Method of preparing a low-friction laminate liner for bearings

• US 4,006,051 A
• Filed: 07/11/1975
• Issued: 02/01/1977
• Est. Priority Date: 02/21/1974
• Status: Expired due to Term

• Current Assignee: New Hampshire Ball Bearings Incorporated (MinebeaMitsumi Inc.)
• Original Assignee: New Hampshire Ball Bearings Incorporated (MinebeaMitsumi Inc.)
• Inventors: Board, David A. Jr.
• Primary Examiner(s): Van Horn, Charles E.
• Assistant Examiner(s): Massie, James W.
• Application Number:
  US05/595,297
• Time in Patent Office: 571 Days
• Field of Search: 428/175, 428/232, 428/245, 428/269, 428/288, 428/290, 428/301, 428/302, 428/305, 428/352, 428/421, 428/436, 428/460, 428/236, 428/237, 428/238, 428/422, 428/474, 428/524, 156/289, 156/298, 156/256, 156/62.2, 156/62.8, 156/305, 156/278, 156/153, 156/250, 156/258, 156/248, 156/309, 156/33 D, 156/335, 156/196, 156/306, 156/344, 156/91 , 156/247, 264/248, 308/238
• US Class Current: 156/247
• CPC Class Codes: F16C 33/201 Composition of the plastic
• CPC Class Codes: F16C 33/28 with embedded reinforcements shaped as frames or meshed materials
• CPC Class Codes: Y10T 156/1062 Prior to assembly
• CPC Class Codes: Y10T 428/24636 Embodying mechanically interengaged strand[s], strand-portion[s] or strand-like strip[s] [e.g., weave, knit, etc.]
• CPC Class Codes: Y10T 428/2839 with release or antistick coating
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31627 Next to aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31743 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31942 Of aldehyde or ketone condensation product

Abstract

A laminate liner adapted to be secured to a supporting surface, which liner comprises in combination: a backing sheet member characterized by a number of relatively large openings therein; a fibrous polymeric sheet material characterized by a number of small openings therein, the fibers composed of a thermoplastic polymeric material having low-friction, self-lubricating properties; and a hardenable resin binder material, the hardenable resin binder material impregnated into the openings of the backing member, and the fibrous polymeric sheet material compressed into the openings of the backing member to form an integral, unitary, laminate liner, the liner characterized by having a low-friction facing surface composed of the polymeric sheet material compressed and bonded to the backing member, and a resin-rich backing surface, the backing surface adapted to be secured by heat pressure to a supporting surface to form a bearing liner.

Claims

1. A method of preparing a laminate liner suitable for use as a low-friction bearing liner, which method comprises:

a. providing an assembly of successively overlying layers of sheet materials, which assembly comprises

i. a flexible backing sheet material,

ii. a separate flexible thin porous polymeric sheet material consisting essentially of a fibrous thermoplastic polymeric material having low-friction, self-lubricating properties,

iii. the backing sheet member characterized by a plurality of substantially regular and uniform relatively large openings therein,

iv. the polymeric sheet material characterized by a plurality of small pores therein, and

v. the assembly having a one exposed surface of the backing sheet member and another exposed surface of the polymeric sheet material;

b. applying a layer of a heat-hardenable resin binder material to the one exposed surface of the backing sheet member in an amount sufficient to fill in the openings of the backing sheet material;

c. placing the resin binder-filled assembly between opposing release surfaces;

d. compressing the assembly under heat and pressure conditions sufficient to force the resin binder material throughout the assembly and to force the porous fibrous polymeric sheet material into the openings of the backing sheet material to bond mechanically the polymeric sheet material to the backing sheet material; and

e. removing at least one release surface and recovering an integral, thin, flexible, laminate liner suitable for use as a bearing liner and characterized by one resin-rich surface adapted to be secured to a supporting member, and another facing surface characterized by low-friction, self-lubricating properties.

2. The method of claim 1 wherein the polymeric sheet material is characterized by pores of from about 10 to 100 microns.

3. The method of claim 1 wherein the backing sheet material is characterized by openings of about 10 to 45 openings per linear inch.

