Adsorption process

• US 4,000,990 A
• Filed: 04/16/1975
• Issued: 01/04/1977
• Est. Priority Date: 04/16/1975
• Status: Expired due to Term

• Current Assignee: NRG Nufuel Company, Reserve Synthetic Fuels Incorporated
• Original Assignee: NRG Nufuel Company, Reserve Synthetic Fuels Incorporated
• Inventors: Bingham, Larry A.
• Primary Examiner(s): Spear, Jr., Frank A.
• Assistant Examiner(s): Cross, Ethel R.
• Application Number:
  US05/568,668
• Time in Patent Office: 629 Days
• Field of Search: 210/30, 55/25, 55/26, 55/58, 55/62, 55/76
• US Class Current: 95/103
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/116 Molecular sieves other than zeolites
• CPC Class Codes: B01D 2256/16 Hydrogen
• CPC Class Codes: B01D 2256/245 Methane
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/306 Organic sulfur compounds, e.g. mercaptans
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/702 Hydrocarbons
• CPC Class Codes: B01D 2257/7025 Methane
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 2258/05 Biogas
• CPC Class Codes: B01D 2259/40001 Methods relating to additional, e.g. intermediate, treatment of process gas
• CPC Class Codes: B01D 2259/4003 with two sub-steps
• CPC Class Codes: B01D 2259/40064 Five
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 2259/403 using three beds
• CPC Class Codes: B01D 53/0476 Vacuum pressure swing adsorption
• CPC Class Codes: B01D 53/261 : by adsorption
• CPC Class Codes: Y02C 20/20 : of methane
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

A process for purifying a fluid stream which includes an impurity and a product fluid comprising providing three adsorption zones, cycling each of the adsorption zones on stream for the adsorption of the impurity from the fluid stream in a predetermined sequence to provide a substantially uninterrupted flow of the product fluid from the adsorption zones, desorbing the impurity from each of the adsorption zones in a predetermined sequence by sequentially reducing the pressure within each of the adsorption zones sufficiently to desorb the impurity, and repressurizing each of the adsorption zones subsequent to the desorption of such adsorption zone to make such adsorption zone ready for subsequent use for on stream adsorption of the impurity. The duration of the period of desorption for each of the adsorption zones is at least as great as about the duration of the period of on stream adsorption of the impurity. The desorption of a first of the adsorption zones occurs during at least the latter portion of the period that a second of the adsorption zones is on stream for the adsorption of the impurity and during at least an initial portion of the period that a third of the adsorption zones is on stream for the adsorption of the impurity.

Claims

1. A process for purifying a fluid stream which includes an impurity and a product fluid, said process comprising:

providing at least three adsorption zones each of which has an inlet and an outlet, each of the adsorption zones including adsorbent material capable of selectively adsorbing the impurity from the fluid stream;

introducing the fluid stream into the inlet of the first of said adsorption zones and contacting the fluid stream with the adsorbent material of the first adsorption zone at a first pressure to thereby adsorb the impurity in the adsorbent material and provide product fluid;

discharging the product fluid from the outlet of said first adsorption zone during first and second periods;

reducing the pressure in a second of the adsorption zones during the first period to a second pressure which is less than said first pressure, said second adsorption zone having previously been used for adsorption of the impurity from the fluid stream;

reducing the pressure in the second adsorption zone during at least a portion of the second period to a third pressure which is less than said second pressure and which is less than atmospheric pressure to desorb at least some of the impurity from the second adsorption zone;

providing a pressure in a third of the adsorption zones during at least a portion of the first period which is less than said second pressure and which is less than atmospheric pressure to desorb at least some of the impurity from the third adsorption zone, said third adsorption zone having previously had the pressure therein reduced to about the second pressure;

repressurizing the third adsorption zone during at least a portion of the second period;

terminating the introduction of the fluid stream into the inlet of said first adsorption zone and the repressurization of said third adsorption zone;

introducing the fluid stream into the inlet of the third adsorption zone to adsorb the impurity in the adsorbent material of the third adsorption zone and to provide product fluid;

discharging the product fluid from the outlet of said third adsorption zone during a third period; and

maintaining the pressure in said second adsorption zone below atmospheric pressure during at least a portion of the third period to desorb some of the impurity from the third adsorption zone during the third period.

2. A process as defined in claim 1 wherein said first mentioned step of reducing includes venting the second adsorption zone to approximately atmospheric pressure.

3. A process as defined in claim 1 including venting the first adsorption zone to approximately atmospheric pressure during the third period.

4. A process as defined in claim 1 wherein the process is carried out with three of said adsorption zones.

5. A process as defined in claim 1 including reducing the pressure in said first adsorption zone during at least a portion of the third period to lower the pressure in said first adsorption zone to about said second pressure, said second mentioned step of reducing includes evacuating the second adsorption zone, said process includes terminating the evacuation of said second adsorption zone and then initiating the evacuation of said first adsorption zone.

