Chemical method of strengthening glass articles subjected to abrasion resistance treatment

• US 4,021,218 A
• Filed: 11/13/1975
• Issued: 05/03/1977
• Est. Priority Date: 04/02/1975
• Status: Expired due to Term

• Current Assignee: Yamamura Glass Kabushiki Kaisha
• Original Assignee: Yamamura Glass Kabushiki Kaisha
• Inventors: Watanabe, Muneo
• Primary Examiner(s): Lindsay, Jr., Robert L.
• Application Number:
  US05/631,604
• Time in Patent Office: 537 Days
• Field of Search: 65/30 E, 65/30 R, 65/60 R, 65/60 B, 427/107, 427/109, 427/237, 427/252, 427/253
• US Class Current: 65/30.14
• CPC Class Codes: C03C 17/23 Oxides C03C17/02 takes precedence
• CPC Class Codes: C03C 21/002 to perform ion-exchange between alkali ions C03C21/005 takes precedence
• CPC Class Codes: C03C 2217/229 Non-specific enumeration
• CPC Class Codes: C03C 2218/32 After-treatment

Abstract

This invention relates to a chemical method of strengthening glass articles subjected to abrasion resistance treatment, which comprises (1) a first step of applying a metal oxide-forming compound to the surface of a heated glass article to form the corresponding metal oxide coating having a thickness of 50 to 130 Angstrom on the surface of the glass article, (2) a second step of causing to adhere, to the outer and inner surfaces of the glass article, a mixed solution of potassium chloride and potassium nitrate, having a potassium chloride to potassium nitrate ratio by weight of 85 to 45:15 to 55, or a mixed solution of potassium sulfate and potassium nitrate, having a potassium sulfate to potassium nitrate ratio by weight of 30 to 100:70 to 0, (3) a third step of holding the glass article at an elevated temperature below the strain point of the glass but as near the strain point as possible for a period of time sufficient to obtain a compressive stress layer having a depth of at least 10 microns and a compressive stress of at least 700 kg/cm² and (4) a fourth step of cooling the glass article to room temperature and then washing the glass article to remove the mixture of the potassium salts remaining on the outer surface and inner surface of the glass article.

Claims

1. A method of chemically strengthening a glass article which comprises (1) applying a metal oxide-forming compound selected from the group consisting of tin compounds, titanium compounds, zirconium compounds and vanadium compounds to the outer surface of a heated glass article to form a metal oxide coating having a thickness of 50 to 130 Angstroms on the outer surface of the glass article, (2) applying a concentrated mixed solution of potassium chloride and potassium nitrate having a potassium chloride to potassium nitrate weight ratio of 85 to 45 :

15 to 55, or a concentrated mixed solution of potassium sulfate and potassium nitrate having a potassium sulfate to potassium nitrate weight ratio of 30 to 100 ;

70 to 0, to the outer and inner surfaces of the thus treated glass article having a temperature of 30°

to 75°

C., (3) maintaining the resultant glass article at an elevated temperature below the strain point of the glass but as near the strain point as possible for a period of time sufficient to obtain a compressive stress layer having a depth of at least 10 microns and a compressive stress of at least 700 kg/cm², (4) cooling the thus heated glass article to room temperature and removing the mixture of the potassium salts remaining on the outer and inner surfaces of the glass article.

2. The method of claim 1, wherein in the mixed solution of potassium chloride and potassium nitrate, a part of the potassium chloride and potassium nitrate is substituted by potassium sulfate.

3. The method of claim 1, wherein the thickness of the metal oxide coating is 70 to 100 Angstroms.

4. The method of claim 1, wherein in the mixed solution of potassium sulfate and potassium nitrate, the quantity of potassium nitrate being greater than zero, a part of the potassium sulfate and potassium nitrate is substituted by potassium chloride.

5. The method of claim 1, wherein wetting aid is added to the mixed solution in a quantity of 0.2 to 1%.

6. The method of claim 5, wherein the wetting aid is selected from the group consisting of anionic surfactants.

7. The method of claim 1, wherein the mixed solution is applied to the glass article by dipping or spraying.

8. The method of claim 1, wherein the temperature of the mixed solution is 50°

to 75°

C.

9. The method of claim 1, wherein the liquidus temperature of the mixed salt is higher than or substantially equal to the strain point of the glass.

10. The method of claim 1, wherein the temperature of the glass article in step (2) is 50°

to 60°

C.