Method and arrangement for measuring the concentration of gases

• US 4,003,707 A
• Filed: 02/26/1976
• Issued: 01/18/1977
• Est. Priority Date: 02/28/1975
• Status: Expired due to Term

• Current Assignee: Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften e.V. (Max-Planck-Gesellschaft zur Frderung der Wissenschaften e)
• Original Assignee: Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften e.V. (Max-Planck-Gesellschaft zur Frderung der Wissenschaften e)
• Inventors: Lubbers, Dietrich W., Opitz, Norbert
• Primary Examiner(s): Reese, Robert M.
• Application Number:
  US05/661,636
• Time in Patent Office: 327 Days
• Field of Search: 23/232 R, 23/232 E, 23/254 R, 23/254 E, 356/39, 356/85
• US Class Current: 436/172
• CPC Class Codes: G01N 2021/6434 Optrodes
• CPC Class Codes: G01N 21/643 non-biological material
• CPC Class Codes: Y10T 436/204998 Inorganic carbon compounds
• CPC Class Codes: Y10T 436/255 including use of a solid sorbent, semipermeable membrane, or liquid extraction

Abstract

A method and an arrangement for measuring the concentration of gases in a mple includes the generation of a monochromatic light beam having predetermined color characteristic. An indicator generates light signals indicative of the concentration of the gases in a sample to be measured and includes a light-transmissive surface positioned to be impinged by the monochromatic light beam, a diffusion membrane adapted to be placed in the proximity of a sample and being permeable to a selected gas component thereof, and an indicating substance positioned to be impinged by the monochromatic light beam penetrating the light-transmissive surface and by the gas component penetrating the diffusion membrane. The indicating substance reacts when illuminated by the incident monochromatic light by emitting a resultant light beam having an emitted component which has a color characteristic different from the predetermined color characteristic of the monochromatic light beam. The resultant light beam is conducted away from the indicating substance through the light-transmissive surface. Finally, the emitted component is discriminated from the resultant light beam so that the change in the color characteristic of the indicating substance can be measured and correlated with the concentration of gases in the sample.

Claims

1. A method of measuring the concentration of gases in a sample comprising the steps of generating a monochromatic light beam having a predetermined color characteristic;

generating light signals indicative of the concentration of gases in a sample to be measured by positioning an indicator having a light-transmissive surface positioned to be impinged by said monochromatic light beam, a diffusion membrane adapted to be placed in the proximity of a sample and being selectively permeable to a gas component thereof, and an indicating substance positioned to be impinged by the monochromatic light beam penetrating said light-transmissive surface and by said gas component penetrating said diffusion membrane, said indicating substance reacting when illuminated by said incident monochromatic light beam by emitting a resultant light beam having an emitted component which has a color characteristic different from said predetermined color characteristic;

conducting said resultant light beam away from said indicating substance through said light-transmissive surface; and

discriminating said emitted component from said resultant light beam so that the change in the color characteristic of said indicating substance can be measured and correlated with the concentration of gases in the sample.

2. In an arrangement for measuring the concentration of gases in a sample, a combination comprising means for generating a monochromatic light beam having a predetermined color characteristic;

indicating means for generating light signals indicative of the concentration of gases in a sample to be measured, including a light-transmissive surface positioned to be impinged by said monochromatic light beam, a diffusion membrane adapted to be placed in proximity of a sample and being permeable to a selected gas component thereof, and an indicating substance positioned to be impinged by said monochromatic light beam penetrating said light-transmissive surface and by said gas component penetrating said diffusion membrane, said indicating substance reacting when illuminated by said incident monocrhromatic light beam by emitting a resultant light beam having an emitted component which has a color characteristic different from said predetermined color characteristic;

means for conducting said resultant light beam away from said indicating substance through said light-transmissive surface; and

means for discriminating said emitted component from said resultant light beam so that the change in the color characteristic of said indicating substance can be measured and correlated with the concentration of gases in the sample.

3. The arrangement of claim 2, wherein said indicating substance is sealingly embedded thoughout said diffusion membrane.

4. The arrangement of claim 2;

and further comprising means for controlling the temperature of a sample.

5. The arrangement of claim 2, wherein the indicating substance is β

-methyl-umbelliferon.

6. The arrangement of claim 2, wherein the indicating substance is Pyrene-butyric acid.

7. The arrangement of claim 2;

and further comprising additional indicating substances intermixed with said first-mentioned indicating substance.

8. The arrangement of claim 2;

and further comprising a reflecting wall located behind said membrane.

9. The arrangement of claim 2;

and further comprising an absorption wall located behind said membrane.

10. The arrangement of claim 2, wherein sid discriminating means comprises filtering means for permitting substantially only said emitted light to pass through.

11. The arrangement of claim 2, wherein said indicating means is comprised of a plurality of particles, each comprising said indicating substance and said diffusion membrane.

12. The arrangement of claim 2;

and further comprising additional indicating means adjacent said first-mentioned indicating means, said additional indicating means having a diffusion membrane selectively permeable to another gas component and an indicating substance which reacts with the latter.

13. The arrangement of claim 12, wherein the diffusion membrane of said first-mentioned indicating means is substantially permeable to oxygen;

and wherein the diffusion membrane of said additional indicating means is substantially permeable to carbon-dioxide.

14. The arrangement of claim 2;

wherein said means for generating said monochromatic light beam includes a light-conductive cable for directing said monochromatic light beam towards said indicating means; and

wherein said conducting means comprises another light-conductive cable for directing said resultant light beam away from said indicating means.

15. The arrangement of claim 14;

and further comprising additional indicating means located adjacent said first-mentioned indicating means; and

wherein said monochromatic light beam comprises two monochromatic components, each being directed by said one light-conductive cable towards said respective indicating means.

16. The arrangement of claim 15, and wherein both said indicating means respectively emit emitted light components, each being conducted by said other light-conductive cable towards said discrimination means so that each emitted light component is individually measured.

17. The arrangement of claim 2;

and further comprising a portable housing containing said means for generating a monochromatic light beam and said discrimination means for transporting the measuring arrangement to a sample.

18. The arrangement of claim 17, wherein said indicating means is interchangeably mounted in said housing.

19. The arrangement of claim 17;

and further comprising additional measuring electrodes mounted in said housing.

20. The arrangement of claim 2, wherein said light-transmissive surface is planar and constitutes an upper layer, and wherein said indicating substance is generally located in a plane intermediate said upper layer and said diffusion membrane.

21. The arrangement of claim 20, wherein said indicating substance is arranged in a dichroic layer having one side which absorbs said monochromatic light beam.

22. The arrangement of claim 20, wheren said membrane has a reflective layer on its side facing said indicating substance.

23. The arrangement of claim 20, wherein said membrane has an absorbing layer on its side facing said indicating substance.

24. The arrangement of claim 2, wherein said means for generating a monochromatic light beam includes means for modifying the latter into a plurality of separate monochromatic components, each monochromatic component being directed towards said indicating substance.

25. The arrangement of claim 24, wherein said modifying means comprises a plurality of monochromatic filters, each positioned to be impinged by said monochromatic light beam.

26. The arrangement of claim 24, wherein said conducting means comprises a plurality of light-reflective elements, each positioned to be impinged by said emitted light component.

27. The arrangement of claim 26, wherein said discriminating means processes each of said emitted light components.