Ion exchange-strengthened silicate glass filter for ultraviolet light

• US 4,022,628 A
• Filed: 09/05/1975
• Issued: 05/10/1977
• Est. Priority Date: 09/05/1975
• Status: Expired due to Term

• Current Assignee: American Optical Corporation
• Original Assignee: American Optical Corporation
• Inventors: Deeg, Emil W.
• Primary Examiner(s): Douglas, Winston A.
• Assistant Examiner(s): Bell, Mark
• Application Number:
  US05/610,608
• Time in Patent Office: 613 Days
• Field of Search: 106/52, 106/47 Q, 65/30 E, 252/300
• US Class Current: 65/30.13
• CPC Class Codes: C03C 21/005 to introduce in the glass such metals or metallic ions as Ag, Cu
• CPC Class Codes: C03C 3/085 containing an oxide of a divalent metal
• CPC Class Codes: C03C 3/095 containing rare earths
• CPC Class Codes: C03C 4/085 for ultraviolet absorbing glass
• CPC Class Codes: G02B 5/226 Glass filters

Abstract

There is provided by the process of the invention a silicate glass which provides protection against mechanical hazards and short and long wavelength ultraviolet radiation while at the same time high transmission of light in the visible range of the spectrum is maintained. By the process of the invention, the incorporation of cerium oxide into the glass followed by ion exchange strengthening using a mixture of potassium salt and silver nitrate provide a synergistic reduction in transmission of light in the ultraviolet range of the spectrum not heretofore obtainable by the use of either cerium oxide or silver staining of the glass alone.

Claims

1. An ion exchange-strengthened silicate glass made from a glass making batch in which each 100 parts by weight on an oxide basis consisting essentially of:

about 64 to about 75 parts silicon dioxide, about 5 to about 10 parts potassium oxide, about 4 to about 8 parts sodium oxide, about 4 to about 8 parts calcium oxide, and about 2 to about 10 parts cerium oxide.

whereby upon ion exchanging at a temperature either above or below the strain point of said glass in a bath comprising salts of potassium and silver said glass provides an impact-resistant glass filter for ultraviolet light having a wavelength below about 400 nanometers and wherein said filter is transparent to light having a wavelength about 400 nanometers.

2. The ion exchange-strengthened silicate glass filter of claim 1 wherein said glass comprises by weight on the oxide basis up to 2 percent aluminum oxide, up to 3 percent zinc oxide and up to 0.5 percent titanium oxide.

3. An ion exchange-strengthened silicate glass according to claim 1 wherein said glass comprises in parts by weight on the oxide basis:

space="preserve" listing-type="tabular">______________________________________ silicon dioxide 65.4 sodium oxide 7.9 potassium oxide 8.5 calcium oxide 8.1 aluminum oxide 1.8 zinc oxide 2.8 titanium dioxide 0.5 cesium oxide 5.0 ______________________________________

4. An ion exchange-strengthened silicate glass according to claim 1 wherein said glass comprises in parts by weight on the oxide basis:

space="preserve" listing-type="tabular">______________________________________ silicon dioxide 67 sodium oxide 8 potassium oxide 8.8 calcium oxide 8.4 aluminum oxide 1.9 zinc oxide 2.9 titanium dioxide 0.5 cerium oxide 2 ______________________________________

5. An ion exchange-strengthened silicate glass according to claim 1 wherein said glass comprises in parts by weight on the oxide basis 10 parts of cerium oxide.

6. The process of producing a silicate glass filter for ultraviolet light comprising ion exchange strengthening a silicate glass made by preparing a silicate glass making batch in which each 100 parts thereof by weight on an oxide basis consisting essentially of:

about 64 to about 75 parts silicon dioxide, about 5 to about 10 parts potassium oxide, about 4 to about 8 parts sodium oxide, about 4 to about 8 parts calcium oxide, and about 2 to about 10 parts cerium oxide wherein said ion exchange is conducted at a temperature either above or below the strain point of said glass in a bath comprising salts of potassium and silver and whereby said glass provides an impact-resistant glass filter for ultraviolet light having a wavelength below 400 nanometers wherein said filter is transparent to light having a wavelength above 400 nanometers.

7. The process of claim 6 wherein said silicate glass comprises in parts by weight on the oxide basis:

space="preserve" listing-type="tabular">______________________________________ silicon dioxide 65.4 sodium oxide 7.9 potassium oxide 8.5 calcium oxide 8.1 aluminum oxide 1.8 zinc oxide 2.8 titanium dioxide 0.5 cesium oxide 5.0 ______________________________________

and wherein said ion exchange strengthening is conducted at a temperature of about 350°

C to about 450°

C in a bath comprising silver nitrate and potassium nitrate.

8. The process of claim 7 wherein said bath comprises 98.3 weight percent potassium nitrate and 1.7 weight percent silver nitrate and said process is conducted at a bath temperature of 400°

C over a period of 4 hours.