Construction material with calcium silicate monohydrate produced thereon in situ and composition therefor

• US 4,015,040 A
• Filed: 07/01/1976
• Issued: 03/29/1977
• Est. Priority Date: 07/04/1973
• Status: Expired due to Term

• Current Assignee: Akitoshi Yoshida, Koichiro Yanagida, Reiko Nakamura, Shigeki Inoue, Tadanobu Maruyama
• Original Assignee: Akitoshi Yoshida, Koichiro Yanagida, Reiko Nakamura, Shigeki Inoue, Tadanobu Maruyama
• Inventors: Inoue, Shigeki, Yoshida, Akitoshi, Maruyama, Tadanobu, Yanagida, Koichiro, Nakamura, Reiko
• Primary Examiner(s): Ives, P. C.
• Application Number:
  US05/701,878
• Time in Patent Office: 271 Days
• Field of Search: 428/454, 428/411, 428/446, 428/471, 428/500, 428/428, 428/313, 428/310, 428/538, 428/539, 428/316, 428/514, 428/540, 428/543, 428/438, 428/320, 428/150, 428/143, 427/216-221, 427/201, 427/180, 427/42, 427/49, 264/333, 260/29.6 PS, 106/12, 106/38.3, 106/120, 106/286, 106/287 S, 106/288
• US Class Current: 428/312.4
• CPC Class Codes: C04B 28/24 containing alkyl, ammonium or metal silicates; containing silica sols reaction mixtures resulting in mineral polymers C04B28/006; polymeric reaction products of alkali metal silicates with isocyanates C08G18/3895
• CPC Class Codes: C09D 1/00 Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
• CPC Class Codes: Y10T 428/249968 Of hydraulic-setting material
• CPC Class Codes: Y10T 428/24999 Inorganic
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
• CPC Class Codes: Y10T 428/31634 Next to cellulosic
• CPC Class Codes: Y10T 428/31649 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31703 Next to cellulosic
• CPC Class Codes: Y10T 428/31906 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/4935 Impregnated naturally solid product [e.g., leather, stone, etc.]
• CPC Class Codes: Y10T 428/8305 Miscellaneous [e.g., treated surfaces, etc.]

Abstract

Calcium silicate monohydrate (2CaO.sup.. SiO₂.sup.. H₂ O) can be produced in a coating which has been formed by a coating material containing silica sol alone or silica sol and other additives such as aggregate, viscosity increasing agent, etc. by subjecting the coating to a chemical treatment such as heat-treatment, ultra-violet ray irradiation treatment, etc. in the presence of water and a calcium compound which may be present either in the coating material, or in the treating liquid, or in an object to be coated. The film which contains the calcium silicate monohydrate produced by said chemical treatment has remarkably high hardness and is excellent in water-resistance, water-imperviousness, weather-resistance, and heat-resistance.

Claims

1. A construction material covered with a film composition on a construction object containing calcium silicate monohydrate, 2CaO.SiO₂.H₂ O, produced in situ by reacting a coating with a calcium compound in the presence of water, said calcium compound selected from the group consisting of calcium hydroxide, calcium halide, calcium nitrate, calcium nitrite, calcium carbonate, calcium oxide, calcium sulfate, calcium silicate, calcium phosphate, and calcium salts of organic acids, said coating being formed from a coating material which comprises a silica sol dispersed in a medium selected from the group consisting of water, methanol, ethanol isopropanol and a mixture thereof, at least one kind of aggregate, at least one kind of viscosity increasing agent selected from the group consisting of polyacrylic acid and sodium polyacrylate, at least one kind of organic polymer, as an aqueous emulsion, selected from the group consisting of polyvinylacetate and polyacrylate, and pigment, said silica sol containing 5 to 50% by weight of SiO₂ and having a mol ratio SiO₂ /Me₂ O, wherein Me represents monovalent alkali metal atom, of more than 25.

2. The construction material according to claim 1 wherein said construction object is in the form of slate board, calcium silicate board, foamed or non-foamed concrete, mortar, plywood board, gypsum board or pulp cement board.

