Process and apparatus for evaporating and heating liquified natural gas

• US 4,036,028 A
• Filed: 10/30/1975
• Issued: 07/19/1977
• Est. Priority Date: 11/22/1974
• Status: Expired due to Term

• Current Assignee: Sulzer Brothers, Ltd (Sulzer AG)
• Original Assignee: Sulzer Brothers, Ltd (Sulzer AG)
• Inventors: Mandrin, Charles
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US05/627,331
• Time in Patent Office: 628 Days
• Field of Search: 62/52, 62/53, 62/86-89, 62/96, 62/99, 60/655, 60/671, 60/39.5, 60/39.05, 60/39.18 R, 60/39.18 B, 60/39.02, 60/39.52, 60/39.53, 60/39.46 G, 122/7
• US Class Current: 62/50.3
• CPC Class Codes: F01K 23/02 the engine cycles being thermally coupled
• CPC Class Codes: F02C 6/18 using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants using waste heat as source of energy for refrigeration plants F25B27/02; using the waste heat of a gasturbine for steam generation or in a steam cycle see F01K23/10
• CPC Class Codes: F02C 7/143 before or between the compressor stages
• CPC Class Codes: F17C 2265/05 Regasification
• CPC Class Codes: F17C 9/02 with change of state, e.g. vaporisation
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

The waste heat of an open gas turbine system used to heat a flow of liquified natural gas is recovered and passed via an intermediate heat exchange circuit or system to the flow of liquified natural gas. The intermediate circuit uses hydrocarbons which may or may not have been halogen-substituted as the heat exchange medium. The heat is extracted from the flue by closed piping systems which use water as a heat carrier as well as a system which uses an anti-freeze agent such as methanol. The anti-freeze circuit permits injection of the anti-freeze agent into the intake of the gas turbine while a rectifying column allows recovery of the anti-freeze agent. The intermediate circuit includes a vapor turbine which expands the hydrocarbon medium after the hydrocarbon medium receives heat in order to produce useful work.

Claims

1. An apparatus for evaporating and heating liquid natural gas comprising

means defining a predetermined flow path for a flow of liquid natural gas;

an open gas turbine system having an air intake and an exhaust flue for a flow of hot exhaust gases;

a first heat exchange system for cooling air taken into said air intake and for heating the flow of liquid natural gas;

a second heat exchange system for extracting heat from the flow of exhaust gases in said flue and for heating the flow of natural gas with the extracted heat, said second heat exchange system including a first closed piping system having a hydrocarbon heat exchange medium therein, a first heat exchanger for receiving heat from the flow of exhaust gases to heat the hydrocarbon medium, a second heat exchanger for heating of the natural gas in said flow path in heat exchange relation with the hydrocarbon medium, a compressor means downstream of said second heat exchanger in said flow path for compressing the hydrocarbon medium and a vapor turbine upstream of said second heat exchanger in said flow path for expanding the hydrocarbon medium to produce work;

means for admixing an anti-freeze agent into said gas turbine system air intake; and

a rectifying means for receiving and vaporizing the anti-freeze agent downstream of said air intake, said rectifying means having a head product removal line connected to a third heat exchanger in said first closed piping system for receiving heat from the flow of exhaust gas.

2. An apparatus as set forth in claim 1 which further comprises a second closed piping system for a heat carrier, said second closed piping system passing in heat exchange relation with said first heat exchanger in said first closed piping system and including a fourth heat exchanger in said flue to transfer heat from the exhaust gases to said heat carrier and a pump for pumping the heat carrier to said fourth heat exchanger in said flue.

3. An apparatus as set forth in claim 1 which further includes a burner in said exhaust flue for supplemental heating of the exhaust gases.

4. A process for evaporating and heating liquid natural gas comprising the steps of

passing a flow of liquid natural gas through a predetermined flow path;

generating a flow of hot exhaust gases in a flue of an open gas turbine system;

passing a flow of hydrocarbon heat exchange medium through a closed piping system for evaporation under heat extracted from the flow of exhaust gases, subsequent expansion with the performance of work, liquifaction under a heat exchange relation with the flow of liquid natural gas in said flow path wherein heat is delivered to the liquid natural gas, and compression at an elevated pressure;

admixing a water-miscible anti-freeze agent into an air flow delivered to the gas turbine system;

rectifying a condensed mixed phase of said agent and moisture from the air flow under a portion of the waste heat of said flow of exhaust gases to obtain a gaseous head product; and

passing the gaseous head product into heat exchange relation with said compressed hydrocarbon medium to condense the head product.

5. A process as set forth in claim 4 which further comprises the step of extracting heat from the expanded hydrocarbon medium prior to liquification for delivery to the compressed hydrocarbon medium.

6. A process as set forth in claim 4 which further comprises the step of passing a heat carrier through the flue of the open gas turbine system in heat exchange relation to extract heat therefrom for delivery to the hydrocarbon heat exchange medium in the closed piping system for said evaporation thereof.

7. A process as set forth in claim 4 which further comprises the step of reheating the exhaust gases.