6. A process as defined in claim 1 wherein product fluid is discharged from the first adsorption zone substantially continuously throughout the first and second periods with said first, second and third periods occurring in sequence substantially without any interval therebetween.

7. A process as defined in claim 1 wherein the interval that product fluid is discharged from the first adsorption zone is no greater in duration than about the interval that impurity is being removed from the second adsorption zone.

8. A process as defined in claim 1 wherein said first adsorption zone includes first and second generally upright towers with each of said towers containing adsorbent material capable of selectively adsorbing the impurity from the fluid stream, said towers being coupled in series with said inlet being on said first tower and said outlet being on said second tower, said fluid stream passing through said towers in series.

9. A process as defined in claim 1 including providing at least first and second pretreating zones with each of the pretreating zones including adsorbent material at least a portion of which is different from the adsorbent material in said three adsorption zones and capable of selectively adsorbing a first portion of the impurity from the fluid stream, introducing the fluid stream into the first pretreating zone and contacting the fluid stream with the adsorbent material in said first pretreating zone to adsorb said first portion of the impurity in such adsorbent material and to provide a partially purified fluid stream, introducing the partially purified fluid stream into the inlet of said first adsorption zone and desorbing the second pretreating zone during at least a portion of the time that the fluid stream is contacting the adsorbent material in the first pretreating zone.

10. A process as defined in claim 9 wherein each of said first adsorption zones includes first and second towers with each of said towers containing adsorbent material capable of selectively adsorbing the impurity from the fluid stream, said towers of each of said adsorption zones being coupled in series with said inlet of each of said adsorption zones being on the first tower thereof and the outlet of each of said adsorption zones being on the second tower thereof.

11. A process for purifying a fluid stream which includes an impurity and a product fluid, said process comprising:

providing three adsorption zones each of which has an inlet and an outlet, each of the adsorption zones including adsorbent material capable of selectively adsorbing the impurity from the fluid stream;

cycling each of the adsorption zones on stream for the adsorption of the impurity from the fluid stream in a predetermined sequence to provide a substantially uninterrupted flow of the product fluid from the adsorption zones;

said step of cycling including introducing the fluid stream into a first of the adsorption zones to adsorb impurity and provide the product fluid, terminating the introduction of the fluid stream into the first adsorption zone and introducing the fluid stream into a second of the adsorption zones to adsorb impurity and provide the product fluid;

desorbing the impurity from each of the adsorption zones in a predetermined sequence by sequentially reducing the pressure within each of the adsorption zones sufficiently to desorb the impurity;

the durations of the periods of desorption for each of the adsorption zones being at least as great as about the durations of the periods of on stream adsorption of the impurity for such adsorption zones, respectively;

repressurizing each of the adsorption zones subsequent to the desorption of such adsorption zone to make such adsorption zone ready for subsequent use for on stream adsorption of the impurity; and

said step of cycling being carried out so that the desorption of a third of the adsorption zones occurs during at least the latter portion of the period that the first adsorption zone is on stream for the adsorption of the impurity and during at least an initial portion of the period that the second adsorption zone is on stream for the adsorption of the impurity.

12. A process as defined in claim 11 wherein said step of desorbing includes sequentially reducing the pressure in each of said adsorption zones to a pressure less than atmospheric pressure with the termination of the desorption in one of the adsorption zones and the initiation of the desorption of the next of the adsorption zones to be desorbed occurring at about the same time.

13. A process as defined in claim 11 wherein the repressurization of the first adsorption zone is carried out for a period which is of less duration than the period of on stream adsorption of the first adsorption zone and of less duration than the period of desorption for the first adsorption zone.

14. A process for purifying a fluid stream which includes an impurity and a product fluid, said process comprising:

providing first and second pretreating zones with each of the zones including adsorbent material capable of selectively adsorbing at least a portion of the impurity from the feed fluid stream;

passing the feed fluid stream through the first pretreating zone and contacting the feed fluid stream with the adsorbent material thereof to adsorb said portion of the impurity in the adsorbent material and provide a partially purified fluid stream;

desorbing the second pretreating zone during at least a portion of the period that the first pretreating zone is providing a partially purified fluid stream;

providing at least two primary adsorption zones each of which includes first and second generally upright towers and adsorbent material in each of said towers capable of selectively adsorbing the impurity from the fluid stream, each of said primary adsorption zones having an inlet on the first tower thereof and an outlet on the second tower thereof;