3. A construction material covered with a film composition on a construction object containing calcium silicate monohydrate, 2CaO.SiO₂.H₂ O, produced in situ by reacting said coating with an aqueous solution of at least one calcium compound selected from the group consisting of calcium hydroxide, calcium halide, calcium nitrate, calcium nitrite, calcium carbonate, calcium oxide, calcium sulfate, calcium silicate, calcium phosphate and calcium salts of organic acids, maintained at a temperature of 50°

C or above, said coating being formed from a coating material which comprises an aqueous silica sol, at least one kind of aggregate, at least one kind of viscosity increasing agent selected from the group consisting of polyacrylic acid and sodium polyacrylate, at least one kind of organic polymer, as an aqueous emulsion, selected from the group consisting of polyvinylacetate and polyacrylate, and pigment, said silica sol dispersed in water and containing 5 to 50% by weight of SiO₂ and having a mole ratio SiO₂ /Me₂ O, wherein Me represents monovalent alkali metal atom, of more than 25.

4. A construction material covered with a film composition on a construction object containing calcium silicate monohydrate, 2CaO.SiO₂.H₂ O, produced in situ by irradiating a coating formed by applying a coating material necessarily containing the calcium compound on said object to be coated which does not contain the calcium compound, by applying said coating material containing the calcium compound on said object to be coated which contains the calcium compound, and by applying said coating material not containing the calcium compound to an object which contains the calcium compound, treatment with ultra-violet irradiation, while spraying water thereonto intermittently, said calcium compound being at least one selected from the group consisting of calcium hydroxide, calcium halide, calcium nitrate, calcium nitrite, calcium carbonate, calcium oxide, calcium sulfate, calcium silicate, calcium phosphate and calcium salts of organic acids, said coating being obtained from a coating material which comprises an aqueous silica sol at least one kind of aggregate, at least one kind of viscosity increasing agent selected from the group consisting of polyacrylic acid and sodium polyacrylate, at least one kind of organic polymer, as an aqueous emulsion, selected from the group consisting of polyvinylacetate and polyacrylate, and pigment, said silica sol being dispersed in water and contaning 5 to 50% by weight of SiO₂ having a mol ratio SiO₂ /Me₂ O, wherein Me represents monovalent alkali metal atom, of more than 25.

5. A construction material covered with a film composition on a construction object containing calcium silicate monohydrate, 2CaO.SiO₂.H₂ O, produced in situ by reacting a coating formed by applying a coating material necessarily containing the calcium compound on said object to be coated which does not contain the calcium compound, by applying said coating material containing the calcium compound on said object to be coated which contans the calcium compound, and by applying said coating material not containing the calcium compound to an object which contains the calcium compound and treating with water maintained at a temperature higher than 50°

C, said calcium compound being at least one selected from the group consisting of calcium hydroxide, calcium halide, calcium nitrate, calcium nitrite, calcium carbonate, calcium oxide, calcium sulfate, calcium silicate, calcium phosphate and calcium salts of organic acids, said coating being obtained from a coating material which comprises an aqueous silica sol, at least one kind of aggregate, at least one kind of viscosity increasing agent selected from the group consisting of polyacrylic acid and sodium polyacrylate, at least one kind of organic polymer, as an aqueous emulsion, selected from the group consisting of polyvinylacetate and polyacrylate, and pigment, said silica sol being dispersed in water and containing 5 to 50% by weight of SiO₂ and having a mol ratio SiO₂ /Me₂ O, wherein Me represents monovalent alkali metal atom, of more than 25.

6. A film composition for coating construction materials comprising calcium silicate monohydrate, 2CaO.SiO₂.H₂ O, produced in situ by reacting a calcium compound in the presence of water with a silica sol dispersed in a medium of at least one of the group consisting of water, methanol, ethanol, isopropanol and t-butanol, containing 5 to 50% by weight of SiO₂ and having a mole ratio, SiO₂ /Me₂ O, wherein Me represents monovalent alkali metal atom, of more than 25, in the presence of at least one kind of aggregate, at least one kind of viscosity increasing agent selected from the group consisting of polyacrylic acid and sodium polyacrylate, at least one kind of organic polymer, as an aqueous emulsion, selected from the group consisting of polyvinylacetate and polyacrylate, and pigment.

7. The film composition according to claim 6 further comprising at least one kind of aggregate selected from the group consisting of gravels, sands, glass pigment, clay, mineral ores, powdered inorganic solids, and refractory materials.

8. The film composition according to claim 6, wherein said calcium compound is at least one selected from the group consisting of calcium hydroxide, calcium halide, calcium nitrate, calcium nitrate, calcium carbonate, calcium oxide, calcium sulfate, calcium silicate, calcium phosphate and calcium salts of organic acids.