Solvent resistant room temperature vulcanizable silicone rubber composition

• US 4,029,629 A
• Filed: 10/06/1975
• Issued: 06/14/1977
• Est. Priority Date: 10/06/1975
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Jeram, Edward M.
• Primary Examiner(s): Briggs, Sr., Wilbert J.
• Application Number:
  US05/619,591
• Time in Patent Office: 617 Days
• Field of Search: 260/825, 260/46.5 UA, 260/46.5 H, 260/37 SB
• US Class Current: 523/203
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

A solvent resistant room temperature vulcanizable silicone rubber composition comprising a blend of vinyl-terminated polysiloxanes having from 2 to 98 mole percent of alkylperfluoroalkylalkylene siloxy units in the polymer chain, a hydride cross-linking agent selected from the class consisting of hydride-containing resins composed of mono-functional units and tetrafunctional units and hydride-containing polysiloxanes or a mixture of the above cross-linking agents which composition is cured in the presence of a platinum catalyst.

The above composition cures to an elastomer at room temperature or elevated temperatures. Preferably, there is incorporated into the composition a treated filler which gives the cured elastomer physical strength properties.

Claims

1. A solvent resistant room temperature vulcanizable silicone rubber composition comprising (A) 100 parts of a vinyl-containing polymer of the formula, ##STR19## where Vi is vinyl, R is selected from the class consisting of alkyl radicals of 1 to 8 carbon atoms and phenyl, R'"'"' is perfluoroalkyl of 1 to 8 carbon atoms, x and y are at least 1 and the viscosity of the compound varies from 1,000 to 200,000 centipoise at 25°

C, and the concentration of siloxy units taken y times varies from 5 to 98 mole percent;

(ii) from 0.1 to 50 parts per million of the total composition of a platinum catalyst, and (B) from 1 to 50 parts based on 100 parts of the mixture (A) of a cross-linking polymer selected from the class consisting of (iii) a resin having ##STR20## and SiO₂ units where the R to Si ratio varies from 1.0 to 2.7;

(vi) a resin having

SiO₂ units and RR" SiO units where the R to Si ratio varies from 1.2 to 2.7 and (v) a polymer of the formula ##STR21## where R,R'"'"' are as previously defined, s is at least 1, t and z may be zero or a positive integer and the viscosity of the polymer varies from 10 to 1000 centipoise at 25°

C, where the concentration of siloxy units taken t times varies from 0 to 75 mole percent, and R" is selected from the class consisting of alkyl radicals of 1 to 8 carbon atoms and --CH₂ CH₂ R'"'"' radicals and in (A) (vi) from 1 to 85 parts per 100 parts of polymer (i) of a vinyl-containing compound of the formula, ##STR22## where, R, Vi, R'"'"' are as previously defined;

v and w are at least 1, and the concentration of the Vi (R)₂ SiO₀.5 units with respect to the total terminal units in the polymer varies from 20 to 100 mole percent and the viscosity of the polymer ranges from 100 to 20,000 centipoise at 25°

C.

2. The composition of claim 1 wherein there is present in (A) from 5 to 100 parts of a filler which is selected from the class consisting of titanium dioxide, lithopone, zinc oxide, zirconium silicate, silica aerogel, iron oxide, diatomaceous earth, calcium carbonate, fumed silica, precipitated silica, glass fibers, magnesium oxide, chromic oxide, zirconium oxide, aluminum oxide, alpha quartz, calcined clay, asbestos, carbon, graphite, cork, cotton and synthetic fibers.

3. The composition of claim 1 wherein there is present in (A) from 5 to 100 parts of a filler which is selected from the class consisting of fumed silica and precipitated silica which has been treated with a silicone compound.

4. The composition of claim 1 wherein R is methyl, R'"'"' is CF₃ and R" is --CH₂ CH₂ CF₃.

5. The composition of claim 3 where the silicone compound is silazane.

6. The composition of claim 1 wherein in (A) there is present from 0.1 to 5 parts of iron oxide.

7. The composition of claim 1 wherein the platinum catalyst is a platinum complex with a vinyl-containing polysiloxane.

8. The composition of claim 1 wherein there is present in the total composition from 100 to 10,000 parts per million of a cure inhibitor which is an alkenyl-containing cyclicpolysiloxane.

9. The composition of claim 1 wherein the concentration of the units taken y times in polymer (i) varies from 30 to 98 mole percent.

