Catalytic reactor

• US 4,005,985 A
• Filed: 01/07/1972
• Issued: 02/01/1977
• Est. Priority Date: 01/07/1972
• Status: Expired due to Term

• Current Assignee: Phillips Petroleum Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Hutson, Thomas Jr.
• Primary Examiner(s): Tayman, Jr., James H.
• Application Number:
  US05/216,100
• Time in Patent Office: 1,852 Days
• Field of Search: 23/288 R, 23/288 S, 23/289, 260/683.3, 260/696, 208/146
• US Class Current: 422/217
• CPC Class Codes: B01J 2208/00407 outside the reactor bed
• CPC Class Codes: B01J 2208/00495 using insulating materials or refractories
• CPC Class Codes: B01J 8/02 with stationary particles, e.g. in fixed beds
• CPC Class Codes: C07C 11/09 Isobutene
• CPC Class Codes: C07C 5/325 of the platinum group
• CPC Class Codes: C07C 5/3337 of the platinum group

Abstract

A method and an improved platinum-tin promoted zinc aluminate catalyst reactor for dehydrogenation of a paraffinic hydrocarbon feed stream as first and second layers of silica-free particles, each positioned in contact with and on opposed surfaces of the catalyst across the direction of feed stream flow through the reactor for preventing the poisoning of said catalyst.

Claims

1. In a catalytic reactor for the dehydrogenation of a paraffinic hydrocarbon material feed stream flowing through the reactor from an inlet to an outlet end of the reactor and having a platinum-tin promoted zinc aluminate catalyst layer in the reactor traversing the direction of flow of the feed stream therethrough, the improvement comprising:

a first layer of silica-free particles positioned in contact with a lower surface of the platinum-tin promoted zinc aluminate catalyst between said catalyst and the outlet of the reactor, said first layer covering substantially the entire lower surface of said catalyst; and

a second layer of silica-free particles positioned in contact with an upper surface of said catalyst between said catalyst and the inlet of the reactor, said second layer covering substantially the entire upper surface of said catalyst.

2. A reactor, as set forth in claim 1, wherein the first and second layers are silica-free stainless steel particles.

3. A reactor, as set forth in claim 1, wherein the first and second layers are silica-free stainless steel particles, each layer having a total void space per unit depth greater than about the total void space per unit depth of the catalyst.

4. A reactor, as set forth in claim 1, wherein the particles of the first and second layers are silica-free stainless steel tubing having a diameter of about 1/8 inch and a length of about 3/16 inch.