passing the partially purified fluid stream in series through the first and second towers of the first primary adsorption zone from the inlet of the first primary adsorption zone and contacting the fluid stream with the adsorbent material in said first and second towers of the first primary adsorption zone at a first pressure to thereby adsorb the impurity on the adsorbent material of the first primary adsorption zone and provide product fluid;

discharging product fluid from the outlet of the first primary adsorption zone;

desorbing the second primary adsorption zone which has previously been on stream for the adsorption of impurity to remove the impurity therefrom for at least a portion of the period that the product fluid is being discharged from the first adsorption zone;

terminating the adsorption in said towers of said first primary adsorption zone and thereafter desorbing the first adsorption zone; and

terminating the impurity removal from said second primary adsorption zone and thereafter passing the partially purified fluid stream in series through the first and second towers of the second primary adsorption zone to adsorb the impurity on the adsorbent material of the second primary adsorption zone and provide product fluid.

15. A process as defined in claim 14 wherein said step of desorbing includes exposing the towers of the second adsorption zone in series to a relatively low pressure.

16. A process as defined in claim 14 including providing a third primary adsorption zone including first and second generally upright towers and adsorbent material in each of said towers capable of selectively adsorbing the impurity from the fluid stream, said third primary adsorption zone having an inlet on the first tower thereof and an outlet on the second tower thereof, said first mentioned step of desorbing includes reducing the pressure in the towers of the second primary adsorption zone to a second pressure which is sufficiently low to remove the impurity from the second primary adsorption zone, and depressurizing the third primary adsorption zone which has been previously on stream for the adsorption of impurity to a third pressure during at least a portion of the period that the first primary adsorption zone is on stream for the adsorption of impurity, said third pressure being intermediate said first and second pressures.

17. A process as defined in claim 16 wherein the towers of said second adsorption zone are countercurrently desorbed in series and the towers of said third adsorption zone are countercurrently depressurized in series.

18. A process as defined in claim 14 wherein each of the pretreating zones includes adsorbent material different from the adsorbent material in said two primary adsorption zones.

19. A process of obtaining methane from a sanitary landfill comprising:

extracting a feed fluid stream containing methane and an impurity from a sanitary landfill;

providing first and second pretreating zones with each of the zones including adsorbent material capable of selectively adsorbing at least a portion of the impurity from the feed fluid stream;

passing the feed fluid stream through the first pretreating zone and contacting the feed fluid stream with the adsorbent material thereof to adsorb said portion of the impurity in the adsorbent material and provide a partially purified fluid stream;

desorbing the second pretreating zone during at least a portion of the period that the first pretreating zone is providing a partially purified fluid stream;

providing at least three adsorption zones each of which has an inlet and an outlet and includes adsorbent material capable of selectively adsorbing at least a second portion of the impurity from the partially purified fluid stream;

introducing the partially purified fluid stream into the inlet of the first of said adsorption zones and contacting the partially purified fluid stream with the adsorbent material of the first adsorption zone at a first pressure to thereby adsorb the second portion of the impurity in the adsorbent material and to provide substantially pure methane;

discharging the methane from the outlet of said first adsorption zone during a first period;

reducing the pressure in a second of the adsorption zones to a second pressure during the first period, said second adsorption zone having been previously used to adsorb the second portion of the impurity from the partially purified fluid stream;

providing a third pressure in a third of the adsorption zones during a portion of the first period with the third pressure being sufficiently low to remove at least some of the impurity from the adsorbent material of the third adsorption zone, said third adsorption zone having been previously reduced to said second pressure;

repressurizing the third adsorption zone during a portion of the first period;

terminating the introduction of the partially purified fluid stream into the first adsorption zone at the end of the first period;

introducing the partially purified fluid stream into the inlet of the third adsorption zone and contacting the partially purified fluid stream with the adsorbent material of the third adsorption zone to thereby adsorb the second portion of the impurity in the adsorbent material and to provide substantially pure methane;

discharging the methane from the outlet of said third adsorption zone during a second period;

reducing the pressure in the second adsorption zone to a desorption pressure less than said second pressure and sufficiently low to remove at least some of the impurity from the adsorbent material of the second adsorption zone; and

maintaining said desorption pressure in said second adsorption zone for a portion of said first period and a portion of said second period.

20. A process as defined in claim 19 wherein the step of desorbing the second pretreating zone includes thermally desorbing the second pretreating zone.

21. A process as defined in claim 19 wherein said first mentioned step of reducing includes depressurizing the second adsorption zone to a first pressure level and recycling the partially purified feed gas trapped in the second adsorption zone, terminating said recycling, and subsequently venting the second adsorption zone to the second pressure.

22. A process as defined in claim 19 wherein said first adsorption zone includes first and second upright towers and said step of contacting the partially purified fluid stream with the adsorbent material of the first adsorption zone includes passing the partially purified fluid stream in series through the first and second towers of the first adsorption zone.