Gas analyzer

• US 4,013,260 A
• Filed: 09/27/1974
• Issued: 03/22/1977
• Est. Priority Date: 09/27/1974
• Status: Expired due to Term

• Current Assignee: AC Limited (Emirate of Dubai (United Arab Emirates))
• Original Assignee: Andros, Inc. (Advanced Energy Industries, Inc. (China))
• Inventors: McClatchie, Edward A., Burough, Irvin G., Watson, Dean A.
• Primary Examiner(s): Smith, Alfred E.
• Assistant Examiner(s): Grigsby, T. N.
• Application Number:
  US05/509,838
• Time in Patent Office: 907 Days
• Field of Search: 250/343, 356/51
• US Class Current: 250/343
• CPC Class Codes: G01N 21/314 with comparison of measurements at specific and non-specific wavelengths dual wavelength spectrometry G01J3/427

Abstract

An improved gas analyzer for measuring the presence of one or more gaseous compounds in a gas sample. The gas analyzer has an infrared source stabilized against temperature variations by a radiation loading scheme in combination with a selected source environmental temperature sensitivity to provide a stable source temperature without a conventional temperature controller. A rotating interference filter assembly is disposed in the optical path. This assembly alternately totally blocks radiation, passes radiation in a wave length band which will not be absorbed by a random gas sample, and sequentially passes radiation in one or more additional bands which will be absorbed by one or more gases in the sample cell. The sample cell features a unique enclosed cell with infrared transparent windows which are substantially free of impingement of contaminants of the gas sample thereon. A unique detector provides protection against deterioration from moisture while allowing easy and inexpensive assembly. The system electronics eliminates sensitivities to background radiation, contamination of windows, etc., and provides a self test capability.

Claims

1. A gas analyzer comprising:

an infrared energy source for repetitively directing along an optical path and toward a sample cell first infrared energy having a first wave length generally different from the wave lengths absorbed by a gas sample, second infrared energy having a second wave length, at least some of which will be absorbed by a gas sample, and substantially no infrared energy;

a sample cell disposed in said optical path, said sample cell having substantially infrared transparent windows to allow infrared radiation to pass therethrough;

detector means sensitive to infrared radiation in said optical path passing through said sample cell, said detector means comprising a photodetector coupled to a controllable power source;

synchronizing means for providing signals indicative of the state of radiation being emitted from said infrared energy source;

electronic means coupled to said synchronizing means and said detector means for providing a first signal of a first predetermined level when said infrared energy source is directing said first infrared energy along said optical path, for providing a second signal of a second predetermined level when said infrared energy source is directing substantially no infrared energy along said optical path, and for providing a third signal of a level substantially equal to said first signal level when said infrared energy source is directing said second infrared energy along said optical path and said sample cell is substantially free of the gas to be detected;

said electronic means including automatic gain control means coupled to said power source to maintain the difference in said first and second signal levels at a predetermined level, whereby the difference in said third and first signal levels is indicative of the gas to be detected in the sample cell.

2. The analyzer of claim 1 wherein said first signal level is a ground voltage.

3. The analyzer of claim 1 wherein said second infrared energy is in itself a sequence of infrared energies, each of which may be absorbed by a specific gas to be detected in a gas sample, whereby said third signal may be a plurality of signals and whereby the differences between the said first signal level and the said third signal levels are a quantitative measure of the concentrations in the gas sample of the respective gases to be detected.

4. The analyzer of claim 1 wherein said infrared energy source comprises an infrared emitter and a rotating filter.

5. The analyzer of claim 4 wherein said synchronizing means comprises a light source and photo detector means for sensing the interruption of the light beam by the rotating filter.

6. The gas analyzer of claim 1 wherein said infrared energy source comprises:

an infrared radiation emitting element having first and second electrical connections;

an enclosure for said element;

a power source including means for coupling said power source to said first and second electrical connections, said power source further including means responsive to ambient temperature to vary the voltage applied to said first and second electrical connections to maintain said element at a substantially constant temperature over a range of ambient temperature.

7. The gas analyzer of claim 6 wherein the outer surface of said element and the inner surface of said enclosure have a high emissivity to infrared radiation.

8. The gas analyzer of claim 1 wherein said sample cell comprises:

an enclosure for said sample;

first and second windows in said enclosure, said windows being disposed in opposite walls of said enclosure, said windows being substantially transmissive to said radiation so as to define a radiation path through said cell;

inlet means adjacent each end of said enclosure for receiving and directing said fluid to the interior of said cell adjacent each end thereof, said inlet means having smooth surfaces defining a flow path with a substantial longitudinal component toward the center of said cell and a substantial inward radial component; and

outlet means longitudinally disposed between said inlet means for removing said fluid from said cell.

9. The gas analyzer of claim 8 wherein the surface defining said inlet means adjacent each window has a shape discontinuity to induce fluid flow separation at said discontinuity.

10. The gas analyzer of claim 1 wherein said detector comprises:

a base having a plurality of electrical feedthroughs;

a thermoelectric cooler supported by said base, said thermoelectric cooler being electrically coupled to at least one of said feedthroughs;

a photoconductor device supported by said thermoelectric cooler and electrically coupled to at least one of said feedthroughs;

a temperature sensitive element supported by said thermoelectric cooler and electrically coupled to at least one of said feedthroughs;

a cover coupled to said base to form an enclosure over said thermoelectric cooler, said photoconductor device and said temperature sensitive element, said cover having a window which is substantially transparent to certain radiation disposed over said photoconductor device; and

at least one pellet of desiccant material cemented within said enclosure, said desiccant material being sufficiently free of water so as to have a high affinity for moisture.

