Powder barrier bonding technique

• US 4,009,231 A
• Filed: 03/20/1975
• Issued: 02/22/1977
• Est. Priority Date: 03/20/1975
• Status: Expired due to Term

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Wasserman, Bernard, Thielbahr, William H.
• Primary Examiner(s): Sebastian, Leland A.
• Application Number:
  US05/560,077
• Time in Patent Office: 705 Days
• Field of Search: 264/3 R, 102/103
• US Class Current: 264/3.1
• CPC Class Codes: C06B 21/0083 Treatment of solid structures, e.g. for coating or impregnating with a modifier compositions therefor C06B23/00
• CPC Class Codes: C06B 45/12 having contiguous layers or zones

Abstract

A barrier layer made up of a suitable powder interspersed within either a trix of cured propellant binder or a matrix of silicone rubber is interposed between a silicone rubber insulator and a solid propellant grain in a rocket motor to prevent curatives from migrating from the propellant into the silicone rubber layer when the propellant is cast.

Claims

1. In a method for loading a rocket motor which comprises casting and curing a solid propellant within a combustion chamber which is lined with a layer of cured silicone rubber insulator material, the improvement residing in casting and curing a barrier layer on said layer of insulator material before casting and curing the propellant grain to prevent materials in the propellant grain from migrating into the insulator layer as the propellant grain cures.

2. In a method according to claim 1 the additional improvement residing in utilizing, as said barrier layer, a composite made up of a powder selected from the group consisting of copper, silica and aluminum interspersed in a matrix of binder selected from the group consisting of carboxy and hydroxy terminated polybutadiene.

3. A method according to claim 2 wherein the powder is silica powder and the matrix is carboxy terminated polybutadiene.

4. A method according to claim 3 wherein from 65 to 75 weight percent of the barrier layer is silica and wherein from 35 to 25 weight percent of the barrier layer is carboxy terminated polybutadiene.

5. A method for providing a barrier layer to substantially prevent migration of a curing agent from a solid propellant grain into an insulation layer comprising the steps of:

1. applying an uncured blend of silicone rubber and a powder onto the cured insulation; and

2. allowing said barrier layer to cure.

6. A method according to claim 5 wherein said insulation layer is made up of silicone rubber and wherein said powder is selected from the group consisting of copper powder, silica powder and aluminum powder.