Alkyl sulfate detergent compositions

• US 4,000,093 A
• Filed: 04/02/1975
• Issued: 12/28/1976
• Est. Priority Date: 04/02/1975
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Nicol, Charles Henry, Burns, Michael Eugene
• Primary Examiner(s): Pitlick, Harris A.
• Application Number:
  US05/560,764
• Time in Patent Office: 636 Days
• Field of Search: 252/531, 252/550, 252/DIG. 15, 252/DIG. 2, 252/529
• US Class Current: 510/299
• CPC Class Codes: C11D 1/146 Sulfuric acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 3/0036 Soil deposition preventing compositions; Antiredeposition agents
• CPC Class Codes: C11D 3/225 etherified, e.g. CMC

Abstract

Cellulose-based soil release ethers are used in detergent compositions containing C₁₀ -C₁₃ alkyl sulfate surfactants, and substantially free from interfering amounts of longer-chain length alkyl sulfates, to provide optimal soil release performance.

Claims

1. A detergent composition comprising:

a. from about 5% to about 50% by weight of a surfactant component consisting essentially of a water-soluble alkyl sulfate wherein the alkyl substituent has a chain length in the range of C₁₀ -C₁₃, or mixtures thereof, said surfactant component containing less than about 5% by weight of C₁₅ and higher alkyl sulfates;

b. from about 1% to about 5% by weight of a water-soluble alkyl sulfate wherein the alkyl substituent is C₁₄ ;

c. from about 0.1% to about 3% by weight of a soil release ether component selected from the group consisting of alkyl cellulose ethers, hydroxyalkyl cellulose ethers and hydroxyalkyl alkyl cellulose ethers;

d. from about 0% to about 70% by weight of a detergency builder component; and

e. the balance of the composition comprising detergency adjunct materials and carriers selected from the group consisting of perfumes, optical bleaches, fillers, anti-caking agents, fabric softeners, perborate bleaches, enzymes, water, water-alcohol mixtures and mixtures thereof.

2. A composition according to claim 1 characterized by a weight ratio of surfactant component:

soil release ether component in the range of from about 5;

1 to about 100;

1.

3. A composition according to claim 2 wherein the surfactant component is selected from the group consisting of the alkali metal, ammonium and alkanolammonium salts of C₁₀ -C₁₃ alkyl sulfates, and mixtures thereof.

4. A composition according to claim 3 wherein the surfactant component is in the sodium salt form.

5. A composition according to claim 2 wherein the soil release ether component is an alkyl cellulose ether having a DS alkyl of from about 1.7 to about 3.0.

6. A composition according to claim 2 wherein the alkyl cellulose ether is selected from the group consisting of methyl, ethyl, propyl and butyl cellulose ethers having a DS alkyl of from about 1.2 to about 2.9.

7. A composition according to claim 6 wherein the alkyl cellulose ether is a methyl cellulose ether characterized by a DS methyl in the range from about 2.0 to about 2.7.

8. A composition according to claim 2 wherein the soil release ether component is a hydroxyalkyl cellulose ether having a DS hydroxyalkyl of from about 1.2 to about 2.9.

9. A composition according to claim 8 wherein the hydroxyalkyl cellulose ether is selected from the group consisting of hydroxyethyl, hydroxypropyl and hydroxybutyl cellulose ethers having a DS hydroxyalkyl of from about 1.3 to about 1.7.

10. A composition according to claim 2 wherein the soil release ether component is a hydroxyalkyl alkyl cellulose ether having a DS hydroxyalkyl of at least about 0.01 and a DS alkyl of at least about 1.0.

11. A composition according to claim 10 wherein the hydroxyalkyl substituent in the hydroxyalkyl alkyl cellulose ether is independently selected from the group consisting of hydroxyethyl, hydroxypropyl and hydroxybutyl wherein the DS hydroxyalkyl is at least about 0.05 and wherein the alkyl substituent is independently selected from methyl, ethyl, propyl and butyl wherein the DS alkyl is at least about 1.0.

12. A composition according to claim 10 wherein the hydroxyalkyl alkyl cellulose ether is characterized by a DS alkyl in the range of from about 1.7 to about 2.7 and a DS hydroxyalkyl in the range of from about 0.01 to about 1.0.

13. A composition according to claim 12 wherein the DS alkyl of the cellulose ether is from about 1.8 to about 2.2 and the DS hydroxyalkyl is from about 0.06 to about 1.0.

14. A granular detergent composition according to claim 2 comprising from about 15% to about 65% by weight of a water-soluble detergency builder.

15. A composition according to claim 14 wherein the builder is an inorganic detergency builder.

16. A composition according to claim 15 wherein the inorganic builder is sodium tripolyphosphate.

17. A composition according to claim 16 wherein the builder is an organic detergency builder.

18. A composition according to claim 17 wherein the organic builder is sodium nitrilotriacetate.

19. A composition according to claim 2 wherein the detergency builder is a seeded builder.

20. A composition according to claim 19 wherein the seeded builder comprises a 30:

1 to 5;

1 weight mixture of sodium carbonate and particulate calcium carbonate having an average particle diameter from 0.01 microns to 5 microns.

21. A composition according to claim 2 wherein the detergency builder is substantially water-insoluble.

22. A composition according to claim 21 wherein the detergency builder is a zeolite-type material.

23. A composition according to claim 2, said composition comprising from about 0.5% to about 1.5% by weight of the soil release ether component.

24. A composition according to claim 5 wherein the DS alkyl is from about 1.7 to about 2.7.

25. A composition according to claim 24 wherein the alkyl cellulose ether is a methyl cellulose ether characterized by a DS methyl in a range from about 1.8 to about 2.2.

26. A composition according to claim 13 wherein the hydroxyalkyl alkyl cellulose ether is a methyl hydroxybutyl cellulose characterized by a DS methyl in a range from about 1.8 to about 2.2 and a DS hydroxybutyl of about 0.08.