Manufacture of modified basic polyaminoamide with ammonium compound

• US 4,036,821 A
• Filed: 10/24/1974
• Issued: 07/19/1977
• Est. Priority Date: 10/25/1973
• Status: Expired due to Term

• Current Assignee: Wolff Walsrode AG (Dow, Inc.)
• Original Assignee: Wolff Walsrode AG (Dow, Inc.)
• Inventors: Hoppe, Lutz, Behn, Rudolf
• Primary Examiner(s): Anderson, Harold D.
• Application Number:
  US05/517,785
• Time in Patent Office: 999 Days
• Field of Search: 260/78 SC, 260/78 A, 260/78 L
• US Class Current: 525/435
• CPC Class Codes: C02F 1/54 using organic material
• CPC Class Codes: C08G 69/48 Polymers modified by chemical after-treatment
• CPC Class Codes: D21H 17/55 Polyamides; Polyaminoamides; Polyester-amides

Abstract

A process for the production of water-soluble auxiliary agents based on polyaminoamides by reacting a polyfunctional compound with a tertiary, monofunctional amine to form an ammonium compound and reacting that ammonium compound with a basic polyaminoamide, the basic polyaminoamide being the polycondensation product of a dicarboxylic acid, a polyalkylenepolyamine and an aminocarboxylic acid or lactam thereof, the basic polyaminoamide being reacted with 0.15 to 0.19 mol of a polyfunctional compound per mol equivalent of secondary amino group in the polyamide, incorporating that modified basic polyaminoamide in the paper pulp so as to increase the retention of fibres, fillers or pigments, or to accelerate the drawings.

Claims

1. A process for the production of a modified basic polyaminoamide resin which comprises the sequential steps of:

a. reacting substantially equimolar portions of a polyfunctional compound selected from the group consisting of epichlorhydrin, dichlorhydrin, or mixtures thereof, with a tertiary amine selected from the group consisting of trimethylamine, triethylamine, tripropylamine, tributylamine, dimethylaniline, dimethylcyclohexylamine, or mixtures of any of said amines, to form an ammonium compound;

b. reacting 0.2 - 1.8 mols of said ammonium compound with each mol of secondary amine group in a water-soluble, basic polyaminoamide which is a condensation product of

1. a dicarboxylic acid,

2. a polyalkylenepolyamine, and

3. an aminocarboxylic acid or a lactam; and

c. reacting the product of step (b) with 0.15 - 0.19 mol of said polyfunctional compound per mol equivalent of secondary amino group in said polyaminoamide.

2. A process according to claim 1, wherein 0.16 to 0.18 mol of said polyfunctional compound per mol equivalent of secondary amino group of said polyaminoamide is reacted.

3. A process for the production of a modified basic polyaminoamide resin which comprises the sequential steps of:

a. reacting substantially equimolar portions of a polyfunctional compound selected from the group consisting of epichlorhydrin, dichlorhydrin, or mixtures thereof, with a tertiary amine selected from the group consisting of trimethylamine, triethylamine, tripropylamine, tributylamine, dimethylaniline, dimethylcyclohexylamine, or mixtures of any of said amines, to form an ammonium compound;

b. reacting a water-soluble, basic polyaminoamide which is a condensation product of

1. a dicarboxylic acid,

2. a polyalkylenepolyamine, and

5. The process of claim 3 wherein 0.16 to 0.18 mol of said polyfunctional compound per mol equivalent of secondary amino group of said polyaminoamide is reacted.

4. an aminocarboxylic acid or a lactam

with 0.15 - 0.19 mol of said polyfunctional compound per mol equivalent of secondary amino group in said polyaminoamide;

and

c. reacting the product of step (a) with the product of step (b) in the proportion of 0.2 - 1.8 mols of said ammonium compound per mol of secondary amino group in said basic polyaminoamide.