Catalysts for electroless deposition of metals on comparatively low-temperature polyolefin and polyester substrates

• US 4,006,047 A
• Filed: 11/08/1974
• Issued: 02/01/1977
• Est. Priority Date: 07/22/1974
• Status: Expired due to Term

• Current Assignee: AMP Incorporated (Johnson Controls International plc)
• Original Assignee: AMP Incorporated (Johnson Controls International plc)
• Inventors: Andrews, Daniel Marshall, Shaak, Ray Ned, Brummett, Charles Roscoe
• Primary Examiner(s): Esposito, Michael F.
• Application Number:
  US05/521,999
• Time in Patent Office: 816 Days
• Field of Search: 117/212, 117/47 R, 117/47 A, 427/304, 427/305, 427/306, 427/307, 427/96, 427/98, 427/259, 427/226, 427/261, 427/229, 427/265, 427/282, 106/1, 156/3, 156/7, 156/8, 156/18
• US Class Current: 216/13
• CPC Class Codes: C23C 18/30 Activating or accelerating or sensitising with palladium or other noble metal

Abstract

A method for the metallization of a nonconductive surface with gold, nickel or copper whereby on a nonconductive, relatively low temperature surface (such as a polyester or a polyolefin) a thermosensitive coordination complex of palladium (or platinum) is deposited from a solvent; the complex has the general formula LmPdXn wherein L is a ligand or unsaturated organic radical, X is a halide, alkyl group or a bidentate ligand and m is an integer from 1 to 4 and n is from 0 to 3; bis-benzonitrile palladium dichloride complex is an appropriate illustration; the palladium complex is applied in a thin film from a suitable nonaqueous solution solvent such as xylene, toluene or a chlorobenzene onto the surface of the nonconductive material and that thin film is thermally decomposed, such as by an infrared irradiation; the method in the preferred embodiment can be practiced without the necessity of surface etching or similar chemical conditioning of the polyester, polyamide, polyvinyl chloride, or polyolefin substrate prior to the catalytic coating; circuit element intermediates of said substrates are also disclosed.

Claims

1. A method for the deposition of a copper, nickel cobalt, or gold as metal onto an inert substrate for said metal said substrate being selected from the group consisting of polyester, polyamides, polyvinylchloride, polyethylene, polypropylene, copolymers of either polyolefin, and poly (1a) olefins in the homologous series of the polyethylene and polypropylene, from an electroless bath containing said metal, said method comprising the steps of:

degreasing said substrate;

applying to said substrate a thin film of a thermally decomposable complex of palladium or platinum having the formulae

space="preserve" listing-type="equation">LmPdXn, or

space="preserve" listing-type="equation">LmPtXn

wherein

L is a ligand or an unsaturated organic group;

Pd or Pt is palladium or platinum metal;

X is a halide, an alkyl group or a bidentate ligand; and

m is from 1 to 4 and n is from 0 to 3

exposing said substrate to which said complex has been applied to heat at a temperature of less than a temperature at which the substrate loses its dimensional stability, to effect decomposition of said complex and to create a residue on said substrate catalytic to a copper, nickel, cobalt or gold metal in an electroless bath solution; and

depositing a copper, nickel, cobalt or gold metal from said electroless bath on said substrate in an area rendered catalytic by decomposition of said complex.

2. The process as defined in claim 1 wherein said substrate is selected from the group consisting of polyesters useful as dielectrics in electrical circuit applications, polyethylene, polypropylene, copolymers of either polyolefin, and poly (α

) olefins in the homologous series of the polyethylene and polypropylene.

3. The process as defined in claim 1 wherein said substrate is polyethylene terephthalate.

4. The process as defined in claim 1 wherein said substrate is selected from the group consisting of polyethylene terephthalate and polypropylene and is exposed with said complex to heat at a temperature of between about 50°

C and about 150°

C, said complex decomposing at or below said temperature.

5. The process as defined in claim 1 wherein said substrate is polyethylene and is exposed with said complex to heat at a temperature up to about 98°

C, said complex decomposing at or below said temperature.

6. The process as defined in claim 1, wherein the palladium complex is selected from the group consisting of bis-benzonitrile palladium dichloride, 1,3-butadiene palladium dichloride, and bis-acetonitrile palladium dichloride.

7. The process as defined in claim 1, wherein the said substrate, after application of said complex decomposition of same and immersion in an electroless bath, is masked and additionally an electroless metal deposit is made and, thereafter the additional deposit protected, said mask removed and said substrate back-etched to obtain a circuit element.

8. The process as defined in claim 1 and wherein the substrate is a polyamide.

9. The process as defined in claim 1 and wherein the substrate is polyvinylchloride.

10. The process as defined in claim 2, wherein the said substrate, after application of said complex and electroless metal in a nickel, cobalt, copper or gold electroless bath solution, is masked and exposed to further additive electroless deposition.

11. The process as defined in claim 2 and wherein the substrate is degreased before applying said complex to same by a solvent which wets and slightly swells the surface of said substrate.

12. The process as defined in claim 7 wherein said substrate after said further additive deposition is stripped of said mask and back-etched in areas wherein said electroless metal has been deposited.

13. The process as defined in claim 3, wherein the palladium complex is selected from the group consisting of bis-benzonitrile palladium dichloride, 1,3-butadiene palladium dichloride, and bis-acetonitrile palladium dichloride.

14. The process as defined in claim 4, wherein the palladium complex is selected from the group consisting of bis-benzonitrile palladium dichloride, 1,3-butadiene palladium dichloride, and bis-acetonitrile palladium dichloride.

15. The process as defined in claim 5 wherein the palladium complex is chosen from the group consisting of bis-benzonitrile palladium dichloride, 1,3-butadiene palladium dichloride, and bis-acetonitrile palladium dichloride.