Cell comprising an alkali metal and aqueous electrolyte

• US 4,007,057 A
• Filed: 12/29/1975
• Issued: 02/08/1977
• Est. Priority Date: 12/29/1975
• Status: Expired due to Term

• Current Assignee: Lockheed Martin Space Operations Company (Martin Marietta Corporation)
• Original Assignee: Lockheed Martin Space Operations Company (Martin Marietta Corporation)
• Inventors: Tsai, Keh Chi, Hollandsworth, Roger Paul, Littauer, Ernest Lucius
• Primary Examiner(s): Mack, John H.
• Assistant Examiner(s): Feeley, H. A.
• Application Number:
  US05/645,199
• Time in Patent Office: 407 Days
• Field of Search: 136/83 R, 136/64, 136/100 R
• US Class Current: 429/57
• CPC Class Codes: H01M 12/04 composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
• CPC Class Codes: H01M 6/26 Cells without oxidising active material, e.g. Volta cells

Abstract

In a reactive metal-water electrochemical cell, an alkaline electrolyte containing soluble inorganic ions which are reduced preferentially to water at the cathode. More particularly, the additives substantially reduce or eliminate reduction of water and evolution of hydrogen at the cathode resulting in significant improvement in current efficiency, gravimetric energy density and cell potential at a given current. Additionally, suppression of hydrogen evolution makes possible a sealed system with venting of gases from the cell no longer necessary. The inorganic ions of the invention are nitrite, hypochlorite, chlorate, bromate, dinitrogen trioxide and sulfite ions which are formed when soluble salts of nitrite, sulfite, hypochlorate, bromate, chlorate, soluble gases such as dinitrogen trioxide and sulfur dioxide and other soluble inorganic compounds are dissolved in the alkaline electrolyte.

Claims

1. An electrochemical cell consisting essentially of an alkali metal anode highly reactive with water and spaced from a cathode by an electrically insulating film formed on said anode in the presence of water, an aqueous alkaline hydroxide electrolyte in which said anode and cathode are immersed, said electrolyte permitting at the anode electrochemical dissolution of reactive metal to aqueous reactive metal ions and formation of an aqueous salt to a solid salt in the form of a porous film on said anode, and at least one soluble inorganic ion selected from the group of ions consisting of nitrite, hypochlorite, chlorate, bromate, dinitrogen trioxide and sulfite ions in said aqueous alkaline hydroxide electrolyte which is reduced preferentially to water at the cathode and substantially eliminates hydrogen evolution.

2. An electrochemical cell in accordance with claim 1 wherein

said soluble inorganic ion is selected from the group of ions consisting essentially of nitrite, hypochlorite, chlorate and dinitrogen trioxide ions.

3. An electrochemical cell in accordance with claim 2 wherein

said ion is nitrite.

4. An electrochemical cell in accordance with claim 1 wherein

said ion is selected from the group of ions consisting essentially of bromate and sulfite ions.