4. The method of claim 1 wherein the polymeric sheet material comprises a thermoplastic fluorocarbon resin.

5. The method of claim 1 wherein the polymeric sheet material is a polytetrafluoroethylene resin or a fluorinated ethylene-propylene resin.

6. The method of claim 1 wherein the polymeric sheet material has a pore volume of from about 60 to 95 percent.

7. The method of claim 1 wherein the backing sheet material comprises a woven mesh-like sheet material of glass, metal or plastic fibers.

8. The method of claim 1 wherein the resin binder material comprises a thermosetting phenolic resin material and wherein the resin is heated during compressing to form a B-stage resin binder material.

9. The method of claim 1 wherein the resin binder material comprises a hardenable resin in a volatile solvent solution, and which includes applying a series of coating layers to the one exposed surface of the backing sheet member in an amount and number of layers to cover the backing sheet member surface, and removing the solvent by drying prior to the compressing step.

10. The method of claim 1 which includes compressing the assembly to form a flexible laminate liner having a thickness of from about 8 to 20 mils.

11. The method of claim 1 wherein, during the compressing step, the pressure is from about 500 to 1500 psi, and the assembly is heated to a temperature of about 130°

to 160°

F.

12. The method of claim 1 wherein the opposing release surface comprises a solid polymeric sheet material placed on either side of the assembly.

13. Th method of claim 12 wherein the material is a tetrafluoroethylene resin.

14. The method of claim 1 which includes cutting the integral laminate liner to a desired size and shape for employment as a bearing liner.

15. A method of preparing a bearing having a low-friction, self-lubricating bearing liner, which method comprises:

bonding the resin-rich surface of the laminate liner prepared in claim 1 to a bearing-supporting surface.

16. The method of claim 15 which includes:

a. applying a layer of adhesive material to a bearing metal supporting surface;

b. placing the laminate liner onto the adhesive layer; and

c. bonding the laminate liner to the supporting surface under heat and pressure sufficient to harden the resin binder material and to secure the laminate liner to the supporting surface.

17. A method of preparing a laminate liner suitable for use as a low-friction bearing liner, which method comprises:

a. placing a flexible, thin, porous, polymeric sheet material consisting essentially of a fibrous thermoplastic polymeric fluorocarbon material having low-friction, self-lubricating properties and characterized by a plurality of pores of from about 10 to 100 microns onto a sheet material having release properties;

b. placing a flexible, woven, backing sheet material characterized by a plurality of substantially regular and uniform openings therein of from about 10 to 45 openings per linear inch onto the polymeric sheet material;

c. coating a layer of a thermosetting resin binder material onto the surface of the backing sheet in an amount sufficient to cover the backing sheet material;

d. placing a sheet material having release properties onto the coated resin layer;

e. compressing the release sheets together at a pressure of 500 to 1500 psi and a temperature of about 130°

to 160°

F to form a laminate with the polymeric sheet material and resin binder material forced into the openings of the backing sheet material to mechanically bond the polymeric sheet material to the backing material; and

f. removing the release sheets to provide an integral, thin, flexible, laminate liner characterized by a low-friction facing surface composed of the fluorocarbon polymeric sheet material and a hardenable resin-rich backing surface.

18. The method of claim 17 wherein the fluorocarbon is a tetrafluoroethylene resin or a fluorinated ethylene-propylene resin, the backing sheet material is a woven nylon sheet material, and the resin is a condensable thermosetting phenolic resin which on compressing is placed in the B-stage.

19. A method of preparing a bearing having a low-friction bearing liner which comprises:

a. cutting the integral laminate liner prepared by the method of claim 17 to a desired size and shape to fit a bearing surface;

b. placing the resin-rich surface of the laminate liner onto the supporting surface of a bearing; and

c. bonding the laminate liner to the bearing surface under heat and pressure to harden the resin binder to the thermoset condition and to secure the laminate liner to the bearing surface.