oxidizing agents including aluminum chloride or ferric chloride with desirable secondary oxidizing agents including chlorine, chlorine dioxide, ozone as in oxygen or air, or sodium hypochlorite. The invention further relates to an activated sludge aeration system in which desirably there are no stagnant areas and maximum diffusion is achieved, efficiently.

The invention further relates to a continuous treatment of a fluid by chemical reaction with a treating fluid as in an in-line reactor.

The invention also relates to the efficient production of ozone by varying the oxygen feed rate, voltage, current or frequency or the ozone in oxygen concentration.

The invention also relates to the enrichment of oxygen by adding air to a high-pressure holding tank containing a liquid in which oxygen is soluble, bleeding off nitrogen-rich gas and desorbing gas from the liquid at a lower pressure.

Claims

1. A two stage oxidative process for disinfection of material containing a distribution of ammonia-ammonium compounds, comprising,

adding a primary oxidizing agent to the material to disinfect and to reduce the pH level of said material,

said primary oxidizing agent selected from the class consisting of ferric chloride and aluminum chloride,

adding a secondary oxidizing agent to the material to obtain a very low bacteria count and a substantial amount of ammonium compounds,

said secondary oxidizing agent selected from the class consisting of chlorine, chlorine dioxide, ozone and sodium hypochloride,

the amount of said primary oxidizing agent added is sufficient to cause said pH of said material to be 7.0 or less,

said amount of primary oxidizing agent being at least 50 parts per million,

the amount of said secondary oxidizing agent being at least 0.7 parts per million for ozone and at least 4.0 parts per million for said chlorine, chlorine dioxide and sodium hypochloride,

said material being selected from the class consisting of sewage effluent, potable water and process water,

the amount of said ammonium compounds to said ammonia compounds produced being at least 97 percent,

said primary oxidizing agent being added to a first stage and, said secondary oxidizing agent being added to a second stage,

said second stage having a conduit located therein, said conduit containing a turbulence-causing device,

said turbulence-causing device being a flat plate orifice, an injection tube having a tip extending through said flat plate orifice,

said tip of said injection tube being located in the vena contracta portion of said flat plate orifice, and said secondary oxidizing agent being injected into said conduit through said injection tube.

2. A two stage oxidative process for disinfection according to claim 1, wherein the maximum amount of said secondary oxidizing agent is about 10 parts per million and wherein said injection tube tip is located from about 0.25 to about 0.50 conduit diameters downstream from said flat plate orifice.

3. A two stage oxidative process for disinfection according to claim 2, wherein a conduit is located in said first stage, a flat plate orifice being located in said conduit, said first plate orifice having a diameter of from about 0.7 to about 0.9 of the conduit diameter, an injection tube having a tip extending through said flat plate orifice, said injection tube tip being located in the vena contracta of said flat plate orifice, and said primary oxidizing agent being added through said injection tube.

4. A two stage oxidative process for disinfection according to claim 3, wherein said injection tube tip is located from 0.25 to about 0.5 conduit diameters down stream from said flat plate orifice.

5. A two stage oxidative process for disinfection according to claim 4, including a final clarifier influent and effluent of a waste treatment plant, said conduit and injection tube injecting said primary oxidizing agent located in a clarifier stream selected from the class consisting of a final clarifier influent and a final clarifier effluent of said waste treatment process and said conduit and a disinfection or contact tank influent of a waste treatment plant, said injection tube injecting said secondary oxidizing agent located in said disinfection contact tank influent.

6. A two stage oxidative process for disinfection according to claim 5, wherein said pH ranges from about 6.7 to about 6.8.

7. A two stage oxidative process for disinfection according to claim 6 wherein said secondary oxidizing agent is selected from the class consisting of ozone and chlorine.

8. A two stage oxidative process for disinfection according to claim 7, wherein the amount of said primary oxidizing agent is approximately 85 parts per million.

9. A two stage oxidative process for disinfection according to claim 8, wherein said injection tube tip in said primary oxidizing conduit and said injection tube tip in said secondary oxidizing conduit is located from about 0.36 to about 0.39 conduit diameters downstream from each respective said flat plate orifice.