11. The gas analyzer of claim 10 wherein said temperature sensitive element is a thermistor.

12. The gas analyzer of claim 1 wherein said detector comprises:

a base having a plurality of electrical feedthroughs;

a detector device supported by said base and electrically coupled to at least one of said feedthroughs;

a cover coupled to said base to form an enclosure over said detector device, said cover having windows for allowing radiation to strike said detector device; and

a desiccant material disposed within said enclosure.

13. The gas analyzer of claim 12 wherein said desicant material is in pellet form.

14. The detector of claim 12 wherein said desiccant material is cemented in place.

15. The detector of claim 12 wherein said detector device is a photo conductor.

16. The detector of claim 12 further including a thermoelectric cooler and a thermistor, said thermoelectric cooler being mounted on said base and electrically coupled to at least one of said feedthroughs, said thermistor also being coupled to at least one of said feedthroughs, and said thermistor and said detector being mounted to said thermoelectric cooler.

17. The gas analyzer of claim 1 wherein said sample cell comprises:

an enclosure for a gas sample;

first and second windows in said enclosure, one of said windows being adjacent each end of said enclosure, said windows being substantially transparent to infrared radiation so as to define an infrared radiation path through said sample cell;

inlet means adjacent each end of said enclosure for providing a gas sample to the interior of said cell adjacent each end thereof, and

outlet means between said inlet means for removing a gas sample from said cell.

18. The gas analyzer of claim 17 further comprising flow control means adjacent each end of said enclosure for receiving a gas sample from the respective inlet means and establishing flows having substantial components toward said outlet means.

19. The gas analyzer of claim 18 wherein said flow control means establishes flow having a substantial component in the radially inward direction, thereby creating a form of stagnation plug inwardly adjacent each of said windows.

20. The gas analyzer of claim 1 wherein said infrared energy source comprises:

an infrared radiation emitting element having first and second electrical connections,

an enclosure for said element having a predetermined transmissive area which is substantially transmissive to infrared radiation to allow infrared radiation from said element to proceed along an optical path, said enclosure including means for supporting said element in a fixed position with respect to said transmissive area, the outer surface of said element and the inner surface of said enclosure each having an emissivity of at least 0.7 with respect to infrared radiation.

21. The gas analyzer of claim 20 wherein said emissivities are at least 0.85.

22. The gas analyzer of claim 21 wherein said means for supporting said element is a means for supporting said element to provide low thermal conduction from said element to said enclosure.

23. The gas analyzer of claim 22 wherein said enclosure is a means for enclosing said element so as to limit convection currents around said element.

24. The gas analyzer of claim 23 further comprised of a power source and leads for coupling to said first and second electrical connections, said leads and power source being selected to maintain said element at a substantially constant temperature over a substantial ambient temperature range.

25. The gas analyzer of claim 24 wherein at least a part of one of said leads has a resistance change with temperature so as to change the voltage applied between said first and second electrical connections with ambient temperature.

26. A gas analyzer for detecting the amount of a specific gaseous compound in a gas sample, comprising, means for directing radiation through the gas sample, such radiation including radiation at a first wave length which is substantially different from wave lengths absorbed by the gas sample and radiation at a second wave length which is substantially absorbed by the specific gaseous compound, means for periodically interrupting the radiation from said directing means, detector means for detecting the radiation of the first and second wave lengths after such radiation has passed through the gas sample and for detecting background radiation in the absence of radiation from said directing means, said detector means providing first and second electrical output signals representative, respectively, of the amounts of radiation at the first and second wave lengths passing through the gas sample, said detector means further providing a background electrical output signal representative of background radiation, gain control means for holding the first and second electrical output signals to a predetermined reference level amplitude in the absence of the specific gaseous compound in the gas sample, said gain control means being responsive to deviation of the first electrical output signal from the predetermined reference level, said gain control means including a servo loop responsive to the background electrical output signal to stabilize said gain control means for variations in background radiation, and sensing means for sensing the difference between the amplitude of the second electrical output signal and the reference level amplitude in the presence of the specific gaseous compound, whereby the signal provided by said sensing means is representative of the amount of the specific gaseous compound in the gas sample compensated for the effect of background radiation.

27. A gas analyzer according to claim 26 wherein the radiation directed by said directing means includes radiation at third and fourth wave lengths which are substantially absorbed by further specific gaseous compounds, respectively, wherein said detector means operate to detect the radiation of the third and fourth wave lengths after such radiation has passed through the gas sample, said detector means providing third and fourth electrical output signals representative, respectively, of the amounts of radiation at the third and fourth wave lengths passing through the gas sample, wherein said gain control means operate to hold the third and fourth electrical output signals to the predetermined reference level amplitude in the absence of the further specific gaseous compounds in the gas sample, and wherein said sensing means operate to sense the differences between the amplitude of the second, third, and fourth electrical output signals and the reference level amplitude in the presence of the respective specific gaseous compounds.