Cellular retroreflective sheeting

• US 4,025,159 A
• Filed: 02/17/1976
• Issued: 05/24/1977
• Est. Priority Date: 02/17/1976
• Status: Expired due to Term

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: McGrath, Joseph M.
• Primary Examiner(s): Corbin, John K.
• Assistant Examiner(s): DELOS Reyes, B. Wm.
• Application Number:
  US05/658,284
• Time in Patent Office: 462 Days
• Field of Search: 350/102-105, 350/106, 350/292, 350/288, 156/99-106, 156/1, 156/331, 156/332, 156/272, 260/77.5 SM
• US Class Current: 359/514
• CPC Class Codes: G02B 5/128 transparent spheres being embedded in matrix

Abstract

Cellular retroreflective sheeting, which comprises a base layer of retroreflective elements and a transparent cover film supported in spaced relation away from the base layer by a network of narrow intersecting bonds that form hermetically sealed cells within which retroreflective elements are isolated from retroreflective elements of different cells, is given greater durability by use of bonds that are cured in situ after they have been thermoformed into sealing contact between the cover film and base layer.

Claims

1. Retroreflective sheeting comprising (1) a base sheet having a layer of retroreflective elements disposed over one of its surfaces;

(2) a cover sheet disposed in spaced relation from the layer of retroreflective elements; and

(3) a network of narrow intersecting bonds extending between said cover sheet and base sheet and comprising binder material thermoformed at the point of contact between said bonds and at least one of said cover sheet and base sheet so as to adhere the two sheets together and form a plurality of cells within which retroreflective elements are hermetically sealed;

characterized in that the binder material is selected from materials that show increased adhesion to said at least one of the cover sheet and base sheet when a solid layer of the material that has been previously laminated to said sheet is cured, and further characterized in that the binder material is cured in situ after being thermoformed, whereby the bonds have increased bond strength to the cover sheet and base sheet.

2. Sheeting of claim 1 in which the curing of said binder material is induced with an electron beam.

3. Sheeting of claim 1 in which said cured binder material comprises an acrylic-based ingredient.

4. Sheeting of claim 3 in which the cover sheet also comprises an acrylic-based ingredient.

5. Sheeting of claim 4 in which the acrylic-based ingredient is polymethylmethacrylate.

6. Sheeting of claim 1 in which the cover sheet includes ingredients that coreact with said binder material during curing of the binder material.

7. Sheeting of claim 1 in which said retroreflective elements comprise transparent microspheres.

8. Sheeting of claim 1 in which said retroreflective elements comprise cube-corner retroreflective elements.

9. Sheeting of claim 8 in which both the base sheet and cover sheet comprise radiation-curable material.

10. Retroreflective sheeting of claim 1 in which the surface of the cover film engaged by the bonds is configured to provide cube-corner retroreflective elements, and the layer of retroreflective elements disposed over a surface of the base sheet comprises transparent microspheres.

11. Retroreflective sheeting comprising (1) a base sheet that includes a support layer and a layer of transparent microspheres partially embedded in, and partially protruding out of, the support layer;

(2) a transparent cover film disposed in spaced relation above the layer of microspheres; and

(3) a network of narrow intersecting bonds comprising binder material thermoformed out of said support layer into sealing contact with the cover film so as to adhere the base sheet and cover film together and form a plurality of cells within which microspheres are hermetically sealed and have an air interface;

characterized in that the binder material is selected from materials that show increased adhesion to the cover sheet when a solid layer of the material that has been previously laminated to the cover sheet is cured, and further characterized in that the binder material is cured in situ by exposure to an electron beam after being thermoformed into contact with the cover film, whereby the bonds have increased bond strength to the cover film.

12. Sheeting of claim 11 in which the cured binder material comprises an acrylic-based ingredient.

13. Sheeting of claim 12 in which the transparent cover film also comprises an acrylic-based ingredient.

14. Sheeting of claim 13 in which the acrylic-based ingredient is polymethylmethacrylate.

15. Sheeting of claim 11 in which the cover film includes ingredients that coreact with said bonds during curing of the bonds.