19. The composition of claim 1 wherein there is further present per 100 parts of (i) 1 to 30 parts of a vinyl-containing polymer of the formula, ##STR28## where m and n are at least 1, R is selected from lower alkyl radicals of 1 to 8 carbon atoms, R'"'"' is a perfluoroalkyl radical of 1 to 8 carbon atoms, R⁵ is selected from alkyl radicals of 1 to 8 carbon atoms, vinyl radicals and mixtures thereof where the alkylvinylsiloxy content varies from 10 to 80 mole percent, and the viscosity of the polymer varies from 100,000 to 10,000,000 centipoise at 25°

C.

10. A process for forming a solvent resistant silicone elastomer comprising (a) mixing (A) 100 parts of a mixture composed of (i) 100 parts of a vinyl-containing polymer of the formula:

##STR23## where Vi is a vinyl, R is selected from the class consisting of alkyl radicals of 1 to 8 carbon atoms and phenyl, R'"'"' is perfluoroalkyl of 1 to 8 carbonatoms, x and y are at least 1, and the viscosity of the compound varies from 1,000 to 200,000 centipoise at 25°

C, and the concentration of siloxy unis taken y varies from 5 to 98 mole percent;

(ii) from 0.1 to 50 parts per million of the total composition of a platinum catalyst;

with (B) from 1 to 50 parts based on 100 parts of the mixture (A) of a cross-linking polymer selected from the class consisting of (iii) a resin having ##STR24## and SiO₂ units where the R to Si ratio varies from 1.0 to 2.7 (iv) a resin having ##STR25## SiO₂ units and RR"SiO units where the R to Si ratio varies from 1.2 to 2.7; and

(v) a polymer of the formula, ##STR26## and mixtures thereof where the concentration of the units taken t times varies from 0 to 75 mole percent where R, R'"'"' are as previously defined, s is at least 1, t and z may be zero or a positive integer and the viscosity of the polymer varies from 10 to 1000 centipoise at 25°

C and R" is selected from the class consisting of alkyl radicals of 1 to 8 carbon atoms and --CH₂ CH₂ R'"'"' radicals and in (A) (vi) from 1 to 85 parts per 100 parts of polymer (i) of a vinyl-containing compound of the formula, ##STR27## where R, Vi, R'"'"' are as previously defined, v and w are at least 1 and the concentration of the Vi (R)₂ SiO₀.5 units with respect to the total terminal units in the polymer varies from 20 to 100 mole percent and the viscosity of the polymer ranges from 100 to 20,000 centipoise at 25°

C and (b) allowing the mixture to cure.

11. The process of claim 10 wherein there is present in (A) from 5 to 100 parts of a filler which is selected from the class consiting of titanium dioxide, lithopone, zinc oxide, diatomaceous earth, zirconium silicate, silica aerogel, iron oxide, calcium carbonate, fumed silica, precipitated silica, glass fibers, magnesium oxide, chromic oxide, zirconium oxide, aluminum oxide, alpha quartz, calcined clay, asbestos, carbon, graphite, cork, cotton and synthetic fibers.

12. The process of claim 10 wherein there is present in (A) from 5 to 100 parts of a filler which is selected from the class consisting of fumed silica and precipitated silica which has been treated with a silicone compound.

13. The process of claim 10 where R is methyl, R'"'"' is CF₃ and R" is --CH₂ CH₂ CF₃.

14. The process of claim 12 where the silicone compound is silazane.

15. The process of claim 10 wherein in (A) there is present from 0.1 to 5 parts of iron oxide.

16. The process of claim 10 wherein the platinum catalyst is a platinum compound with a vinyl-containing polysiloxane.

17. The process of claim 10 wherein there is present in the total composition from 100 to 10,000 parts per million of a cure inhibitor which is an alkenyl-containing cyclocpolysiloxane.

18. The process of claim 10 wherein the concentraton of the units taken y times in polymer (i) varies from 30 to 98 mole percent.

20. The process of claim 10 wherein there is mixed in (A) from 1 to 30 parts of a vinyl-containing polymer of the formula, ##STR29## where m and n are at least 1, R is selected from lower alkyl radicals of 1 to 8 carbon atoms, R'"'"' is a perfluoroalkyl radical of 1 to 8 carbon atoms, R⁵ is selected from alkyl radicals of 1 to 8 carbon atoms, vinyl radicals and mixtures thereof where alkylvinylsiloxy content varies from 10 to 80 mole percent and the viscosity of the polymer varies from 100,000 to 10,000,000 centipoise at 25°

C.