Anode moderator for reactive metal electrochemical cells

• US 4,001,043 A
• Filed: 05/23/1975
• Issued: 01/04/1977
• Est. Priority Date: 05/23/1975
• Status: Expired due to Term

• Current Assignee: Lockheed Martin Space Operations Company (Martin Marietta Corporation)
• Original Assignee: Lockheed Martin Space Operations Company (Martin Marietta Corporation)
• Inventors: Momyer, William R.
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US05/580,303
• Time in Patent Office: 592 Days
• Field of Search: 136/6 R, 136/6 F, 136/100 R, 136/83 R, 136/155, 136/154
• US Class Current: 429/206
• CPC Class Codes: H01M 12/04 composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
• CPC Class Codes: H01M 6/04 Cells with aqueous electrolyte

Abstract

In a reactive metal-water electrochemical cell, an alkaline electrolyte, containing soluble peroxide ions which improve the uniformity of reaction at the anode, reduces the anode'"'"'s sensitivity to changes in the hydroxyl ion concentration of the electrolyte, reduces the anode'"'"'s sensitivity to electrolyte flow rate and reduces the anode'"'"'s sensitivity to temperature. The improved characteristics of the cell result from the ability of the peroxide ions to stabilize the anode and also to be reduced at a more electronegative potential than is required for the reduction of water. The soluble peroxide ion, HO₂^-, is formed when hydrogen peroxide, sodium peroxide and other soluble inorganic peroxide compounds are dissolved in the alkaline solution.

Claims

1. An electrochemical cell consisting essentially of a lithium anode spaced from a cathode by an electrically insulating film formed on said anode in the presence of water, an aqueous lithium hydroxide electrolyte in which said anode and cathode are immersed, and an anode moderator for improving the efficiency of said cell by reducing the said anode'"'"'s sensitivity to changes in electrolyte molarity, flow rate and temperature, said anode moderator consisting essentially of soluble peroxide ions.

2. An electrochemical cell in accordance with claim 1, wherein said soluble peroxide ions are formed from soluble peroxide compounds selected from the group consisting of hydrogen peroxide, sodium peroxide, sodium super oxide, lithium peroxide, potassium peroxide and potassium super oxide.

3. An electrochemical cell in accordance with claim 2, wherein said soluble peroxide compound is hydrogen peroxide.

4. An electrochemical cell in accordance with claim 2, wherein said soluble peroxide compound is sodium peroxide.

5. An electrochemical cell in accordance with claim 2, wherein said soluble peroxide compound is lithium peroxide.

6. An electrochemical cell in accordance with claim 2, wherein said soluble peroxide compound is potassium peroxide.

7. An electrochemical cell in accordance with claim 2, wherein sufficient peroxide ions are utilized to sustain the desired current density of the cell with the maximum amount being dictated by the production of excess heat and spontaneous decomposition of said anode.